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UNIT 4 NOTES: THE PERIODIC TABLE SECTION 1 : PERIODIC LAW Periodic Law states that the properties of elements are _________________________ functions of their ___________________ _______________________. This means when the elements are listed according to their atomic number, the properties repeat periodically. SECTION 2: ARRANGEMENT OF THE PERIODIC TABLE The periodic table is arranged in order of increasing __________________________________________________. The location of an element can be described by indicating what vertical ____________ or horizontal __________________ it is in. The columns and rows on the table are numbered. 1. VERTICAL COLUMNS: The vertical columns on the table are also known as __________________ or __________________. Some of them have specific names, such as: Group 1: ____________________________ Group 2:_____________________________ Groups 3-11__________________________ Group 17: ____________________________ Group 18: ____________________________ Elements located in the same group on the table the same number of _________________ _____________________. Because of this they have the same ________________________. There are a few exceptions (see group 18) 18 He 2 Ne 2,8 Ar 2,8,8 Kr 2,8,18,8 Xe 2,8,18 18,8 Rn 2,8,18 32,18,8 2. Horizontal Rows- The horizontal rows on the table are also known as: _______________________________________. Elements located in the same period have the same number of occupied ____________________________ _______________________. Another way to say this is that they all have their _____________________ _________________ in the same __________________. As you go across a period the number of valence electrons ___________________ and the properties of the elements also __________________ systematically. We will look at some of these properties later. Section 3: Atomic Radius Atomic radius is really the ____________ of the atom. It is defined as ____________of the distance between two adjacent nuclei. It is usually measured in the units of ____________________. Values of atomic radii are found in __________________. 1. Atomic radius down a group: As you proceed down a group atomic radius generally _____________________. This is because as you go down you _____________________ the number of _______________ ______________ _______________. More energy levels mean a _________________ atom. 2. Atomic radius across a period: As you proceed across a period atomic radius generally _____________________________. This may not make sense at first because the atoms get more ________________ , more ________________ and a greater mass, yet they get __________________. This is because the ___________________ ____________________ of the elements are all in the same ___________________ __________________, but the number of _______________________ in the nucleus attracting them ________________________, causing the radii to _________________. SECTION 4: IONIC RADIUS 1. Becoming an ion: Atoms become ions either by ________________ or by losing _______________________. If you gain electrons to become an ion you are called a _________________. If you lose electrons to become an ion you are known as a _________________. 2. Definition of ionic radius: Ionic radius is defined at the distance from the_______________ of an ion to the _______________________ energy level. 3. Metal ions: Metals are located to the _______________ of the stairs. They form ions by ______________ their valence electrons. Therefore in metals, the _________________ radius is always smaller than the ______________ radius. Another way to say this is that the ____________ radius is always ______________ than that of the parent atom. 4. Nonmetal ions: Nonmetals are located to the _____________ of the stairs. Nonmetals form ions by ______________________ electrons until they have ___________ in their valence shell. The ___________ electrons are not as strongly attracted as the native electrons and are located a bit ______________ from the nucleus. As a result nonmetal ions are always _________________ than their parent atoms. In other words, in nonmetals, the ionic radius is ____________ than the atomic radius. SECTION 5: IONIZATION ENERGY AND ELECTRONEGATIVITY 1. ELECTRONEGATIVITY is defined as the measure of an atom’s ability to ____________________ _______________________. An atom with a low Electronegativity- like ____ ________________ attract electrons well. An atom with a high Electronegativity- like _____________________ attract electrons well. Electronegativity values are given in reference table _________________. As you proceed down ____________________. As you proceed across ____________________. a group electronegativity a period electronegativity 2. IONIZATION ENERGY is defined as the _________________ that must be added to an atom to ________________________ it’s outermost electron. An atom with a low Ionization Energy- like ______________requires _________ of energy to remove its valence electron. An atom with a high Ionization Energy- like ______________only requires _________________ of energy to remove its valence electron. Ionization energy values are given in reference table __________________. As you proceed down the group _________________________. As you proceed across a period ________________________. Ionization energy ionization energy SECTION 6: METALS 1. Metals are located on the periodic table to the ____________ of the _______________. 2. Some examples of metals include ____________________ and _______________________ and _____________________ and ________________. Even though __________________ is to the left of the stairs it is _______________ considered a metal. 3. Metals have the following properties: Metals have ________________ - this means that they are __________. Metals are ________________. This means they can be ______________ into shapes. Metals are ___________________________ conductors of heat and electricity. Metals _____________ electrons easily- this indicates they have low ________________________ _____________. Metals ____________ their own valence electrons and therefore do not ________________ others. This indicates they have low _________________________________. In metals, their _____________ radius is smaller than their ______________ radius Metals are ______________________, this means they can be _________ into a wire. Most metals are _______________ at 25C or 298 K. The only exception is _____________________, which is a ____________. The reactivity of metals _________________ down a group and _______________ across a period. __________________ is the most active metal. SECTION 7: NONMETALS 1. Nonmetals are located to the _________________ of the stairs. Even though the Group 18 elements are to the left- they are not considered to be ____________________. 2. Some examples of nonmetals include_______________________ and ___________________________ and _________________________ and _____________________________. 3. Nonmetals have the following properties: Nonmetals do not have ________________- they are _______________ Nonmetals are ___________________- they are not _______________ or ductile. Nonmetals _____________ electrons in reactions and form _______________. They have a strong ability to attract electrons from other elements. This means they have a _________________ ___________________________. In nonmetals, their _____________ radius is smaller than their ________________ radius. Nonmetals are _________________ conductors of heat and electricity. Nonmetals have _____________ ionization energies- this means it requires ______________ of energy to remove electrons from them. Nonmetals exist as ______________ -like ___________; or as colored ______________ - like __________________ or as a __________________ like _________________. The reactivity of nonmetals ____________________ down a group and ________________ across a row. _________________ is the most active nonmetal. SECTION 8: SEMI-METALS OR METALLOIDS 1. Semi-metals are located _____________ the stairs. The following elements are metalloids: 2. Semi-metals have properties of both ________________ and ___________________. SECTION 9: THE GROUP 1 METALS 1. The group 1 metals are known as the ___________________ metals. 2. They have ___________ valence electron. 3. They ___________ one electron to be stable and form ions with a _________ charge. 4. They have _______ ionization energies and _________ electronegativities. 5. They are the ___________ reactive group of metals- and are so active they are never found in nature as _____________ only as ________________. 6. They react with water to form _____________ and a _____________. 7. As you go down the group reactivity _____________________. 8. Members include: SECTION 10: THE GROUP 2 METALS 1. The group 2 metals are known as the ____________________ ________________ metals. 2. They have ___________ valence electrons. 3. They ______________ two electrons to be stable and form ions with a ___________ charge. 4. They have _______ ionization energies and _________ electronegativities. 5. They are the ____________-___________ reactive group of metalsand are so active they are never found in nature as _____________ only as ________________. 6. They react with water to form _____________ and a _____________. 7. As you go down the group reactivity _____________________. 8. Members include: SECTION 11: GROUPS 3-11 1. These are known as the ___________________________ metals. 2. They are __________ at reactive as other metals. 3. They form _______________ solutions when dissolved in water. For example Cu+2 is ___________, while Fe3+ is ___________. In other words transition elements have _______________ ions. 4. They have _____________________ positive oxidation states. 5. They can ________ electrons from their _____________________ shell and their ___________________________. SECTION 12: GROUP 15 1. This group is composed of nonmetals, semi-metals and _______________. 2. As you proceed down the group non-metallic character ________________ and metallic character __________________. 3. This group contains one diatomic element ________________, that is ________________ bonded to itself. SECTION 13: GROUP 17 1. These elements are known as the _____________________. 2. The have _________ valence electron. 3. They will ______________ 1 electron to become stable and therefore have a charge of ____________ as ions. 4. These have___________ ionization energies and electronegativities. 5. These are the _______________ reactive nonmetals and their reactivity ________________ down a group. 6. These elements are so reactive they are not found in nature as ______________ only as __________________. 7. This is the only group on the periodic table that contains elements in all three ____________________ of matter. Fluorine and chlorine are ________________. Bromine is a __________________ and iodine is a ______________. 8. This group also contains four diatomic elements: SECTION 14: THE GROUP 18 ELEMENTS 1. These elements are called the _____________________________. 2. They have _______________ valence electrons- except for _____ it only has ____________. 3. These elements are very ________________- they have a _________ outer shell of electrons. 4. These elements do not ______________ in nature, but _______________. ________________. And _______________ have been forced to react with fluorine and oxygen in a lab.