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6. Flow and Humidity Sensors Flow sensors Venturi tube turbine flowmeter ultrasonic flowmeters laser flowmeter thermal flowmeters, anemometer correlation flowmeter Coriolis flowmeters Humidity sensors piezoresistance - type resistance - type capacitance - type gravimetric SAW dew-point 1 Flow sensors Flow sensors can be divided into two groups: • mass flowmeters registering the mass flow rate dm/dt • volume flowmeters registering the volume flow rate dV/dt Flow rate Mass flow rate for a cross section A dV dm vA dt A dt A For a pipe of a cross section A: dm dV v dA v av A dt dt A In general there exists a distrubution of velocity v(r) in a pipe cross-section, what has to be taken into account in the design of flowmeters (one determines the local value or average for a certain area). Depending on the magnitude of Reynolds number we have: a) laminar flow (Re < 2300) r 2 v v m 1 - R R – radius of a pipe b) transition flow (critical), for 2300<Re<104 c) turbulent flow, dla Re > 104 r v v m 1 - R Reynolds number: Re 2R v av 1 n n - dep. on Re and roughness of a pipewall η – coeff. of viscosity ρ - density Velocity profiles for different kinds of flow 1 – laminar flow 2 – turbulent flow (rough pipewalls) 3 – turbulent flow (smooth pipewalls) Narrow channel sensors One measures the differential pressure existing during transfer of a fluid through the narrow channel. Sensors with Venturi tube v 2w v 2n pw pn 2 2 vwAw vvAn Bernoulli’s law continuity equation Solving the equation system one obtains: vn 1 A 2n 1- 2 Aw 2(p w - p n ) v n p Volume flow rate: dV v v A n A n p dt Mass flow rate: dm A n p dt Turbine flowmeter Frequency of rotations depends linearly on medium velocity. Time rate of change of a pulse number at the magnetic coil output is prop. to the volume flow rate. Precise measurements are obtained for liquids of small viscosity. Ultrasonic flowmeters Applied essentially for measurements of volume flow in liquids. Transit time method Transit time for a down-stream direction: t1 s c v s cos c – velocity of sound in a fluid vs – average fluid velocity Transit time for an up-stream direction: t2 A, B – transmitters/receivers s c - v s cos Fluid velocity: vs s 1 1 - 2 cos t 1 t 2 The local value of liquid velocity v(r) can be also measured t1 l c v( r ) t2 l c - v( r ) down-stream direction up-stream direction t t 2 - t 1 2 v( r ) c 2 - v( r ) 2 In order to avoid the influence of temperature on sound velocity c one determines: t 2 v( r ) t1t 2 l Volume flow rate: dV K R 2 vx dt where K depends on r/R and vx is a given velocity Doppler flowmeter Developed first of all for measurements in inhomogeneous liquids, e.g. containing solid particulates or gas bubbles. If the transmitted wave frequency is f, then due to scattering on moving particles one observes also f1 and f2. Scattering by escaping particles gives: f1 f c - vx c Scattering by particles moving in reverse direction gives: f 2 f Velocity v is determined from relation: f 2 - f1 2v x 2v cos f c c c vx c Doppler flowmeter, cont. Doppler flowmeters enable also the determination of velocity profile. The ultrasonic pulses lasting 0.1 – 1 ms are emitted and the distance from which they are received is changed by selection the instant of time of receiver opening. By this method the variations of velocity profile of blood in aorta are determined. Laser Doppler flowmeter fD - Doppler shift Thermal flowmeters These flowmeters give the mass flow rate. The mass flow rate is equal: dm dQ / dt dQ / dt dt c w T c w (T2 - T1 ) By keeping T constant (change of mass requires change of a heat): dm dQ dt dt In order to keep constant T an appreciable power is required. Placing a heater on a pipe (at low flows) decreases the power consumption. A bypass can be also applied for this purpose. Anemometers At a staeady state the power of heating is equal to the power of heat dissipation for a wire resistor (Tw – resistor temp., Tf – fluid temp.) coeff. of heat loss From above equations one obtains the fluid velocity vf wire: PtRh, W, Pt diameter: 4 – 10 mm length: 1 mm layers: Ni, Pt Anemometers, cont. Constant temperature condition (Tw and Rw constant): Constatnt current condition: Thermal anemometer Anemometers in a measurement system Constant current method Constant current bridge (R2 - initial balance setting, source resistor – initial temperature setting) Constant temperature method A bridge with constant temperature sensor Uout ~ vgas Correlation flowmeter The system realizes the correlation function T 1 R xy () lim y( t ) x ( t - ) dt T 2T - T Rxy attains maximum for: Having L and one calculates velocity. Used at injection of physiological fluids in medicine. No contacts of sensors with the medium. Humidity sensors Moisture – the amount of water contained in a liquid or solid. Absolute humidity – the mass of water vapour per unit volume. Relative humidity (RH) – the ratio of actual vapour pressure (pw - partial pressure of water vapour) to the saturation vapour pressure ps at the same temperature. RH pw 100 ps Dewpoint temperature – the temperature at which RH is 100%. At dewpoint condensation droplets appear (at low teperature below O0C the moisture can freeze). Piezoresistance sensors 4 piezoresistors at the membrane edge (2 parallel and 2 perpendicular to the edge). The voltage UA at a bridge output is a linear function of the difference between stress σL in a perpendicular resistor and stress σQ in a parallel resistor. π44 – piezoresistance coeff. of Si (100) in direction <110> UA - 44 U SS ( L - Q ) 2 R. Buchhold et al. Sens.&Act.B 53 (1998) 1-7 Integrated resistance sensors Integrated resistance sensor in CMOS-MEMS technology. Polysilicon resistor RS changes its resistance due to water vapour absorption by the WO3 surface layer. Vout = - RS/R1 ·Vin C.L. Dai i in. Sens.&Act.B123 (2007) 896 Integrated resistance sensors, cont. Porous sensitive layer as WO3 nanowires. Integrated humidity sensor in 0,35 μm technology (outside view). C.L. Dai i in. Sens.&Act.B 123 (2007) 896 Manufactured op amp Resistance - capacitive sensors Measurement of impedance Z Au Equivalent circuit of a pore and its environment Rs Ro Al2O3 CB Co RB Al Anodized Al R0, C0 – layer of aluminum oxide RS – pore wall RB, CB – area between the pore bottom and Al electrode Capacitive sensors A capacitive thin flm humidity sensor. The electrodes form interdigitized pattern. The dielectric layer can be CVD SiO2 or CVD PSG (phosphosilicate glass). When humidity increases, the distributed resistance drops and equivalent capacitance increases. Capacitive sensors, cont. Capacitive sensors with different electrode configuration: interdigital, spiral, grid. Nonlinear behaviour of capacitance as a function of RH Cs w C0 d n J.G. Korvink i in., Sens. Mater. 4 (6) (1993)323-335 Capacitive sensors, cont. Microsystem technologies Membrane with a buried n-Si heater for regeneration, surface gold meshtype electrodes and porous silicon (PS) layer absorbing humidity. G.M. O`Halloran et al., Delft Univ. Press (1999) 1919 Bulk-type humidity sensor with a surface heater and temperature detectors. Porous Si sheet is covered by meshtype electrodes. Z.M. Rittersma i in., Sens. Mater. 12 (1) (2000) 035 Gravimetric sensors Oscillating element, e.g. quartz, is covered with a humidity absorbing layer. Change in oscillator’s mass causes a change in its resonance frequency: f -m f0 m For a quartz plate with AT cut, 35o15’ versus its z-axis, one obtains: f -2,3 106 f 02 m A Large fo is therefore beneficial. the units are:Δm [g], A [cm2 ], f [MHz] Gravimetric sensor in an oscillator circuit Typical parameters for a quartz microbalance (QMB) sensor are as follows: f0 = 10 MHz, Δfmin = 0,1 Hz, Δfmax = 1 – 10 kHz. In this case it is possible to detect the change of a mass at the level of 0,1 ng/cm2. When measuring with computer, one can use the frequency/voltage converter and the output voltage is passed to the measurement card for data aquisition. Gravimetric sensors, cont. A resonant cantilever humidity sensor with a piezoelectric PVDF (polyvinyl –difluorene) layer and Al electrodes. Expanding or contraction of the piezoelectric foil forces the cantilever into vibracions which are influenced by the change of mas of the adsorbed water vapour. A. Gluck i in. Sens.&Act.B 18/19 (1994)554 Sensors based on Surface Acoustic Waves (SAW) Surface wave in a piezoelectric medium. Rayleigh wave consists of two components: a longitudinal wave and shifted in phase by π /2 transversal wave. These waves disappear completely at the depth of order two wavelengths. SAW sensors Interdigitated electrodes on the piezoelectric substrate forming a transducer with period L and aperture W. The condition for resonance frequency is: f0 v v L v – velocity of a sound Changing the period L of a transducer one can generate SAW waves in a wide frequency range. For a quartz substrate one obtains frequencies in the range from ca. 30 MHz to 1 GHz. In this case the resonance frequency is not connected with a thickness of the quartz plate. SAW resonator SAW resonator with a hygroscopic layer. SAW resonator in a resonance is equivalent to the series connection of RLC elements with a parallel capacitance C0. SAW sensors, cont. Measurement of phase shift in a differential configuration of delay lines. One delay line is covered with a humidity absorbing layer, the other serves as a reference. Detection system of frequency shift for two SAW resonators in a differential configuration. As small frequency changes as 10-8 are detected. SAW sensors, cont. Practical solution of a system based on measurement of frequency change for differentially connected resonators. The change in frequency is caused by absorption of humidity by a hygroscopic polimer PVA. M. Penza et al. Sens.& Act.B 68 (2000)300-306 Psychrometric sensor Temperature difference ΔT = T1 – T2 is a function of relative humidity RH. Dew point sensors – optical type The dew point is determined by temperature at which the water vapour and the liquid are in equilibrium. The mirror covers with water droplets and a diffusive reflectivity appears (instead of specular). The dew point temperature determines RH, once the pressure is known. Dew point sensors – optical type, cont. Condensing water vapour changes the amplitude and polarization of an incident optical signal. S. Lomperski et al. Meas. Sci. Technol. 7 (1996) 742-745 Dew point sensors – capacitive type Capacitive-type dew point sensor R. Jachowicz et al. Sens.& Act. A 85 (2000)75-83 Intersection of a membrane - the smallest repeatable fragment of capacitive detector (not to scale).