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PowerPoint® Lecture Slide Presentation by Patty Bostwick-Taylor, Florence-Darlington Technical College Basic Chemistry 2 PART A Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Chp. 2 Vocabulary 1. Enzyme 2. Cholesterol 3. Glucose 4. Organic Compound 5. Inorganic Compound 6. Decomposition 7. Electron 8. Atomic # 9. Atomic Mass 10.Valence Shell 11.Elements 12.Atoms 13.Atomic Symbol 14.Proton 15.Neutron 16. Molecule 17. Compound 18. Ionic Bond 19. Covalent Bond 20. Hydrogen Bond 21. SynthesisReaction 22. Matter 23. Energy 24. Kinetic Energy 25. Potential Energy Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Matter and Energy  Matter—anything that occupies space and has mass (weight)  Energy—the ability to do work  Chemical  Electrical  Mechanical  Radiant Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Chemical Energy  Stored in the bonds of chemical substances  Broken bonds release (potential) energy and it becomes kinetic energy  Ex: gasoline molecules power you vehicle  Ex: Chemical energy from foods we eat power our body Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Electrical Energy  Results from movement of charged particles  Ex: electricity is from electrons flowing across wiring  Ex: Nervous system uses eletrical currents called nerve impulses to transmit messages throughout the body. Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Mechanical Energy  Energy directly involved in moving matter  Ex: riding a bike; your legs provide the mechanical energy that moves the pedals  Ex: muscles in you legs shorten, they pull on your bones, causing your limbs to move (allowing you to pedal the bike) Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Radiant Energy  Travels in waves  Ex: x-rays, infrared radiation, visible light, radio, ultraviolet waves, Sonar Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Composition of Matter  Elements—fundamental units of matter  96% of the body is made from four elements  Carbon (C)  Oxygen (O)  Hydrogen (H)  Nitrogen (N)  Atoms—building blocks of elements  Hydrogen – simplest atom Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Elements  Unique substances that cannot be broken down into smaller substances by ordinary methods  112 elements are know with certainty; 113-118 are alleged  92 of these elements occur naturally Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Atoms  Building blocks of elements  Comes from Greek word meaning “incapable of being divided”  3 subatomic particles  Protons – positive charge;  Neutrons – uncharged (Protons & electrons are heavy particles and have about the same mass)  Electrons – negative charge; (equal to the positive charge of protons) Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Atomic Structure  Nucleus  Protons (p+)  Neutrons (n0)  Outside of nucleus  Electrons (e-) Figure 2.1 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Identifying Elements  Atomic number—equal to the number of protons that the atom contains  Protons = # of electrons  Ex: An atom has 5 neutrons, 4 protons, and 4 electrons. Whats the atomic #.  Atomic mass number—sum of the protons and neutrons  Ex: An atom has 5 neutrons, 4 protons, and 4 electrons. Whats the atomic mass #. Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Planetary Model vs. Orbital model Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Atomic Structure of Smallest Atoms Figure 2.2 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Isotopes and Atomic Weight  Isotopes  Have the same number of protons  Vary in number of neutrons Figure 2.3 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Isotopes and Atomic Weight  Atomic weight  Close to mass number of most abundant isotope  Atomic weight reflects natural isotope variation Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Radioactivity  Radioisotope  Heavy isotope  Tends to be unstable  Decomposes to more stable isotope  Radioactivity—process of spontaneous atomic decay Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Molecules and Compounds  Molecule—two or more like atoms combined chemically  Compound—two or more different atoms combined chemically Figure 2.4 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Chemical Reactions  Atoms are united by chemical bonds  Atoms dissociate from other atoms when chemical bonds are broken Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Electrons and Bonding  Electrons occupy energy levels called electron shells  Electrons closest to the nucleus are most strongly attracted  Each shell has distinct properties  The number of electrons has an upper limit  Shells closest to the nucleus fill first Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Electrons and Bonding  Bonding involves interactions between electrons in the outer shell (valence shell)  Full valence shells do not form bonds Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Inert Elements  Atoms are stable (inert) when the outermost shell is complete  How to fill the atom’s shells  Shell 1 can hold a maximum of 2 electrons  Shell 2 can hold a maximum of 8 electrons  Shell 3 can hold a maximum of 18 electrons Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Inert Elements  Atoms will gain, lose, or share electrons to complete their outermost orbitals and reach a stable state  Rule of eights  Atoms are considered stable when their outermost orbital has 8 electrons  The exception to this rule of eights is Shell 1, which can only hold 2 electrons Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Inert Elements Figure 2.5a Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Reactive Elements  Valence shells are not full and are unstable  Tend to gain, lose, or share electrons  Allow for bond formation, which produces stable valence Figure 2.5b Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Chemical Bonds  Ionic bonds  Form when electrons are completely transferred from one atom to another  Ions  Charged particles  Anions are negative  Cations are positive  Either donate or accept electrons Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Ionic Bonds Na Cl Sodium atom (Na) (11p+; 12n0; 11e–) Chlorine atom (Cl) (17p+; 18n0; 17e–) + – Na Cl Sodium ion (Na+) Chloride ion (Cl–) Sodium chloride (NaCl) Figure 2.6 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Ionic Bonds Na Cl Sodium atom (Na) (11p+; 12n0; 11e–) Chlorine atom (Cl) (17p+; 18n0; 17e–) Figure 2.6, step 1 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Ionic Bonds Na Cl Sodium atom (Na) (11p+; 12n0; 11e–) Chlorine atom (Cl) (17p+; 18n0; 17e–) Figure 2.6, step 2 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Ionic Bonds Na Cl Sodium atom (Na) (11p+; 12n0; 11e–) Chlorine atom (Cl) (17p+; 18n0; 17e–) + – Na Cl Sodium ion (Na+) Chloride ion (Cl–) Sodium chloride (NaCl) Figure 2.6, step 3 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Chemical Bonds  Covalent bonds  Atoms become stable through shared electrons  Single covalent bonds share one pair of electrons  Double covalent bonds share two pairs of electrons Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Examples of Covalent Bonds Figure 2.7a Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Examples of Covalent Bonds Figure 2.7b Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Examples of Covalent Bonds Figure 2.7c Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Polarity  Covalently bonded molecules  Some are non-polar  Electrically neutral as a molecule  Some are polar  Have a positive and negative side Figure 2.8 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Chemical Bonds  Hydrogen bonds  Weak chemical bonds  Hydrogen is attracted to the negative portion of polar molecule  Provides attraction between molecules Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Hydrogen Bonds Figure 2.9 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Patterns of Chemical Reactions  Synthesis reaction (A + BAB)  Atoms or molecules combine to form larger ones  Energy is absorbed for bond formation (energy absorbing reactions)  Decomposition reaction (ABA + B)  Molecule is broken down  Chemical energy is released  Ex: digestion of food Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Synthesis and Decomposition Reactions Figure 2.10a Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Synthesis and Decomposition Reactions Figure 2.10b Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Patterns of Chemical Reactions  Exchange reaction (AB + CAC + B)  Involves both synthesis and decomposition reactions  Switch is made between molecule parts and different molecules are made Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Patterns of Chemical Reactions Figure 2.10c Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings