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Transcript
Gilbert
Kirss
Foster
Chapter 2
Big Bang Theory
Big Bang Theory
β€’ Theoretical physicists believe that
the universe began 13.7 billion
years ago with an enormous
release of energy
β€’ All of the mass of the universe was
compressed into one infinitely
dense mass, which exploded and
expanded
β€’ Within milliseconds, energy
converted to matter, which formed
subatomic particles.
© 2014 W. W. Norton Co., Inc.
Big Bang Theory
β€’ Within 4 minutes, the universe had expanded and cooled to 109
K. Neutrons and protons collided and fused to form deuterium,
2
1𝐻
β€’ When all of the free neutrons were consumed, deuterium atoms
underwent fusion to form Helium:
2
1𝐻
© 2014 W. W. Norton Co., Inc.
+ 21𝐻 β†’ 42𝐻𝑒
Big Bang Theory
β€’ Most of the matter in the universe today is still hydrogen and
helium, which supports the theory, but how did other elements
form?
β€’ As the universe cooled further, the particles slowed, allowing
electrons to combine with the nuclei to produce neutral atoms
© 2014 W. W. Norton Co., Inc.
Big Bang Theory
β€’ Large masses of hydrogen and helium formed the first stars.
Energy released from the fusion fuels the stars.
β€’ Inside stars, 4He would fuse to create 12C, which fused with other
4He to produce 16O, which fused with other 4He to produce 20Ne,
and so on…… until 56Fe forms
β€’ Once a star produces iron, the star is near death, because the
formation of iron does not release energy…it consumes it. Thus,
a star with an iron core has run out of fuel.
© 2014 W. W. Norton Co., Inc.
Big Bang Theory
β€’ The mass of a stable nucleus is always less than the sum of the
separate masses of the subatomic particles. For example,
consider 4He
2 neutrons + 2 protons = 6.69510 x 10-27 kg
Actual mass of 4He nucleus = 6.64466 x 10-27 kg
Difference = 0.05044 x 10-27 kg
β€’ This difference is called the mass defect, Ξ”m. This β€œmissing”
mass is converted to energy according to E =Ξ”mc2. Some of this
excess energy is used to hold the nucleus together, so it is called
the binding energy, or mass energy.
β€’ Takes significant energy to counteract the repulsion of
protons in the nucleus
© 2014 W. W. Norton Co., Inc.
Big Bang Theory
© 2014 W. W. Norton Co., Inc.
Big Bang Theory
β€’ A collapsing star is hot enough to disintegrate nuclei and
produce free neutrons. Trans-iron elements can form by
successive neutron capture. Ex: formation of Co
56
26𝐹𝑒
+
3 10𝑛
β†’
59
26𝐹𝑒
Ξ²
β†’
59
27πΆπ‘œ
+ βˆ’10𝑒
β€’ The eventual explosion of the star leads to the dispersion of the
elements across the universe. All matter in the solar system is
star debris.
© 2014 W. W. Norton Co., Inc.
Artificial Nuclides
β€’ Following the gold foil experiment, scientist began bombarding
elements with alpha particles to artificially create isotopes. The
first radionuclide not found in nature was 30P, created in 1933
27
13𝐴𝑙
+ 42𝐻𝑒 β†’
30
15𝑃
+ 10𝑛
β€’ Trans-uranium elements are obtained by a combination of
neutron capture and Ξ± particle capture.
β€’ For elements 93<Z<103, neutron bombardment is easier than
Ξ± bombardment because neutrons don’t repel, so less energy
is required
β€’ For elements with Z>103, bombardment of 249
98𝐢𝑓 with other
nuclei leads to formation of radionuclides up to Z=118.
© 2014 W. W. Norton Co., Inc.
Artificial Nuclides
238
92π‘ˆ
+ 10𝑛 β†’
239
94𝑅𝑓
+ 2 βˆ’10𝑒
249
98𝐢𝑓
+ 126𝐢 β†’
257
104𝑅𝑓
+ 4 10𝑛
249
98𝐢𝑓
18
8𝑂
263
106𝑆𝑔
4 10𝑛
© 2014 W. W. Norton Co., Inc.
+
β†’
+
Trans-uranium neutron capture
Trans-californium nuclei fusion
10