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CHEM 1411 Study Guide #2 Introduction to Molecules, Ions, Formulas and Stoichiometry (revised 08/23/07) (Kotz, Treichel, Weaver, 6th Ed) Textbook Readings and Assignments. Chapter 3: All sections, pages 98 - 139 Know: Charges on Some Common Ions, Fig 3.7, pg 105; Fig 3.9, pg 110; Table 3.1, pg 107 Key Terms: molecules, compounds, formulas, molecularformula, condensed-formula, structural-formula, ball-and-stick model, space-filling model, ionic compound, ions, cations, anions, polyatomic ions, halide ions, oxoanions, electrostatic forces, crystal lattice, Coulomb’s Law, binary compound, covalent bond, mole, percent composition, mass percent, empirical formula, formula weight (FW), hydrated compound, anhydrous, mole weight (GMW), molar mass (MM) Key Equation, Eq 3.1, pg 112, pg 131 Problems: 1, 2, 4 - 39, 41, 43, 46, 49, 51, 53 – 57, 59, 61 – 63, 65, 67, 71, 75, 83, 85 – 91, 95, 97, 98, 100, 102 – 104, 111 – 113. Chapter 4: All Sections, pages 140 - 173 Know: Key Terms: quantitative, balanced chemical equation, reactants, products, law of conservation of matter, stoichiometry, coefficients of balance, combustion, stoichiometric-factor, limiting reagent, excess reagent, percent yield, actual yield, theoretical yield, Key Equations, pg 165 Problems: 3 – 5, 7, 9 – 11, 13, 15, 17, 19 – 24, 27, 31, 33, 39, 41, 45, 47, 51, 53, 55, 57, 61, 65, 66, 74, 75, 77, 79, 80, 83. Study Guide (optional). Chapter 3: pages 32 - 44 Chapter 4: pages 45 - 66 Computer Generated Problem Set Stoichiometry - due at exam time CHEM 1411 Study Guide #2 page 2 General Chemistry Interactive CD-ROM (version 3.0) Chapter 3: All sections, except 3.13, Naming Alkanes Chapter 4: All sections Laboratory Work. (see: http://www.delmar.edu/nsci/cgambill/labsch11071.pdf ) Properties of Hydrates (Experiment #6) Determination of Chemical Formula (Experiment #4) Web Resources 1. Formulas, Compounds, Naming tutorials, see: http://science.widener.edu/svb/tutorial/index.html 2. Atoms, Ions and Molecules, Writing and Naming Compounds, see: http://www.chemistry210.com/notes/u01s02d.htm 3. Balancing Equations and Reaction Types, see: http://dbhs.wvusd.k12.ca.us/Equations/Equations.html 4. A Tutorial on Balancing Chemical Equations, see: http://www.chemistry.ohio-state.edu/betha/nealChemBal/ 5. Balancing Chemical Equations, see: http://members.aol.com/profchm/balance.html 6. Six Types of Chemical Reaction, see: http://misterguch.brinkster.net/6typesofchemicalrxn.html 7. The Chemistry of Carbon (diamond, graphite and Buckyball), see: http://www.nyu.edu/pages/mathmol/modules/carbon/carbon1.html 8. Library of 3-D Molecular Structures (requires browser plug-ins), see: http://www.nyu.edu/pages/mathmol/library/ 9. Structure of Amino Acid Side-Chains (structural formulas and molecular models), see: http://imgt.cines.fr:8104/textes/IMGTeducation/Aidememoire/_UK/aminoacids/TABLE-AA/ 10. The Molecular Structure Pages, see: http://www.chem.purdue.edu/gchelp/molecules/ 11. Ionic Bonding, see: http://www.sparknotes.com/chemistry/bonding/ionic/section1.html CHEM 1411 Study Guide # 2 page 3 12. Percent Composition and Molecular Formula, see: http://www.epcc.edu/faculty/victors/pcef.htm 13. Percent Composition - Formulas (pdf file), see: http://www.sciencebyjones.com/PDF%20files/Formula%20Math%201%20PDF.pdf 14. Mathematics of Chemistry, see: http://dwb.unl.edu/Chemistry/LearningObjectives/NY05.html 15. Atoms and Molecules - Quizzes (math relationships), see: http://lrc-srvr.mps.ohio-state.edu/under/chemed/qbank/quiz/bank2.htm 16. Wigner's Tutotials, Chapter 3 and Chapter 4; see: http://science.widener.edu/svb/tutorial/index.html 17. ICSD Chemistry Zone, Stoichiometry Lessons; see: http://207.10.97.102/chemzone/lessons/05reactions/default.htm 18. LUCID - Stoichiometry; see: http://www.chem.lsu.edu/lucid/subjectinfo/stoichiometry.html Steps to solve stoichiometry problems. 1. write the balanced equation 2. write known ratios from balanced equation coefficients of balance relate to moles of species involved 3. determine the limiting reagent and the excess reagents set-up mole ratio table from coefficients of balance 4. base all calculations of limiting reagent 5. calculate the theoretical yield (100 % conversion) 6. calculate the per cent yield