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Atomic Theory The Movers and Shakers of the Subatomic World. Democritus • 440 B.C.E • All matter is made up of atoms, which are indivisible • he pounded up materials in his pestle and mortar until he had reduced them to smaller and smaller particles which he called ATOMA (greek for indivisible) Dalton • In the early 1800’s, the English chemist John Dalton did a number of experiments that eventually led to the acceptance of the idea of atoms. Dalton’s Atomic Theory • All elements are composed of atoms. Atoms are solid small spheres and indivisible particles. continued... • Atoms of the same element are exactly alike. H H continued... • Atoms of different elements are different. O H continued... • Compounds are formed by the joining of atoms of two or more elements. H H O Questions... • What were the four parts of the Dalton’s atomic theory? • Say it again... Was he right? • Dalton’s atomic theory of matter became one of the foundations of chemistry. • BUT it needed work…other scientists had to modify the theory. Thomson • In 1897, the work of an English scientist J. J. Thompson provided the first hint that atoms were made up of even smaller particles • Atoms are divisible…Dalton was wrong! Thompson’s Model • He stated that atoms are made up of positively (+) and negatively (-) charged particles And... • He thought the positive (+) and negative (-) particles were s p r e a d o u t in atoms like ppuldudmisn • (plums in puddin’) Questions... • What kind of particles did Thompson find in atoms? • What did his idea of an atom look like? Was Thomson Right? • Not really…there are positively (+) and negatively (-) charged particles inside atoms. •BUT... Rutherford’s Model • In 1908, Rutherford discovered the nucleus. • He stated that atoms have a small, dense, positively (+) charged ce nucleus. nter called a The Nuclear Atom Alpha Particle Scattering 29/04/2017 . Alpha Source An atom Back Next The Nuclear Atom 29/04/2017 Rutherford’s Model He suggested that all of the atom’s positive charge, together with most of its mass, is concentrated in the centre. + Alpha particles which travel close to the nucleus are strongly deflected. The degree of deflection depends on how close it approaches. Back Next The Nuclear Atom Rutherford’s Model 29/04/2017 The nucleus must be very small in comparison to the atom. This will account for the vast majority making it through unaffected. Back Next Questions... • What did Rutherford find inside the atom? • What did Rutherford’s atom look like? So... • Particles are not spread out like plums in pudding… • Positive particles (protons) are in the center (nucleus). • Where are the negative particles (electrons)? Bohr’s Model • In 1913, Niels Bohr proposed an improvement to Rutherford’s Model: • Electron’s move in definite orbits around the nucleus, like planets around the sun. + Back Next Questions... • What did Bohr propose? • Where were the particles in Bohr’s model of an atom? • What did it look like? • What was special about the electrons in Bohr’s model? Are we there yet? • Bohr’s model was used for a long time… •BUT... Modern Atomic Model • An atom has a small, positively charged nucleus surrounded large region by a in which there are enough electrons (-) to make the atom neutral (0). E E E E E PPP P PP P P PP P P E E E E E E E Questions... • Do electrons have specific orbits in the modern model? • What does the atom look like in the new model? Make Your Timeline • After the sheet is passed out: – write your name on it! – Fill out the timeline according to date, scientist, notes, and picture (if there is one) for each scientist we went over. – Neatness counts!!!!! – HAVE FUN Bohr’s Atom electrons in orbits nucleus HELIUM ATOM Shell proton + - N N + electron What do these particles consist of? - neutron ATOMIC STRUCTURE Particle Charge Mass proton + ve charge 1 neutron No charge 1 electron -ve charge nil ATOMIC STRUCTURE 2 He Helium 4 Atomic number the number of protons in an atom Chemical Symbol Chemical Name Atomic mass the number of protons and neutrons in an atom number of electrons = number of protons ATOMIC STRUCTURE Electrons are arranged in Energy Levels or Shells around the nucleus of an atom. • first shell a maximum of 2 electrons • second shell a maximum of 8 electrons • third shell a maximum of 8 electrons • forth shell a maximum of 8 electrons ELECTRONIC CONFIGURATION With electronic configuration elements are represented numerically by the number of electrons in their shells and number of shells. For example; Nitrogen 2 in 1st shell 5 in 2nd shell configuration = 2 , 5 2 + 5 = 7 7 N 14 ELECTRONIC CONFIGURATION Write the electronic configuration for the following elements; a) Ca 20 b) Na 40 2,8,8,2 d) Cl 17 35 2,8,7 11 23 c) 2,8,1 e) Si 14 28 2,8,4 O 8 16 2,6 f) B 5 11 2,3 Bohr Rutherford Diagrams With Bohr Rutherford diagrams, elements and compounds are represented by Dots to show electrons, and circles to show the shells. For example; O Nitrogen O O N OO O O N 7 14 Bohr Rutherford Diagrams Draw the Bohr Rutherford Diagrams for the following elements; O 8 17 O a) O b) Cl 35 O 16 O O O O O O O O O Cl O O O O O O O O O O O O O O O SUMMARY 1. The Atomic Number of an atom = number of protons in the nucleus. 2. The Atomic Mass of an atom = number of Protons + Neutrons in the nucleus. 3. The number of Protons = Number of Electrons. 4. Electrons orbit the nucleus in shells. 5. Each shell can only carry a set number of electrons. References • Investigating Science Pearson 9 • Dercho