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Name: THE INTERNATIONAL SCHOOL OF AZERBAIJAN Topic Test: Atomic Theory SL & HL Standard & Higher Level Time allowed: One lesson MC Score: / EA Score: / Total: / Percent: All questions are from IB past papers % Grade ≥ 80.0 7 79.9 - 68.0 6 67.9 – 58.0 5 45.0 – 57.9 4 30.0 – 44.9 3 20.0 – 29.9 2 < 20.0 1 1. [1 mark] Bromine consists of two stable isotopes that exist in approximately a 1 : 1 ratio. The relative atomic mass, A, of bromine is 79.90. Which are the stable isotopes of bromine? 2. A. 79Br and 81Br B. 80Br and 81Br C. 78Br and 80Br D. 79Br and 80Br [1 mark] Which is correct for 3. ? [1 mark] Which representation would be correct for a species, Z, which has 31 protons, 40 neutrons and 28 electrons? A. B. C. D. 4. [1 mark] Which ion will show the least deflection in a mass spectrometer? A. B. C. D. Документ1 Page 2 of 13 5. [1 mark] Which statements about the isotopes of chlorine, I They have the same chemical properties. II They have the same atomic number. III They have the same physical properties. 6. A. I and II only B. I and III only C. II and III only D. I, II and III and , are correct? [1 mark] Which quantities are the same for all atoms of chlorine? I Number of protons II Number of neutrons III Number of electrons 7. A. I and II only B. I and III only C. II and III only D. I, II and III [1 mark] What is the ground state electron configuration of an atom of chromium, Cr (Z = 24)? 8. A. [Ar]3d6 B. [Ar]4s23d4 C. [Ar]4s13d5 D. [Ar]4s24p4 [1 mark] Which transition in the hydrogen atom emits visible light? A. n = 1 to n = 2 B. n = 2 to n = 3 C. n = 2 to n = 1 D. n = 3 to n = 2 Документ1 Page 3 of 13 9. [1 mark] Which statements are correct for the emission spectrum of hydrogen? I The lines converge at higher frequencies. II Electron transitions to n = 2 are responsible for lines in the visible region. III Lines are produced when electrons move from lower to higher energy levels. A. I and II only B. I and III only C. II and III only D. I, II and III 10. [1 mark] Which electron transition emits radiation of the longest wavelength? MULTIPLE CHOICE QUESTIONS are now HIGHER LEVEL STANDARD LEVEL QUESTIONS CONTINUE AFTER THESE M/C Документ1 Page 4 of 13 11. [1 mark] Which element is represented by the first eight successive ionization energies on the graph? A. Mg B. S C. Cl D. Ar 12. [1 mark] The values for the first three successive ionization energies for two elements X and Z are given. Which pair of elements represents X and Z? Документ1 Page 5 of 13 13. [1 mark] The graph shows the first ionization energies of some consecutive elements. Which statement is correct? A. Y is in group 3 B. Y is in group 10 C. X is in group 5 D. X is in group 18 14. [1 mark] A period 3 element, M, forms an oxide of the type M2O. Which represents the first four successive ionization energies of M? 15. [1 mark] Between which ionization energies of boron will there be the greatest difference? A. Between 1st and 2nd ionization energies B. Between 2nd and 3rd ionization energies C. Between 3rd and 4th ionization energies D. Between 4th and 5th ionization energies Документ1 Page 6 of 13 STANDARD LEVEL QUESTIONS RESUME 16. a. [1 mark] This question is about iron. Deduce the full electron configuration of Fe2+. b. [1 mark] State the nuclear symbol notation, c. , for iron-54. [2 marks] Mass spectrometry analysis of a sample of iron gave the following results: Calculate the relative atomic mass, Ar, of this sample of iron to two decimal places. Документ1 Page 7 of 13 17. a. [2 marks] State the relative mass and charge of the subatomic particles of an atom. b. i. [3 marks] Calculate the number of neutrons and electrons in one atom of . Neutrons: Electrons: ii. State one difference in the physical properties of the isotopes their chemical properties are the same. Physical: Chemical: Документ1 Page 8 of 13 and and explain why c. [1 mark] Copper is a metal that has been used by humans for thousands of years. State the full electron configuration of . 18. [6 marks] Every element has its own unique line emission spectrum. (i) Distinguish between a continuous spectrum and a line spectrum. (ii) Draw a diagram to show the electron transitions between energy levels in a hydrogen atom that are responsible for the two series of lines in the ultraviolet and visible regions of the spectrum. Label your diagram to show three transitions for each series. 19. a. [1 mark] Explain why the relative atomic mass of argon is greater than the relative atomic mass of potassium, even though the atomic number of potassium is greater than the atomic number of argon. Документ1 Page 9 of 13 b. [1 mark] Deduce the electron configuration for the ion END OF STANDARD LEVEL Документ1 Page 10 of 13 . HIGHER LEVEL 20. [1 mark] Sketch the orbital diagram of the valence shell of a bromine atom (ground state) on the energy axis provided. Use boxes to represent orbitals and arrows to represent electrons. 21. a. [1 mark] The emission spectrum of an element can be used to identify it. Hydrogen spectral data give the frequency of 3.28 × 1015 s–1 for its convergence limit. Calculate the ionization energy, in J, for a single atom of hydrogen using sections 1 and 2 of the data booklet. b. [1 mark] Calculate the wavelength, in m, for the electron transition corresponding to the frequency in (a)(iii) using section 1 of the data booklet. Документ1 Page 11 of 13 22. a. [1 mark] Draw the first four energy levels of a hydrogen atom on the axis, labelling n = 1, 2, 3 and 4. b. [1 mark] Draw the lines, on your diagram, that represent the electron transitions to n = 2 in the emission spectrum. End of Paper Документ1 Page 12 of 13 Документ1 Page 13 of 13