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Lecture 1: chemistry, measurement, conversions Topic Brown Chapter 1 1. Science and Chemistry What is science? The scientific method What is chemistry? 1.1 2. What is matter? 1.2 States of matter Pure substances vs. mixtures Physical vs. chemical change 1.3 3. Measurement, metric units & prefixes 1.4 Derived units and density Exact & inexact numbers Uncertainty, precision & accuracy 1.5 Significant figures & use in calculation Scientific notation 4. Dimensional analysis = conversions 1.6 With multiple conversion factors Conversions with unit prefixes With cubed unit volumes Matter takes has mass & volume; it occupies space. Matter has energy-dependent physical states. Matter can be a pure substance or a mixture. Matter undergoes physical or chemical change. What’s this “matter” that chemists study? Matter? The physical stuff of the universe; anything that has mass & occupies volume or space. All matter is found in one of three physical states: p.4-9 Energy content determines physical state. What does it take to convert from one form to the other? abundance? Gas? Liquid? Solid? energy? low high medium medium high none/low shape? compression? indefinite indefinite fixed possible difficult not possible What happens to physical state when: 1. Temperature is increased or decreased? Increased: solid -> liquid -> gas 2. Pressure is increased or decreased? Increased: gas -> liquid -> solid p.4-9 Pure substances Pure Substance? Matter with distinct properties and composition - does not vary from sample to sample. …. Examples? There are two types of pure substance: 1. Elements Cannot be decomposed into simpler substances. (Although it’s true that particle physicists can smash atoms into subatomic particles.) 2. Compounds Substances created by combining two or more atoms at a constant atomic ratio. So compounds can be broken down (or decomposed) into simpler substances or atoms. An example is the electrolysis of water. Two identical atoms a. diatomic b. mixed atoms Well……. p.5-8 How many elements are there? Currently, 117 elements. And they’re all listed in the periodic table Inside cover Mixtures: varying ratios Mixtures Two or more substances combined at a varying ratio. Note that most of the matter we see in daily life exists as mixtures. Mixtures can be found in all three physical states. Give me examples of mixtures in each state…… p.8-9 Homogeneous vs. heterogenous? Mixtures are described using one of these terms. Homogeneous (aka SOLUTIONS) Uniform throughout, or “smooth” Heterogeneous Not uniform throughout, or “chunky” p.8-9 Flowchart for describing matter Get to know these questions! p.9 Physical properties of matter Physical properties Can be observed without changing the identity or composition of the substance. Example: changes in physical state. • color • odor • Density • melting point • boiling point • freezing point Intensive properties? Are independent of the amount of a material being observed. They are innate, inborn, inherent and unchanging characteristics of a substance. In fact, intensive characteristics are often used to identify substances. Extensive properties? Depend on the amount of material being observed. There are really only two extensive properties: mass & volume p.9-11 Separating mixtures Both physical & chemical properties of substances can be used to separate mixtures into their component parts. filtration distillation chromatography p.11-12 Chemical properties of matter Chemical properties Describe how a substance may change or react to form other substances. Chemical change Transforms one substance into another. Identity changes, but the atoms that make up substances aren’t changed, atomic connections are just rearranged. p.9-11 “Decomposition” of molecules Decomposition: The breakdown of molecules into smaller molecules or elements. Electricity can break water down into hydrogen & oxygen gases. [Note that electrolysis produces twice as much hydrogen as oxygen. Why? Water molecules, H2O, have two H atoms for each O atom.] p.7