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Early Proterozoic Assembly of Tectonostratigraphic Terranes in Southwestern North America Author(s): Karl E. Karlstrom and Samuel A. Bowring Source: The Journal of Geology, Vol. 96, No. 5 (Sep., 1988), pp. 561-576 Published by: The University of Chicago Press Stable URL: http://www.jstor.org/stable/30053570 . Accessed: 06/10/2014 18:24 Your use of the JSTOR archive indicates your acceptance of the Terms & Conditions of Use, available at . http://www.jstor.org/page/info/about/policies/terms.jsp . JSTOR is a not-for-profit service that helps scholars, researchers, and students discover, use, and build upon a wide range of content in a trusted digital archive. We use information technology and tools to increase productivity and facilitate new forms of scholarship. For more information about JSTOR, please contact [email protected]. . The University of Chicago Press is collaborating with JSTOR to digitize, preserve and extend access to The Journal of Geology. http://www.jstor.org This content downloaded from 129.24.37.22 on Mon, 6 Oct 2014 18:24:18 PM All use subject to JSTOR Terms and Conditions EARLY PROTEROZOIC ASSEMBLY OF TECTONOSTRATIGRAPHIC IN SOUTHWESTERN NORTH AMERICA' KARL E. KARLSTROM AND SAMUEL TERRANES A. BOWRING of Geology,Northern Department ArizonaUniversity, Flagstaff, Arizona St. Louis, Missouri University, of Earthand Planetary Sciences,Washington Department ABSTRACT A 500kmwideearlyProterozoic orogenicbeltinArizonaand adjacentareasis dividedintolithotectonic and U-Pbzirconstudiessuggestthatthese shearzones. Structural blocksby northeastand north-trending juxtaposition blocksmayhaveexperienceddifferent tectonichistories and strike-slip priorto their bythrust on shearzones. A northwestern herecalledtheYavapai Province,is composedofat province, movements leastfivetectonicblocksand was assembledat about1700Ma. A southeastern province,herecalledthe Mazatzal Province,is composedof at least threeblocksand was assembledand juxtaposedwiththe provinceduringtheMazatzalorogeny, between1695and 1630Ma. Thediversity northwestern ofseemingly nowinclose proximity to each other,andtheabsenceofsystematic 1700Ma tectonicregimes incompatible plutonism, cross-strike ofdeformation, suggesta model changesin age and character and metamorphism, wherebythe orogenicbelt developed,and NorthAmericagrew,by assemblyof diversetectonostratito previousmodelsofprogressive graphicterranes.Such a modelprovidesan alternate hypothesis working growth southward of ofNorthAmerica.Thismodelprovidesa betterexplanation fortherapiddevelopment theorogenicbelt(1700-1630),theaccretion oflargevolumesofjuvenilecrust,andthecomplexity intiming and stylesof EarlyProterozoictectonism in southwestern NorthAmerica. INTRODUCTION More than 50% of the present crust of North America was assembled in the period 2.0-1.6 Ga. Studies of the development of earlyProterozoic orogenic belts are therefore essential for understandingthe historyand mechanisms of continental growthof North America. In Canada and the northernUnited States, Proterozoic orogenic belts surround Archean cratons and record a major period of continental assembly 2.0-1.8 Ga (Hoffman 1988). Much of the continentalcrustin these orogens consists of older sialic crustthatwas modifiedby tectonism, with relativelyminor additions of juvenile crust (Patchett and Arndt1987). The wide orogenicbelt in southwesternNorth America is fundamentallydifferent in that it apparently represents the generation of large volumes of juvenile Proterozoic (1.8-1.6 Ga) crust (DePaolo 1981; Nelson and DePaolo 1985; Wooden et al. 1987). The north margin of the Proterozoic orogenic belt in southwesternNorth America is the Cheyenne belt of southern Wyoming, a ' ManuscriptreceivedSeptember14, 1987;acceptedApril22, 1988. OF GEOLOGY,1988, vol. 96, p. 561-576] [JOURNAL © 1988by The University of Chicago.All rights reserved. 0022-1376/88/9605-0006$1.00 wide mylonitezone interpretedto representa suture zone between the Archean Wyoming Province, with its miogeoclinal cover sequence, and accreted 1.8-1.7 Ga island arc terranes(Hills and Houston 1979; Karlstrom and Houston 1974; Duebendorfer and Houston 1987). From southern Wyoming, early Proterozoic crust extends southward for more than 1300 km to northernSonora, Mexico. Based on our work in central Arizona, we propose a model which views the developmentof this orogenic belt, and hence early Proterozoic growth of southwestern North America, in terms of the independent development and subsequent accretion of diverse tectonostratigraphic terranes.This "terrane" interpretation from is fundamentallydifferent previous tectonic models for the Proterozoic of the Southwest (for example, Van Schmus and Bickford 1981; Condie 1982, 1986; Anderson 1986; Conway and Silver in press) that propose southward growth by progressive addition of continentalmarginvolcanic arcs and arc-related or continental margin sedimentarybasins. In the absence of paleomagnetic and biostratigraphicdata, which have been used successfully to definefar-traveledtectonostratigraphicterranesin the Cordillera (Jones et al. 1983), our approach is as follows. (1) We first identifytectonic blocks where a block is defined as an area of Proterozoic basement bounded by major Proterozoic faults and 561 This content downloaded from 129.24.37.22 on Mon, 6 Oct 2014 18:24:18 PM All use subject to JSTOR Terms and Conditions 562 KARL E. KARLSTROM AND SAMUEL A. BOWRING shear zones or, if a tectonic boundary is not exposed or mapped, an area with distinctly differentgeologic character than adjacent areas. (2) Kinematic indicators are used to deduce sense and history of movements across shear zones. (3) Geologic history withineach block is established by determining the relative timing of sedimentation, plutonism,deformation,and metamorphism. (4) U-Pb zircon geochronology is utilized to constrainthe geologic history.(5) Similarities and differencesin geologic historyare used to help identifytectonostratigraphic terranes.A terrane is defined here as a block or group of blocks that represent a semi-coherent segment of Proterozoic lithosphere which evolved, at least in part, separately fromadjacent terranes.(6) We then attemptto define the timingofjuxtaposition of terranesand the assembly of orogenic provinces. A province is definedas a large tract of the orogen that was assembled during one major pulse of convergenttectonism. The quality of available geologic and geochronologic data is variable across the transect so that our identificationof blocks and the way in which the proposed blocks are grouped into tectonostratigraphicterranesis preliminary.Our hope is that by pointingout importantdifferencesbetween blocks, and by emphasizingthe importanceof the major network of shear zones, we will stimulatefurther work to evaluate stratigraphicand tectonic links between blocks and therebydistinguish tectonic boundaries that separate fundamentally differentterranes fromboundaries that record relatively minor movements within terranes. TECTONOSTRATIGRAPHIC PROVINCES IN ARIZONA Figure 1 shows that Arizona's Transition Zone between the Colorado Plateau and Basin and Range Province, combined with adjoining areas of the Basin and Range Province of Nevada, southeasternCalifornia, and Sonora, expose a 500 km long outcrop belt that is subperpendicular to the Proterozoic orogenic strike. This outcrop belt exposes an orogenic cross section thatis as wide as many of the world's major orogens. For perspective, a comparable cross-strike distance in the Cordilleran and Appalachian orogens in most places would extend fromthe continental slope to the undeformedforeland. Structuralstudies and geologic mappingin Arizona have identifieda familyof north-and northeast-trendingEarly Proterozoic shear zones that divide this transect into at least eighttectonic blocks (figs. 1 and 2). Some of these shear zones were recognized fromearly mapping (Shylock fault zone and Chaparral fault zone of Anderson and Creasey 1958); othersare emergingfrommore recentstudies (Moore Gulch fault-Maynard 1986; Karlstromand Conway 1986; Slate Creek shear zone-Roller and Karlstrom 1986; Roller 1987). We can now document thatseveral of these blocks experienced differentdeformational and tectonic histories and therefore should be considered distinct tectonostratigraphicterranes. In central Arizona the Moore Gulch fault (fig. 1) is part of a major boundarythatseparates a northwesternprovince, the Yavapai Province, froma southeastern province, the Mazatzal Province. This fault zone contains mylonites with subvertical foliation and stretchinglineation thatrecord movementafter 1700 Ma, the age of the youngest rocks deformedalong the Moore Gulch fault. This tectonic boundary approximately coincides witha geochronologic boundary proposed by Silver (1965, 1967, 1969) and Silver et al. (1977, 1986) based on U-Pb zircon data. This geochronologic boundary was believed to separate an older 1800-1700 Ma province to the northwestfroma younger 1700-1600 Ma province to the southeast. Karlstromet al. (1987) presentedtwo models for the juxtaposition across the Moore Gulch fault. In the firstmodel, the 1700 Ma supracrustalsequence of the Mazatzal province was deposited with angular unconformity on the previously accreted island arc volcanic and batholithicrocks of the Yavapai Province. Younger dip-slip motion along the Moore Gulch faultjuxtaposed deep levels of the Yavapai Province and shallow levels of the Mazatzal Province. The second model considers the two provinces to representseparate tectonostratigraphicterranes that record verydifferent tectonic histories.In itthe Moore Gulch faultis considered to be part of the suture between rocks of the two provinces. This paper presents argumentsthatsupport the second model of Karlstrom et al. (1987), involvingtectonicjuxtaposition of these two This content downloaded from 129.24.37.22 on Mon, 6 Oct 2014 18:24:18 PM All use subject to JSTOR Terms and Conditions ASSEMBLY 115° 114° OF TECTONOSTRATIGRAPHIC 113° 112° TERRANES 111 563 110 FIG. 1.-Distribution of early Proterozoic rocks (stippled) in Arizona and adjacent areas. Proposed tectonostratigraphicblocks: MO-Mojave block; HB-Hualapai-Bagdad block; G-Green Gulch block; B-Big Bug block; A-Ash Creek block; M-Mazatzal block; S-Sunflower block; P-Pinal block. Major Proterozoic shear zones: CH-Chaparral fault zone; SH-Shylock fault zone; MG-Moore Gulch fault; SC-Slate Creek movement zone. Lineaments on Colorado Plateau: SI-Sinyala fault system; BABrightAngel faultsystem; MB-Mesa Butte faultsystem;G-northwest boundary of gravityhigh;HOHolbrook lineament,a gravityand magnetic lineament(see Shoemaker et al. 1978; Lysonski et al. 1980; Sauck and Sumner 1970). Other boundaries: Pb (shortdashed line)-boundary between Pb isotope provinces proposed by Wooden et al. (1987); Sm/Nd(dot-dash)-boundary between Sm/Ndprovincesproposed by Bennettand DePaolo (1987); C (dots)-geochemical boundaryproposed by Condie and Demalpas (1985) and Copeland and Condie (1986). major provinces. Each province is composed of smaller tectonostratigraphicterranes; we argue that the orogenic belt in central Arizona is a collage of blocks and terranesthat experienced differenttectonic histories and then were assembled perhaps starting as early as 1740 Ma and continuinguntil about 1630 Ma. The following section reviews the distinctive tectonic features of each block and the nature of the major shear zones. More detailed discussion of various aspects of the geology are in Karlstromand Conway (1986), Conway and others (1987), Karlstrom and others(1987), and referencestherein.All This content downloaded from 129.24.37.22 on Mon, 6 Oct 2014 18:24:18 PM All use subject to JSTOR Terms and Conditions TIMING OF TECTONIC ROCK UNITS PINAL SCHIST TONTO BASIN SUPERGROUP AND DIAMOND POINT INTRUSIVE SUITE GRANITIC ROCKS VOLCANOGENIC ROCKS, INCLUDING YAVAPAI SUPERGROUP MO HB A MOJAVE HUALAPAI/BAGDAD NEVADA GREEN GULCH ARIZONA BIG BUG ASH CREEK MAZATZAL SUNFLOWER- CALIF PINAL FIG. 2.-Block diagramshowingproposed tectonostratigraphic blocks in Arizona and adjacent regions.The province(5 blocks) froma composite southeasternprovince(3 blocks). Timingof tectonicevent northwestern dates in Karlstromet al. (1987) and unpublisheddata. This content downloaded from 129.24.37.22 on Mon, 6 Oct 2014 18:24:18 PM All use subject to JSTOR Terms and Conditions ASSEMBLY OF TECTONOSTRATIGRAPHIC TERRANES ages, unless otherwise referenced,are U-Pb zircon ages taken fromTable 1 of Karlstrom and others (1987). 565 thatis axial planar to tight-to-isoclinalfolds. This foliation is cut by unfoliateddikes and plutons of the Cherrybatholith,which is not penetrativelydeformedexcept along the marYAVAPAI PROVINCE BLOCKS AND SHEAR ZONES gins of the block, in the Moore Gulch and The Yavapai Province is divided into five Shylock fault zones. Thus, timingof deformationin the Ash Creek Group is bracketed blocks, the Ash Creek, Big Bug, Green between 1790 and 1740 Ma and is the oldest Gulch, Hualapai-Bagdad, and Mojave blocks (figs. 1 and 2). These blocks are made up of known deformationin central Arizona. supracrustal rocks of the Yavapai SuperShylock Fault Zone.-The Shylock fault zone is a several kilometerwide zone of vertigroup and associated calc-alkaline batholiths (Andersonet al. 1971). (The lithostratigraphic cal foliation,with dominantlyvertical lineation, that extends some 60 km north-south term Yavapai Supergroup is used here in place of the chronostratigraphictermYavaand separates the Ash Creek and the Big Bug pai "Series" used by Anderson et al. (1971) blocks. This zone records a complex deforin accordance with amendments to the U.S. mation historythat we interpretto have reCode of stratigraphicnomenclatureproposed sulted fromtranspressionalconvergence beby Henderson et al. 1980). The Yavapai tween blocks (Karlstrom 1988). Deformation, at least in part, post-dated the 1720 Bland Supergroupis a diverse sequence of maficto intermediate volcanic rocks and volcaniquartz diorite of the Cherrybatholith of the Ash Creek block. The Bland quartz diorite is clastic sedimentaryrocks in centralArizona. intenselyfoliated along its west margin and These rocks were divided by Anderson et al. (1971) into two groups, the Ash Creek Group contains the vertical lineation that is characteristicof early movements on the Shylock and the Big Bug Group, the lattermade up of fault zone. The vertical L-S fabric records the Green Gulch Volcanics, Spud Mountain Volcanics, and Iron King Volcanics. The shorteningand dip-slip movementacross the zone. Vertically-plungingisoclinal folds in blocks in centralArizona correspondto these the Shylock fault zone are overprinted by stratigraphicsubdivisions, as each of the groupsis, forthe most part, areally restricted folds with consistent sinistral asymmetry, to the fault-boundedblocks definedin figure and early vertical foliationis reactivated in a 2. (The followingdiscussion of northwestern zone several hundredmeterswide and 25 km long by sinistral strike-slipmovement. This blocks proceeds from the southeast to the northwest.) reactivated zone in the Shylock is called the Ash Creek Block.-The Ash Creek block is Cleator mylonitezone (Darrach et al. 1986). bounded on the southeast by the Moore Transpressional movement involving both Gulch fault and on the west by the Shylock shorteningacross the Shylock fault and sinfault zone. It contains: (1) the Ash Creek istral strike-slipappear to have been tempoGroup, the oldest rocks in central Arizona rally related to intrusion of the 1699 Ma (ca. 1790 Ma), with the importantmassive Crazy Basin Quartz Monzonite (Karlstrom sulfide deposit at Jerome; (2) the Cherry and Conway 1986; Conway et al. 1987). batholith,a large calc-alkaline batholithwith Big Bug Block.-The Big Bug block is numerousplutons thatrange in age from1740 bounded by the Shylock fault zone on the to 1720 Ma and in composition fromquartz east and the Chaparral faulton the northwest. dioriteto granodiorite,and (3) a sequence of Big Big Group rocks in thisarea include mafic metavolcanic and metasedimentary rocks to felsic volcanic and volcaniclastic rocks thatcrop out near the Moore Gulch faultand thatare dated at 1755 Ma and are intrudedby 1750-1735 Ma granodiorites. One of these are intruded by the Cherry batholith. The metamorphicgrade of the Ash Creek Group granodiorites,the Brady Butte granodiorite has not been studied in detail, but pet(1750 Ma), intrudesthe Big Bug Group and is rographic descriptions by Anderson and unconformablyoverlain by metasedimentary Creasey (1958) suggest upper greenschistto and metavolcanic rocks of the Texas Gulch lower amphibolite grade metamorphism. Formation.The Brady Buttegranodioriteand the Texas Gulch Formation are folded toRocks of the Ash Creek Group contain a steeply dipping, northwest-trending foliation getherinto recumbentisoclinal folds (F1) that This content downloaded from 129.24.37.22 on Mon, 6 Oct 2014 18:24:18 PM All use subject to JSTOR Terms and Conditions 566 KARL E. KARLSTROM AND SAMUEL A. BOWRING plunge shallowly to the northand verge west or northwest. This early recumbent folding was associated with northwest-directed thrustingas shown by asymmetricalfabricsin the mylonitic Brady Butte Granodiorite (Karlstrom 1988). Recumbent folds (F1) are refolded by uprightfolds (F2) with variable plunge and subvertical axial plane foliation. In most of the Big Bug block, the dominant verticalfabricis related to intense shortening (F2) but is a composite fabric consisting of rotatedand transposed bedding and S1 and S2 axial plane foliation. This composite foliation, with subvertical stretchinglineation, can be traced eastward and is continuous with the vertical fabric of the Shylock fault zone, which exhibits similar sequence and style of fold generations. If the correlationof the vertical fabric (F2) in the Big Bug block with the vertical fabric in the Shylock fault zone (F2) is correct, F2 shorteningdeformation must have post-dated the 1720 Bland quartz dioriteas discussed earlier. In the area of the 1699 Ma Crazy Basin Quartz Monzonite the verticalfabricand associated upright isoclinal folds (F2) of the Big Bug block are deflectedaroundthe northernterminousof the Crazy Basin Quartz Monzonite, and one macroscopic uprightfold (F2) is crosscut by an aplite which is similarin compositionand age (1700 Ma) to the nearby Crazy Basin Quartz Monzonite. This indicates thatthe recumbentfoldingand some of the uprightfolding of the Big Bug block took place before 1700 Ma. Further,the aplite and the Crazy Basin Quartz Monzonite are foliated, presumably by continued shortening(F2). The shorteningis therefore interpretedto have been broadly synchronouswith 1700 Ma emplacement of the Crazy Basin Monzonite. Sinistral strike-slipreactivation of the Shylock fault zone along the Cleator mylonite zone was progressivelyrelated to F2 shortening (Darrach 1988) and was also contemporaneous with 1700 Ma plutonismas shown by en echelon vein arrays filledwith Crazy Basin Quartz Monzonite that are compatible with sinistral strike-slip movement. Metamorphism post-dated the major shortening (F2) deformationin the Crazy Basin area and reached temperatures of about 550°C and pressures of 3.7 kb, as recorded by garnetbiotite geothermometryand garnet zoning profiles (Michael Williams pers. comm. 1987). The Crazy Basin Quartz Monzonite contains muscovite, biotite, and garnet, an assemblage that suggests the batholithcrystallized at pressures in excess of 2-3 kb (Miller 1985). Distinctive features of the Big Bug block include the following: (1) The supracrustal rocks of the Big Bug Group (1755-1740 Ma) are youngerthan the Ash Creek Group (1790 Ma). (2) The deformationalhistoryinvolved northwestverging recumbentfolds (F1) and thrustsoverprinted by tight-to-isoclinaluprightfolds (F2). The resultingfabricis characterizedby northeast-trending subverticalfoliation with subvertical stretchinglineation rotated to a northerlystrikewithinthe Shylock faultzone. (3) F1 recumbentfoldingwas post-1750Ma, and F2 shorteningwas at 1700 Ma. (4) The Crazy Basin Quartz Monzonite is a strongly peraluminous early Proterozoic batholiththatwas intrudedat depthsof 10-15 km into a crust undergoingductile deformation at 5500C and 3.7 kb at 1700 Ma. Chaparral Fault.-The Chaparral fault (Anderson and Creasey 1958) is a 2 km wide vertical shear zone that trends northeast, parallel to vertical foliation in the Big Bug block. It contains well-developed shallowlyplunging stretchinglineation and abundant kinematicevidence fora major componentof dextral strike-slipmovement. Movement on the zone post-dated intrusionof the 1735 Ma Crooks Canyon Granodiorite.North-trending foliationin the Green Gulch Volcanics north of the Chaparral faultbecomes progressively of the fault deflectedinto the northeast-trend demonstratingin excess of 3-5 km dextral strike-slipbased on shear strains calculated by measuring deflection of foliation trajectories (c.f. Ramsey and Huber 1983). Green Gulch Block.-Yavapai Supergroup rocks immediatelynorthwestof the Chaparral fault were named the Green Gulch Volcanics of the Big Bug Group by Anderson et al. (1971). There are no published isotopic ages on the supracrustal rocks, but they are intrudedby 1740 Ma granodioritesand were believed by Anderson et al. (1971) to be older than the volcanics exposed in the Big Bug block, based on stratigraphicarguments.Deformationof the Green Gulch Volcanics is reportedby Krieger (1965) to be pre- to synintrusion of the 1740 Government Canyon granodiorite. Tectonic history of the Green This content downloaded from 129.24.37.22 on Mon, 6 Oct 2014 18:24:18 PM All use subject to JSTOR Terms and Conditions ASSEMBLY OF TECTONOSTRATIGRAPHIC 567 TERRANES 0 0 km Present surface 25 25 km 50 0 50 50 100 NW blocks deformed 1700 Mo and metamorphosed calc-alkaline at ca. 1700 Mo plutons post-deformationaol NW blocks 1700 Mo strongly SE blocks deformed plutons, 1650-1630 deformed peraluminous pre-1740 Mo pluton 1690-1630 Ma and 1400 Ma Thrusts Strike-slip foults FIG. 3.-Schematic NW-SE cross-section throughthe TransitionZone of Arizona showing minimum complexityof assembled blocks. At least three major terranesseem to be required by data on timingof deformation. Gulch Volcanics appears to be similarto the Ash Creek Group, as indicated by the northwest trendof foliationin both blocks, similar metamorphic grade, similar compositions and ages of plutonic rocks (Krieger 1965), and similar timingof deformation(pre-1740 Ma). We suggest that these two blocks may be part of the same terranethatis folded into a crustal-scale antiformcored by the Big Bug block, as shown schematically in figure3. Siliciclastic sedimentary rocks that are similarin lithologyto the Mazatzal Quartzite of the southeastern province occur in one small outcrop in the Green Gulch block. These rocks are very low-grade(theycontain pyrophyllite,kaolinite, and other clay minerals) and not penetratively deformed, in marked contrast with volcanic and granitic rocks nearby. The lower contact of the quartzite is not exposed, so the relationshipbetween the quartzite and the underlyingunits is in doubt (Karlstrom et al. 1987). If these rocks do indeed correlate with the Mazatzal Group-as all workers have proposed-they represent a link between the southeastern and northwesternprovinces. This link could be stratigraphicor tectonic, an angular unconformityor a thrust. volcanic Hualapai-Bagdad Block.-The and volcaniclastic rocks in the Bagdad area have been correlatedwiththe Yavapai Supergroup (Anderson et al. 1955), although rhyolitic rocks that are interstratified with mafic volcanic rocks yield ages of 1709 Ma, younger than any rocks known in the Yavapai Supergroupto the southeast. Published dates fromgranitesin this area range from1720 Ma to 1696 Ma, and deformationappears to be bracketed between 1706 and 1696 Ma, the ages of stronglyfoliatedplutonic rocks and a syn- to post-deformationalgranite, respectively(Bryantand Wooden 1986). The timing of deformationis thus similar to that of the Big Bug block. In the western Hualapai Mountains, Stensrudand More (1980) described a sequence of supracrustalrocks thatincludes amphibolites and pelitic schists intrudedby several types of graniticintrusives.The metamorphicgrade is reported to be upper amphibolite facies, which may be compatible with either a general increase in metamorphic grade to the northwestin the Hualapai-Bagdad block or withthe presence of several distinctblocks. Graniticrocks make up the western Hualapai plutoniccomplex (Stensrud and More 1980), a northwest-trending80 km long belt of granodioriteplutons which may be a distinctive feature of the Hualapai-Bagdad block. New U-Pb zircon dates on several plutons in the western Hualapai Mountains range between 1660 and 1730 Ma (Chamberlain et al. 1988). The Majave Block.-Early Proterozoic rocks in the Mojave desert occur within rangesof the Basin and Range province. The geologic historyof these uplifts is complex and generally involves Mesozoic compression followed by ductile and brittleTertiary extensional tectonism. Although the Proterozoic historyin the Mojave is still incompletelyknown, it contains remnantsof 19002300 Ma supracrustal rocks, and isotopic evidence indicates that this area is a distinct tectonostratigraphicterrane relative to the rest of Arizona (Wooden et al. 1988). We in- This content downloaded from 129.24.37.22 on Mon, 6 Oct 2014 18:24:18 PM All use subject to JSTOR Terms and Conditions 568 KARL E. KARLSTROM AND SAMUEL A. BOWRING clude the Mojave block in the Yavapai Province because it experienced deformationand metamorphismat about 1700 Ma (Wooden et al. 1988). Isotopic Data.-Sm-Nd and Pb isotopic data suggest the presence of a boundary (fig. 1) thatis subparallel to the California-Arizona border. Rocks west of this boundary have high Nd/Sm ratios that require mixing of a significantcomponent of older crustal material duringcrustalformationat 1800-1700 Ma (Bennett and DePaolo 1987). In contrast, rocks in Arizona east of this boundary have low Nd/Sm ratios that are consistent with derivationofjuvenile early Proterozoic crust from a MORB-like mantle source at 18001700 Ma. In addition, Mojave rocks have a more radiogenic Pb isotope signature than Arizona rocks (Wooden et al. 1987; 1988). The higher Pb 207/206ratio in the Mojave seem to require either addition of Pb from Archean sources or from ca. 2.1 b.y. old crust. Mojave rocks also have lower Pb 206/ 204 ratios, which probably reflectthe higher regional metamorphic grade of Proterozoic rocks in the Mojave (highT, low P, granulite facies in the New York Mountains according to Elliott et al. 1986). MAZATZAL PROVINCE BLOCKS AND SHEAR ZONES The area southeast of the Moore Gulch faultis divided into threeblocks: the Mazatzal, Sunflower,and Pinal (fig.2). These areas expose predominantly1710-1690 Ma supracrustal rocks and associated hypabyssal intrusions. The nature of the basement to the supracrustal succession and hypabyssal intrusions is poorly known. Mazatzal Block.-The Mazatzal block is distinct from the northwesternblocks in termsof stratigraphy,style and timingof deformation, and metamorphic grade. Supracrustal rocks have been named the Tonto Basin Supergroup (Conway et al. 1987),whichis divided into three groups: Alder, Red Rock, and Mazatzal. This sequence is intrudedby penecontemporaneous shallow level granites and granophyrescalled the Diamond Rim IntrusiveSuite (Conway et al. 1987). Rocks that may be part of the basement to the Tonto Basin Supergroup include the Gibson Creek batholith, a 1738 Ma calc-alkaline gabbrodiorite complex, metasedimentaryand metavolcanic rocks found as screens in the batho- lith, and sedimentary packages that may correlate with the screens, for example the East Verde River Formation (Conway and Wrucke 1986). However, the lower Alder Group has not been found in depositional contact with older basement rocks. The lower Alder Group is up to several kilometersthick and contains pillow basalts, graywacke, small exhalative sulfidedeposits, and slates. This sequence is widespread and presumablyrecords marine sedimentationin arc-related basins. Upper Alder rocks consists of several kilometers of slates, lithic arenites, intermediate-to-felsicpyroclastic rocks, quartzarenite,and rhyolite.Upper Alder Group felsic pyroclastic rocks have been dated at 1710-1700 Ma and thus appear to overlap in age the overlyingRed Rock Group rhyolites. The Red Rock Group is dominated by alkaline highsilica rhyoliticash flowtuffs,rhyolitic lava flows, and related hypabyssal intrusives that range in age from 1703-1692 Ma. This group is several kilometers thick locally, has a volume of several thousand cubic kilometersregionally,and has been interpretedto record caldera-related rhyolitic volcanism analogous to Yellowstone or the Basin and Range province (Conway 1976; Conway and Silver 1984). Red Rock Group volcanism gave way to fluvial and shallow marinesiliciclastic sedimentationin the Mazatzal Group. The Mazatzal Group is 1-2 km thick and generally disconformablyoverlies the Red Rock Group. This sequence has been interpretedto be part of a regionallyextensive miogeoclinal sand blanket (Trevena 1979). Dated sills and domes of rhyoliteintrudethe lower Mazatzal Group and indicate thatsiliclasticsedimentationimmediatelyfollowed and overlapped in time with rhyolitic volcanism. The structuralstyle in the Mazatzal block is that of a shallow-level foreland fold and thrust belt. Major thrusts have ramp-flat geometries with duplex systems. Folds of three major types characterize the Mazatzal block; all are related to the northwestdirectedthrusting:(1) fault-bendfolds above ramps are seen at mesoscopic to macroscopic scales; (2) large-scale uprightfolds above detachmentsare associated with shorteningdue to tectonic wedging; and (3) northwestvergingasymmetricalfolds occur associated This content downloaded from 129.24.37.22 on Mon, 6 Oct 2014 18:24:18 PM All use subject to JSTOR Terms and Conditions ASSEMBLY OF TECTONOSTRATIGRAPHIC with thrusts in less competent units. The thrustingin the Tonto Basin Supergroupis of regionalextent. Puls (1986) estimatedgreater than 50% (>18 km) shorteningin one area of the northern Mazatzal Mountains on the basis of a restoredcross section of the Mazatzal thrustsystem, which consists of a roof thrustabove a duplex system. This estimate of thrust transport, as well as observed geometries,necessitates that all of the Tonto Basin Supergroupin the southeasternpart of the Mazatzal block is allochthonous relative to the northwestpart of the block (fig.2). The Gibson Creek batholith(1738 Ma) also is involved in thrusting(Conway 1976), so if thisis a portionof the basement on whichthe Tonto Basin Supergroup was deposited, the basement and cover are intimatelyshuffled. Thrustingtook place between 1692 and 1630 Ma, the youngest rocks involved in thrusting and the age of the Young Granite respectively. The Young Granite intrudesthe Alder Group south of the Slate Creek shear zone and is reported to be syn- or postdeformational(Conway and Silver 1988). Rocks exposed in the Mazatzal block are of low metamorphicgrade. Kaolinite is present in argilliticquartzites, and pyrophylliteis observed at slightlydeeper levels in slates. Xray data on dioctahedral illite shows about 90% ordered (2 m) polymorph, suggestingT of 200-3500C (Maxwell and Hower 1967). This is compatible with fluid inclusions in syntaxial quartz fibersalong thrustsurfaces that have homogenization temperatures of less than 2500C. These conditions and the predominance of pressure solution as the dominant deformationmechanism, are consistentwith shallow crustal conditionsduring deformationand metamorphism. The Mazatzal block is distinct from the Ash Creek block in the following ways: (1) The distinctive1700 Ma supracrustalpackage and alkalic granitesof the Mazatzal block terminateabruptlyat the Moore Gulch fault.(2) The Mazatzal block was deformed between 1692 and 1630 Ma at low metamorphicgrade, whereas the Ash Creek block records pre1740 and 1700 Ma deformations at higher metamorphicgrades. (3) The two blocks have distinctlydifferentmetalogenic characteristics, as discussed by Titley (1987). Slate Creek Movement Zone.-The Slate Creek movement zone is an east-northeast TERRANES 569 strikingnetwork of shear zones up to 5 km wide thatseparates the Sunflowerand Mazatzal blocks. It is exposed fora strikedistance of 40 km and may be extended to coincide with the Holbrook lineament, a magnetic (Sauck and Sumner 1970) and gravity (Lysonski et al. 1980) lineamentof the Colorado Plateau (fig. 1). The movement history includes south-side up (and sinistral) oblique slip (fig. 2) followed by shorteningacross conjugate but predominantlydextral shear bands (Roller 1987). Early south-side up movementsare interpretedto be temporally and kinematicallyrelated to the thrustingin the Mazatzal block, and cross sections suggest that the movement zone in part reflects above a ramp in the regional decolflattening lement(see Conway et al. 1987). Large southside-up displacements across the zone are suggestedby very high strainsand by higher grade metamorphicrocks south of the movementzone. Sunflower Block.-The Sunflower block contains a supracrustal package of rhyolite and quartz arenite that is similar to the Mazatzal block but is distinguishedby a generally higher grade of metamorphism.The Sunflower block also contains a suite of 1640-1630 Ma graniticintrusivesthatare unknown north of the Slate Creek movement zone. Supracrustal rocks make up only a small percentage of the exposed Sunflower block relative to granites (both 1640-1630 and 1400 Ma granites). Metamorphic grade is highersouth of the Slate Creek movement zone, suggestinggenerallydeeper crustal levels than are exposed in the Mazatzal block. At Four Peaks, andalusite and sillimanite coexist in pelitic metasedimentary rocks. In the McDowell Mountains near Phoenix, Couch (1981) reportedkyanite,sillimanite,and K-feldsparin peliticrocks. These assemblages, along with garnet-biotitegeothermometry,were interpreted by Couch (1981) to record an early regional metamorphismwith T=350-450°C and P= 4-6 kb, followed by "contact metamorphism" with T= 550-580°C and P=3-3.7 kb. Assemblages found on Squaw Peak, in Phoenix, contain Mn-andalusite,kyanite, staurolite, and chloritoid(Thorpe and Burt 1978) similar to regional metamorphic assemblages seen in New Mexico which representpeak conditions of T= 5000C, P= 4 kb This content downloaded from 129.24.37.22 on Mon, 6 Oct 2014 18:24:18 PM All use subject to JSTOR Terms and Conditions 570 KARL E. KARLSTROM AND SAMUEL A. BOWRING (Grambling 1986). All of these amphibolite assemblages in the Sunflower block have been interpretedto be the productsof contact metamorphism.However, the highpressures indicate depths of 10-20 km at least in some areas of the Sunflower block and, at Four Peaks for instance, the effect of contact metamorphismaround the 1400 Ma granite appears to be retrogressive. The higher metamorphic grades and the presence of 1640-1630 granitoids in the Sunflowerblock both suggest differentcrustal levels and/or differentlithospheric sections for the two blocks. The southern boundary of the Sunflower block is unknown but is shown (dashed) in figure1 south of the southernmostoutcrops that have been correlated with the Mazatzal Group and north of the northernmostoutcrops of Pinal Schist. Voluminous 1400 Ma post-tectonicgranitesare exposed in thisarea and conceal the boundary. Pinal Block.-The Pinal block differsfrom the othersoutheasternblocks in thecharacter of its supracrustalpackage. Outcrops of Proterozoic rocks in southeasternArizona have traditionallybeen referred to as the Pinal Schist (Ransome 1903, 1905; Cooper and Silver 1964; Silver 1978). Condie and DeMalas (1985) and Copeland and Condie (1986) have proposed that this area can be divided into two assemblages with differentpetrologic and geochemical characteristics, a western assemblage of quartz wacke turbiditesand an easternassemblage of basalt, rhyolite,and diverse metasedimentaryrocks (fig. 1). Their proposed boundary between assemblages strikesnorthwest,perpendicularto the trend of foliation, folds, and faults in the Pinal Schist and to the trend of the shear zones discussed above. The western assemblage contains quartz wacke turbiditesthatare uniformin composition over a wide area, and minorbasalt and rhyolite. Widely-scattered outcrops occur over an area of several thousand square kilometers, and some workers have interpreted this to represent a large basin filled submarinefans. However, withinterfingering thereis no evidence that the turbiditeswere deposited in the same basin or at the same time (Swift 1987). U-Pb zircon ages for the Pinal block are few. Silver (1978) reported an age of 1680- 1700 Ma for rhyodacite sills that intrudeturbidites and basalts in the JohnnyLyon Hills. These sills were intrudedbefore the end of deformationand metamorphism,and Cooper and Silver (1968) interpretedthe sills to be entirelypretectonic. In contrast,Swiftinterpretedthemto be broadly syntectonic,noting the presence of a xenolithof stronglyfoliated basalt within less-foliated rhyodacite. The 1625 Ma JohnnyLyon Granodioritehas been interpretedto be late syn-kinematicto postkinematic(Cooper and Silver 1964) because it crosscuts foliated rocks of the Pinal Schist and is itself generally unfoliated. However, one body, identifiedas JohnnyLyon Granodiorite by Cooper and Silver (1964), is foliated with foliationtruncatedby flatlying Middle Proterozoic Apache Group sedimentaryrocks. This suggeststhatsome earlyProterozoic deformationmay have affectedthe JohnnyLyon Granodiorite. Correlation of the Pinal Schist with rocks of the lower Alder Group of the Tonto Basin Supergroup has been proposed by Conway and Silver (1986; 1988) who suggest that the turbiditesreflecta facies change to more distal parts of a large successor basin. A gradual transitionfromone package to the other has not been documented, and our view is that this correlation is not supported by existing data. TECTONIC LINKAGES BETWEEN BLOCKS The identification of tectonic blocks bounded by major shear zones and having one or more distincttectonicfeaturesrelative to adjacent blocks is a firststep in identifying the architecture of an orogenic belt. The next, and necessarily more interpretive,step is to attempt to identifylinkages between blocks and therebyidentifythe geometryand timingof assembly of terranesthat may represent once separate lithospheric plates or microplates. Figure 3 is a schematic cross section of a possible post-collisional geometryof juxtaposed terranes. In this cross section, we suggest that the eight blocks described earlier can be grouped into three major terraneson the basis of timingof deformation in the various blocks. This cross section is almost certainlyan oversimplification because each of the three terranes may be composites of one or more microplates. However, by using timingof deformation,we This content downloaded from 129.24.37.22 on Mon, 6 Oct 2014 18:24:18 PM All use subject to JSTOR Terms and Conditions ASSEMBLY OF TECTONOSTRATIGRAPHIC present a new criterionfor evaluating linkages between terranes that can be combined withstratigraphic, petrologic,and geochronologic data. Three blocks of the Yavapai Province, the Mojave, Hualapai-Bagdad, and Big Bug blocks (figs. 1, 3) show broadly similartiming and styles of deformationand metamorphism about 1700 Ma. There are certainlymajor differences between these blocks, including very old supracrustal rocks (2300-1900 Ma) and distinctiveNd and Pb isotopic signatures in the Mojave and parts of the HualapaiBagdad blocks relative to central Arizona, and younger supracrustal rocks (1710 Ma) in the Hualapai-Bagdad block relativeto the Big Bug block (1755 Ma). These and otherdifferences suggest the probabilityof distinctpre1700 Ma tectonic histories for these blocks. However, these blocks were apparently in close enough proximityto have been affected by the same 1700 Ma tectonic event; they were apparently becoming part of a single large terraneby about 1700 Ma. The other two northwesternblocks, the Ash Creek and Green Gulch blocks, were deformedbefore 1740 Ma but show no evidence of penetrative deformationat 1700 Ma, except withinthe bounding faultzones, and no evidence for the voluminous ca. 1700 Ma granitic plutonism that affected the other northwestern blocks. Figure 3 tentatively suggeststhatthe Ash Creek and Green Gulch blocks were part of a singleterrane,now antiformallyfolded across the Big Bug block. Transpressional convergence across the Shylock fault and the nearly synchronouspenetrative deformationin the far northwestern province could both have been driven by 1700 Ma collision of the Ash Creek-Green Gulch terrane with other Yavapai Province blocks. The absence of penetrative1700 Ma deformation in the Ash Creek and Green Gulch blocks could be explained if these blocks were part of an upper plate during thrust-relatedconvergence (fig. 3). Blocks of the Mazatzal Province were deformedbetween 1692 and 1630 Ma, afterthe composite Yavapai Province was assembled by collision of two or more terranesat about 1700 Ma. Informationon timingof deformation in the Mazatzal Province is not yet detailed enough to evaluate whether these blocks are all part of one terranethatcollided TERRANES 571 with the Yavapai Province, or whether the Mazatzal Province is itselfa composite of terranes. At present,the tentativecorrelationof quartzites and rhyolitesblock to block suggests a single terrane (Conway and Silver 1988), whereas highermetamorphicgrades in the Sunflower block, an absence of 16401630 granites in the Mazatzal block, and thick turbiditepackages in the Pinal block all may suggest that differentterranes may be presented. The presence of syn- to postdeformational1640-1630 granitesin both the Sunflower and Pinal blocks suggests that these blocks were togetheror in close proximityat 1640-1630 Ma. The designationof three terranesbased on timingof deformationshown in figure3 is tentative and needs to continue to be evaluated in termsof analysis of possible stratigraphic and petrologic linkages between blocks. Stratigraphicand petrologiclinkages between the Yavapai and Mazatzal Provinces have been proposed by various workers (e.g., Anderson 1986; model one of Karlstrom et al. 1987; Conway and Silver 1988). For example, the 1738 Ma Gibson Creek batholith of the Mazatzal block is the same age and is similar to the Cherry batholith of the Ash Creek block, and neitheris penetrativelydeformed. Consequently,these plutonicrocks may have been a continuous basement for deposition of the rhyolite-quartzitesuccession of the Mazatzal block. However, this interpretation is difficultto reconcile with data that suggest that at the same time that these 1700 Ma quartzitesand rhyoliteswere being deposited in the Mazatzal block, the Ash Creek block was undergoing deformationat its margins and the 1700 Ma strongly peraluminous Crazy Basin Quartz Monzonite was being emplaced duringcompressional deformation at 10-15 km depths. Syntectonic deposition of the rhyolitequartzite succession of the Tonto Basin Supergroup may be compatible with the interpretationof Middleton (1986) that conglomerates in the Mazatzal Group outcrops of the Green Gulch block are syntectonic fluvialdeposits. However, it is inconsistent with the other interpretationsthat the rhyolite-quartzitesuccession is related to fluvial to shallow marineplatformsedimentation (Trevena 1979; Conway and Silver 1984). Further,it seems difficultto reconcile with This content downloaded from 129.24.37.22 on Mon, 6 Oct 2014 18:24:18 PM All use subject to JSTOR Terms and Conditions 572 KARL E. KARLSTROM AND SAMUEL A. BOWRING the absence of 1700 Ma plutonicrocks in the Ash Creek block thatwould representequivalents of the extensive 1700 Ma rhyolitic plutonism and volcanism in the Mazatzal block and it ignoresthe differencein timingof deformationbetween the provinces. One way to evaluate proposed linkagesand the magnitudeof displacementsbetween terranes is to assess the compatibilityof inferred tectonic and structuralevolution. The apparent diversityof tectonic regimes at 1700 Ma in centralArizona suggeststo us thatthe proposed terraneswere at distances greaterthan 100's of km fromone another, prior to their juxtaposition. This interpretation more easily explains the extremelydiverse 1700 Ma tectonic events such as: (1) calc-alkaline plutonism in the northwest;(2) ductile deformation and metamorphism in the northwest; (3) stronglyperaluminousgraniticmagmatismin the Big Bug block; (4) extrusion of calderarelated alkaline rhyolitesfollowed shortlyby deposition of maturesiliciclasticsedimentsin the Mazatzal and Sunflowerblocks; and (5) deposition of turbiditesin the Pinal block (fig. 3). Using the Indonesian or Caribbean regions as actualistic models, such complexities are easily explained in termsof separate terranes that become incorporated into an orogenic collage. This interpretationalso readily explains the absence of systematic cross-strikechanges in age of magmaticrocks and age and style of deformationand metamorphism. ASSEMBLY OF OROGENIC PROVINCES Our workinghypothesis is that early Proterozoic rocks in Arizona representdiverse tectonostratigraphicterranes that were assembled during several episodes of convergent tectonism. This is in contrastto earlier interpretations.Wilson (1939) proposed the term "Mazatzal Revolution" for a profound compressional disturbance that post-dated deposition of the Mazatzal Group and affected all the older Precambrian rocks of Arizona. Althoughdisputed by Hinds (1938), Wilson and most subsequent workers have believed that early Proterozoic rocks in Arizona have been affected by one major Proterozoic orogenic event, and most workers have used the termMazatzal orogenyfor this event (Silver 1978). Conway and Silver (1988) give age brackets of 1680-1630 Ma for this orogeny. Evidence for pre-1740 and 1700 Ma deformations in northwestern Arizona demonstratesmultipletectonic events and raises the question of how to apply the termMazatzal orogeny. We agree with Conway and Silver (1988) thatthe termMazatzal orogenyshould be used for the post-1690 Ma compressional deformationin the southeastern blocks. We interpretthis deformationto be the resultof collision of the Mazatzal Province blocks withthe previouslyassembled Yavapai Province. However, this tectonic interpretation need not be implicitin use of the termMazatzal orogeny. The termMazatzal orogeny should probably not be used for deformation of the Yavapai Province, which was apparently older and of ductile character. Using figures2 and 3 as guides, it seems reasonable to define a major 1700 Ma orogeny in Arizona thatresulted from the assembly of northwestern blocks. Pre-1740 Ma deformationin the Ash Creek and Green Gulch blocks represents stillearlier tectonic events. It seems inescapable that the tectonic events that produced deformationand metamorphism in Arizona also affected other areas of southwesternNorth America. Deformation in New Mexico involved thrusting and recumbentfolding at amphibolitefacies conditions. The intense late stages of deformation in New Mexico in part post-dated 1650 Ma (Bowring et al. 1983). Deformation of cover rocks in the Needle Mountains of southernColorado took place between 1680 and 1430 Ma (Tewksbury 1985; Harris et al. 1987; Gibson and Simpson 1988) and involved regional compression and strike-slip faulting.Both the timingand style of these deformations may be compatible with the southeastern province of Arizona, and the termMazatzal orogeny may be applicable to regional post-1690 Ma early Proterozoic deformationin the Southwest. Earlier deformationsat 1700 and pre-1740 may also have affected a larger region, althoughthis will require much more detailed data on timingof deformations.In the Needle Mountains of southern Colorado, Harris et al. (1987) and Gibson and Simpson (1988), followingBarker (1969), suggested that the Uncompahgre Group was deposited uncon- This content downloaded from 129.24.37.22 on Mon, 6 Oct 2014 18:24:18 PM All use subject to JSTOR Terms and Conditions ASSEMBLY OF TECTONOSTRATIGRAPHIC formablyon a gneissic basement thatwas deformedbefore intrusionof 1690 Ma granites. In other areas of southern Colorado, deformation and metamorphismreportedly took place 1730-1714 Ma (Bickfordand Boardman 1984; Reed 1986). Farthernorth,Reed (1986) reported deformationin the Sawatch Range 1670-1658 Ma; deformation in the central Front Range post-1700 Ma; and deformation in the northernFront Range at 1710 Ma. Along the Cheyenne belt, Duebendorfer and Houston (1987) reported that thrust-related deformationtook place before 1750 Ma. It should be noted that interpretationof timingof deformationin most of these areas involves evaluation of the pre-, syn-,or postkinematic character of datable plutonic rocks. Such evaluations are not straightforward, as plutonicrocks have markedlydifferent material properties than their country rock, and diapiric emplacementof plutonsoften imparts strains on country rocks and granitemarginsthat must be understood before the component of strainimpartedby regional deformationcan be evaluated. As a consequence, interpretationsof timingof deformation will need to be continually reevaluated with more detailed structuralstudies. It seems clear to us fromavailable data that REFERENCES ANDERSON,C. A.; BLACET,P. M.; SILVER,L. T.; and STERN, T. W., 1971, Revision of the Precambrian stratigraphyin the Prescott-Jerome area, Yavapai County,Arizona: U.S. Geol;. Survey Bull. 1324-6, p. 1-16. , and CREASEY,S. C., 1958, Geology and ore deposits of the Jerome area, Yavapai County, Arizona: U.S. Geol. Survey Prof. Paper 308, 185 p. ----; SCHOLZ,E. A.; and STROBELL,J. D., 1955, Geology and ore deposits of the Bagdad area, Yavapai County, Arizona: U.S. Geol. Survey Prof. Paper 278, 103 p. ANDERSON,P., 1986, Summary of the Proterozoic plate tectonic evolution of Arizona from 1900 to 1600 Ma, in BEATTY, B., and WILKINSON, P. A. K., eds., Frontiersin geology and ore deposits of Arizona and the Southwest: Arizona Geol. Soc. Digest, v. 16, p. 5-11. BARKER,F., 1969, Precambrian geology of the Needle Mountains, southwestern Colorado: U.S. Geol. Survey. Prof. Paper 644-1A, p. 1-33. BENNETT,V. C., and DEPAOLO, D. J., 1987, Proterozoic crustal history of the western United States as determined by neodymium isotopic TERRANES 573 the deformation history in Colorado and southernWyomingis complex and cannot be viewed in terms of progressive southward growthof the continent.This is in contrastto the interpretationof Reed et al. (1987). The tectonostratigraphic terrane model proposed here for Arizona suggests that complexities of assembly of the entire orogen fromWyomingto Mexico are likelyto be greatand correlationsof stratigraphicand tectonic events as well as tectonostratigraphicterranes and orogenic provinces, need to be made cautiously. Using actualistic models, it is reasonable to assume that there may have been tensofdiscrete tectonic events duringassembly of the 1300 km wide orogen in southwestern North America and there is certainlyno reason to believe that collisions of terranes would necessarily have preceded fromnorth to south. ACKNOWLEDGMENTS.-Researchhas been supported by National Science Foundation Grants EAR-8411998 and EAR-8509354, by donors of the Petroleum Research Fund of the American Chemical Society (PRF16199GB), and by the NorthernArizona UniversityOrganized Research Fund. We thank K. Eriksson, and J. Dann forhelpfulreviews of thispaper. CITED mapping: Geol. Soc. 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