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PowerPoint® Lecture Slide Presentation by Patty Bostwick-Taylor, Florence-Darlington Technical College Basic Chemistry 2 PART A Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Matter  Biochemistry- the specialized area of chemistry that deals with living organisms and life processes  Matter—anything that occupies space and has mass (weight) Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Energy  Energy—the ability to do work or put matter in motion  Kinetic- when energy is doing work, moving objects  Potential- when energy is inactive or stored Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Energy  Forms of Energy  Chemical- stored in bonds  Electrical- results from movement of charged particles  Mechanical- energy directly involved in moving matter  Radiant- travels in waves  X-ray  Infrared  Radio waves  heat Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Composition of Matter  Elements—fundamental units of matter  96% of the body is made from four elements  Carbon (C)  Oxygen (O)  Hydrogen (H)  Nitrogen (N)  Others present in trace amounts  Atoms—building blocks of elements Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Atomic Structure  Nucleus  Protons (p+)  Neutrons (n0)  Outside of nucleus  Electrons (e-) Figure 2.1 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Atomic Structure of Smallest Atoms Figure 2.2 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Identifying Elements  Atomic number—equal to the number of protons that the atom contains  Indirectly related to the number of electrons  Atomic mass number—sum of the protons and neutrons  Only nucleus has mass Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Isotopes and Atomic Weight  Isotopes  Have the same number of protons  Vary in number of neutrons Figure 2.3 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Isotopes and Atomic Weight  Atomic weight  Close to mass number of most abundant isotope  Atomic weight reflects natural isotope variation Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Radioactivity  Radioisotope  Heavy isotope  Tends to be unstable  Decomposes to more stable isotope  Radioactivity—process of spontaneous atomic decay  When we are exposed to radiation it knocks electrons out of their shell and may kill the cell  Alpha radiation is the weakest  Gamma radiation is the strongest Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Molecules and Compounds  Molecule—two or more like atoms combined chemically  Compound—two or more different atoms combined chemically Figure 2.4 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Chemical Reactions  Atoms are united by chemical bonds  Atoms dissociate from other atoms when chemical bonds are broken Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Electrons and Bonding  Electrons occupy energy levels called electron shells  Electrons closest to the nucleus are most strongly attracted  Each shell has distinct properties  The number of electrons has an upper limit  Shells closest to the nucleus fill first Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Electrons and Bonding  Bonding involves interactions between electrons in the outer shell (valence shell)  Full valence shells do not form bonds Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Inert Elements  Atoms are stable (inert) when the outermost shell is complete  How to fill the atom’s shells  Shell 1 can hold a maximum of 2 electrons  Shell 2 can hold a maximum of 8 electrons  Shell 3 can hold a maximum of 18 electrons Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Inert Elements  Atoms will gain, lose, or share electrons to complete their outermost orbitals and reach a stable state  Rule of eights or octet rule  Atoms are considered stable when their outermost orbital has 8 electrons  The exception to this rule of eights is Shell 1, which can only hold 2 electrons Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Inert Elements Figure 2.5a Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Reactive Elements  Valence shells are not full and are unstable  Tend to gain, lose, or share electrons  Allow for bond formation, which produces stable valence Figure 2.5b Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Chemical Bonds  Ionic bonds  Form when electrons are completely transferred from one atom to another  Ions  Charged particles  Anions are negative  Cations are positive  Either donate or accept electrons PLAY Ionic Bonds Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Ionic Bonds Na Cl Sodium atom (Na) (11p+; 12n0; 11e–) Chlorine atom (Cl) (17p+; 18n0; 17e–) + – Na Cl Sodium ion (Na+) Chloride ion (Cl–) Sodium chloride (NaCl) Figure 2.6 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Ionic Bonds Na Cl Sodium atom (Na) (11p+; 12n0; 11e–) Chlorine atom (Cl) (17p+; 18n0; 17e–) Figure 2.6, step 1 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Ionic Bonds Na Cl Sodium atom (Na) (11p+; 12n0; 11e–) Chlorine atom (Cl) (17p+; 18n0; 17e–) Figure 2.6, step 2 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Ionic Bonds Na Cl Sodium atom (Na) (11p+; 12n0; 11e–) Chlorine atom (Cl) (17p+; 18n0; 17e–) + – Na Cl Sodium ion (Na+) Chloride ion (Cl–) Sodium chloride (NaCl) Figure 2.6, step 3 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Chemical Bonds  Covalent bonds  Atoms become stable through shared electrons  Single covalent bonds share one pair of electrons  Double covalent bonds share two pairs of electrons PLAY Covalent Bonds Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Examples of Covalent Bonds Figure 2.7a Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Examples of Covalent Bonds Figure 2.7b Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Examples of Covalent Bonds Figure 2.7c Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Polarity  Covalently bonded molecules  Some are non-polar  Electrically neutral as a molecule  Some are polar  Have a positive and negative side Figure 2.8 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Chemical Bonds  Hydrogen bonds  Weak chemical bonds  Hydrogen is attracted to the negative portion of polar molecule  Provides attraction between molecules  Causes surface tension property of water and allows water to change states easily Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Hydrogen Bonds Figure 2.9 Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Patterns of Chemical Reactions  Synthesis reaction (A + BAB)  Atoms or molecules combine  Energy is absorbed for bond formation  Decomposition reaction (ABA + B)  Molecule is broken down  Chemical energy is released Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Synthesis and Decomposition Reactions Figure 2.10a Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Synthesis and Decomposition Reactions Figure 2.10b Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Patterns of Chemical Reactions  Exchange reaction (AB + CAC + B)  Involves both synthesis and decomposition reactions  Switch is made between molecule parts and different molecules are made Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings Patterns of Chemical Reactions Figure 2.10c Copyright © 2009 Pearson Education, Inc., publishing as Benjamin Cummings
 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
                                             
                                             
                                             
                                             
                                             
                                             
                                             
                                             
                                             
                                            