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Chemistry I Final Exam review topics – Semester 1 Probable format: December 2008 80 multiple choice, no written problems or questions. 1 – The Chemical World Scientific method, terms Law of conservation of mass, application of 2 – Measurement and Problem Solving Sig figs, add/sub rule, mult/div rule, apply them, from a picture SI unit system; base units, derived units Prefixes (micro, milli, centi, kilo) Conversion problems; single to multistep problems Density; know its meaning, apply the equation 3 – Matter and Energy States of matter; solid, liquid, gas – properties of , id from a picture Amorphous vs crystalline Matter classification; pure sub (element compound), mixture (homo, hetero); id from a picture Physical vs. chemical properties, changes Methods of separation (distillation, filtration, chromatography) Law of conservation of energy, converting to different forms Energy unit conversion problems Temperature scales, conversions (°C ↔ K) Heat calculations – calorimeter, q = mcT 4 – Atoms and Elements Democritus Dalton’s atomic theory Thomson – cathode ray tube work; what did it show Rutherford – gold-foil experiment; how was it done, what did it show Structure of the atom; nucleus, protons, neutrons, electrons Notation for an element; atomic number, mass number, charge Periodic table arrangement; based on what; zig-zag line Group names; Alkali, alkaline earth, halogens, noble gases Charges for those elements with a fixed charge Isotopes Average atomic mass; conceptual idea; calculate one 5 – Molecules and Compounds Law of constant composition Diatomic molecules (7 of them) Ionic vs. covalent compounds; how do you know Naming compounds and writing formulas o Ionic compounds – know those ions and charges o Molecular compounds – know those prefixes o Acids – three types 6 – Chemical Composition Mole conversions Avogadro’s number Molar mass Conversions from a chemical formula (formula ratio) Percent composition (by mass); from data; from chemical formula Empirical formula; molecular formula problems 7 – Chemical Reactions Evidences of a chemical reaction Writing and balancing chemical equations Aqueous, what does it mean Solubility, (sol. table (p. 200)) will be provided, be able to use it Precipitation reactions Molecular, ionic, and net ionic equations (spectator ions) Acid base reactions; what are the products, … Gas evolution reactions; 4 gases you will need to predict Oxidation- reduction reaction; yes or no Combustion reactions Identify types of reactions (Syn, Dec, SR, DR, Comb) Identify if a reaction is redox or not 8 – Quantities in Chemical Reactions Calculations involving balanced equations o Mass – mass o Mole - mole o Molar volume o Molarity o Thermochemical equations (involving heat) Limiting reactant concept Theoretical yield Percent yield 17 – Radioactivity & Nuclear Chemistry Becquerel – discovered radioactivity Curies – coined the term radioactivity and researched it for years Types of radioactive emissions; alpha, beta, gamma Write and balance nuclear equations Alpha; what’s an alpha particle like; write a decay equation; what happens to alpha particles once they leave Beta decay; what’s a beta particle like; write a decay equation, where does a beta particle come from Gamma decay; … Positron emission; what’s a positron like; write a decay equation, where does a positron come from Half-life problems (whole number of half-lives) Decay series Fission, nuclear reactors – basic components, finish an equation Fusion, stars (including our sun), finish an equation 18 – Organic Chemistry Vitalism; what is it Wohler; what did he do? Hydrocarbons, names and structures, straight, branched o Saturated, unsaturated o Alkanes, alkenes, alkynes o Aromatics (benezene); ortho, meta, para Functional groups; recognize them; (name the underlined types) o Alcohols, ethers, aldehydes, ketones, carboxylic acids, esters, amines Polymers; two types – addition, condensation o monomer