Survey
* Your assessment is very important for improving the workof artificial intelligence, which forms the content of this project
* Your assessment is very important for improving the workof artificial intelligence, which forms the content of this project
California State University, San Bernardino CSUSB ScholarWorks Electronic Theses, Projects, and Dissertations Office of Graduate Studies 9-2014 DEGRADATION OF PROTECTIVE GLOVE MATERIALS EXPOSED TO COMMERCIAL PRODUCTS: A COMPARATIVE STUDY OF TENSILE STRENGTH AND GRAVIMETRIC ANALYSES Todd B. Pelham [email protected] Follow this and additional works at: http://scholarworks.lib.csusb.edu/etd Recommended Citation Pelham, Todd B., "DEGRADATION OF PROTECTIVE GLOVE MATERIALS EXPOSED TO COMMERCIAL PRODUCTS: A COMPARATIVE STUDY OF TENSILE STRENGTH AND GRAVIMETRIC ANALYSES" (2014). Electronic Theses, Projects, and Dissertations. Paper 107. This Thesis is brought to you for free and open access by the Office of Graduate Studies at CSUSB ScholarWorks. It has been accepted for inclusion in Electronic Theses, Projects, and Dissertations by an authorized administrator of CSUSB ScholarWorks. For more information, please contact [email protected]. DEGRADATION OF PROTECTIVE GLOVE MATERIALS EXPOSED TO COMMERCIAL PRODUCTS: A COMPARATIVE STUDY OF TENSILE STRENGTH AND GRAVIMETRIC ANALYSES A Project Presented to the Faculty of California State University, San Bernardino In Partial Fulfillment of the Requirements for the Degree Master of Science in Earth and Environmental Science by Todd Bracewell Pelham September 2014 DEGRADATION OF PROTECTIVE GLOVE MATERIALS EXPOSED TO COMMERCIAL PRODUCTS: A COMPARATIVE STUDY OF TENSILE STRENGTH AND GRAVIMETRIC ANALYSES A Project Presented to the Faculty of California State University, San Bernardino by Todd Bracewell Pelham September 2014 Approved by: Dr. Robert N. Phalen, Committee Member, Health Science Dr. James Noblet, Committee Member, Chemistry Dr. Renwu Zhang, Committee Member, Chemistry © 2014 Todd Bracewell Pelham ABSTRACT Current glove guides attempt to assist in recommending which type of glove is appropriate for handling chemicals; however, they include information on less than 1% of the 89 million chemical products available today. This study offers a solution by testing five durable polymer materials against 50 chemicals, using two rapid chemical degradation assessment techniques. The first technique involves gravimetric analysis of the weight change following constant immersion against the chemical mixture. The second method uses tensile strength to assess molecular changes in the polymer structure. This study is focused on addressing three issues of concern. First, this study examines if current degradation testing methods are adequate to determine chemical resistance against complex mixtures. Secondly, this study will be used to determine if current degradation information on pure chemicals is effective in predicting degradation of complex chemical mixtures, based on the major ingredient(s). Lastly, this study will start a chemical resistance index for complex mixed chemicals. The results of this study clearly show that glove recommendations of pure and mixed chemicals are frequently different. In more than 58.4% of the cases, the mixed chemical requires a different glove than that of its pure chemical components. Results also show that glove recommendations based solely on weight change and/or permeation results are missing important information on iii tensile test performance. There are several instances (15.2%) in which the initial glove recommendation would be changed to a lower recommendation rating if the results of a tensile test were included. iv ACKNOWLEDGEMENTS Dr. Robert Phalen PhD, CIH Kandace Steele California State University, San Bernardino Carpool Technicians California State University, San Bernardino Plumbers California State University, San Bernardino Environmental Health Specialists v TABLE OF CONTENTS ABSTRACT ................................................................................................. iii ACKNOWLEDGEMENTS ............................................................................ v LIST OF TABLES ........................................................................................ viii CHAPTER ONE: INTRODUCTION ............................................................. 1 CHAPTER TWO: LITERATURE REVIEW Background ....................................................................................... 6 Current Glove Guides ....................................................................... 7 Hypothesis ........................................................................................ 11 CHAPTER THREE: MATERIALS AND METHODS Polymer Selection ............................................................................. 13 Chemical Selection ........................................................................... 14 Equipment.......................................................................................... 15 Gravimetric Analysis .......................................................................... 15 Tensile Testing ................................................................................. 17 Mixed- and Pure- Chemical Analysis Determining Pure Chemical Composition Using the SDS ....... 18 Determining Recommendations Using Available Guidelines ............................................................................... 18 Determining Degradation Based on Tensile Strength ............ 19 CHAPTER FOUR: RESULTS Gravimetric Analysis Results ............................................................ 21 Tensile Strength Test Results ............................................................ 29 vi CHAPTER FIVE: DATA ANALYSIS Organizing Results to Establish a New Library ................................. 38 Pure- and Mixed- Chemical Analysis for Polymer Selection .............. 40 Weight and Tensile Strength Data ..................................................... 43 Weight and Tensile Strength Ratings for Polymer Selection.............. 45 CHAPTER SIX: DISCUSSION Pure Chemicals and Mixed Chemicals ............................................. 49 Weight versus Tensile Results .......................................................... 51 More Conservative Polymer Recommendations ............................... 52 CHAPTER SEVEN: CONCLUSIONS .......................................................... 53 APPENDIX A: PROPERTIES OF THE 50 MIXED CHEMICALS TESTED .............................................................................. 56 APPENDIX B: PROPOSED NEW GLOVE MATERIALS INDEX ................. 59 REFERENCES ............................................................................................ 70 vii LIST OF TABLES Table 1. Gravimetric Analysis Results ......................................................... 22 Table 2. Tensile Strength Test Results ........................................................ 30 Table 3. Weight and Tensile Strength Variances in Polymer Recommendation ............................................................................ 43 viii CHAPTER ONE INTRODUCTION Gloves can act as both the first and last lines of defense in protecting individuals from chemical exposure in both industrial and household settings. Gloves, classified as a type of Personal Protective Equipment (PPE), are designed to provide barriers against potentially dangerous chemicals from having direct contact or prolonged exposure to skin. According to OSHA, “an estimated 60,000 deaths and 860,000 occupational illnesses per year in the US are attributed to occupational exposure, a relatively small percentage caused by skin exposure would represent a significant health risk”.(1) Chemical burns, wounds, infection, and death could result if a glove were to not effectively protect against chemical exposure. According to Reuscher (2012), there are several factors to consider when choosing the right gloves, including: splash or immersion protection, characteristics of the chemical being handled, temperature and concentration of the chemical, length of exposure time to chemical, dexterity needed to do task, and whether disposable or reusable are the best option. (2) Gloves are not solely used as protection against pure chemicals hazards, but are frequently used as protection against exposure to industrial or commercial products, which can include complex mixtures of various chemical components. Industrial and commercial products will be referred to as ”mixed chemicals” in this study. These complex mixed chemicals can have very different 1 chemical properties from their pure chemical ingredients. There is currently no published index enabling consumers to properly identify which glove choice can best protect against a variety of mixed chemical industrial and commercial products. This lack of information could lead to undue injury, illness or death. The wrong glove could be chosen because of the misconception that the chemical resistance to protect against a mixture is equal to the chemical resistance of the pure chemical ingredients. This belief in equal chemical resistance excludes any potential changes in chemical hazard or strength resulting from the pure chemicals being mixed together. Gravimetric studies analyze the differences in the weight of the glove material prior to and after chemical exposure. Variations in weight signify that a chemical reaction or physical change in the polymer occurred. Procedures for methods to evaluate weight change as a measure of degradation can be found in the American Society for Testing and Materials (ASTM) Method D 471 Standard Test Method for Rubber Property – Effect of Liquids.(3) Another degradation standard, the American National Standards Institute’s International Safety Equipment Association (ANSI/ISEA) Standard 105 Hand Protection Selection Criterion(4), provides a set of criteria to analyze the puncture resistance of a polymer glove, which is related to the tensile properties of the material. Analyzing the tensile properties of a glove material before and after exposure to a chemical can help determine if a breakdown in the polymer structure has occurred, which is when the glove material breaks or tears more easily after exposure to a 2 chemical. A significant difference in measurements for either a weight or tensile test indicates that the glove may not completely protect against the chemical and a more suitable glove may need to be chosen. However, most current guides neglect to include information on changes in puncture resistance or tensile properties, limiting the scope of coverage for the guides, which can potentially result in the recommendation of an inadequate glove material. Many guides, such as the Ansell Guide(5) or Forsberg et al. Quick Selection Guide to Chemical Protective Clothing(6), evaluate permeation data in place of chemical degradation weight or tensile changes, which further complicates the selection process. Significant differences are anticipated in comparing the degradation results of glove material exposed to mixed chemicals to that of the individual pure chemical ingredients. These differences are worth noting because if a glove is unable to withstand a chemical, then its use could result in injury, illness or death. The analysis of weight and tensile strength changes, following exposure to chemical mixtures, in comparison to their pure chemical components will help determine if current degradation methods can be used to determine proper glove choice for chemical resistance. Current published glove guides are limited in their scope of included chemicals. The American Chemical Society’s Chemical Abstract Service database (CAS), includes roughly 89 million chemicals that existence today.(7) Of the 89 million chemicals in existence, the Ansell Guide lists PPE recommendations for 167 chemicals(5), and the Forsberg et al. Quick Selection 3 Guide to Chemical Protective Clothing lists PPE recommendations for approximately 1000 chemicals(6). There are also other smaller database systems, such as the National Institutes for Occupational Safety and Health (NIOSH) Recommendations for Chemical Protective Clothing: A Companion to the NIOSH Pocket Guide to Chemical Hazards.(8) The NIOSH guide is also limited in scope and application for the vast myriad of chemicals on the market today. It is evident that there is a lack of available information on glove recommendations for safe chemical handling. There is an estimated one new chemical discovered or created every 2.3 seconds.(7) However, chemical resistance data exist for less than 1% of the available chemicals.(7) This study offers a solution for determining appropriate chemical protective glove materials used in both industrial and household applications. It does so by testing five durable polymer materials, common glove materials available on the market, using two rapid chemical degradation assessment techniques. The first technique involves gravimetric analysis of the weight change following constant immersion in the chemical component or mixture, in a manner similar to ASTM Method D 471.(3) The second method uses tensile strength to assess molecular changes in the polymer structure, similar to a previous study by Gao and Tomaovic (2005).(9) A total of 50 chemicals, found in a variety of industrial and household settings, were used to evaluate the effectiveness of these methods in determining a polymer material best suited to resist chemical degradation to complex mixtures and commercial products. 4 This study is focused on addressing three issues of concern. First, this study examines if current degradation testing methods, which focus on weight change (and in some cases permeation) are adequate to determine glove chemical resistance to degradation. Secondly, this study will be used to determine if current degradation results on pure chemicals are effective in predicting degradation of complex chemical mixtures, based on the major ingredient(s). Lastly, this study will start an index and create a chemical guide that can be used for complex mixed chemicals. 5 CHAPTER TWO LITERATURE REVIEW Background Exposures to chemicals happen every day and in a variety of settings. Whether at home cleaning or at an industrial work environment, safe practices in choosing the correct personal protective equipment, such as gloves, can prevent burns, wounds, infection, and even death. Gloves come in all different types of materials and thicknesses. They can range in cost between two cents for a single-use, disposable latex glove to over $110 dollars for a multi-use, heavy duty polyvinyl chloride glove. According to Hatada et al. (1996), degradation is defined as the “chemical changes in a polymeric material that result in undesirable changes in the values of in-use properties of the material”.(10) Glove degradation is often thought of as occurring when the polymer material breaks down enough for an unwanted chemical to come in contact with the skin. This can still occur even if there is no apparent sign of either holes or tears in the polymer material. To prevent a potentially harmful chemical coming in contact with skin, one must use a glove that can offer the best protection for that exact individual application. To determine if degradation is occurring, one may be able to observe changes following exposure to a chemical, as a glove may begin to swell, shrink, harden, stiffen, brittle or blister. According to Chemical Protective Clothing (Anna, 2003), 6 the best way to describe glove degradation is when a glove has lost its ability to provide adequate protection to the user of the glove.(11) To choose the glove that offers the best protection, a consumer must first look up the exact individual chemical ingredients of a product by using the Safety Data Sheets (SDS),(12) formerly known in the United States as Material Safety Data Sheets (MSDS).(13) One would then have to look up these individual chemical ingredients in a PPE recommendation guide, such as the Ansell Guide(5) or the Forsberg et al. Quick Selection Guide to Chemical Protective Clothing(6) to determine which polymer is the least likely to degrade during chemical exposure. The question that still remains unanswered is whether or not the selected glove material will provide the predicted level of protection. For simplification, in this study, individual chemical ingredients will be referred to as ”pure chemicals” and complex chemical products will be referred to as ”mixed chemicals”. Current Glove Guides One guide that provides chemical information is the Safety Data Sheets most commonly known as the SDS. Every commercial chemical in the United States has an SDS, displaying data on identification, hazard identification, composition/information on ingredients, first-aid measures, fire-fighting measures, accidental release measures, handling and storage, exposure controls/personal protection, physical and chemical properties, stability and 7 reactivity, and toxicological information.(12) There are two main problems with utilizing the SDS for glove recommendations. First, it is generally written in language more suited for business applications and the promotion of employee safety, rather than layman language for individual use. Secondly, the SDS guides do not often recommend specific glove materials for individual chemicals. To ensure that the SDS does not give improper regimentations, the print will often state something vague, such as ”use a chemically resistant glove”.(14) Although the SDS does not often provide resolution in determining the appropriate glove to use, it can be utilized to research the pure chemical ingredients contained within each listed commercial product, as the chemical components are often provided. The Ansell Chemical Resistance Guide is commonly used in order to determine whether an Ansell glove product can withstand chemical permeation,(5) as well as, chemical degradation in some cases. According to Chemical Protective Clothing (Anna, 2003), permeation is a process that occurs when a chemical passes through a surface without going through an opening such as a hole or tear, at a molecular level.(11) The Ansell Guide(5) is a compilation of test results and charts that assist in determining the degradation of an Ansell glove product in a hazardous chemical. This helps a consumer decide which Ansell glove product can work best given the type of pure chemical they will be exposed to. The Ansell charts use a letter rating system and a color-coded system in order to show the consumer the recommended rating of each glove material. The color-coded system is based on chemical permeation. Green colored boxes 8 mean the glove is excellent or good and the permeation breakthrough is 30 min or longer. Red colored boxes mean that the glove is poor or not recommended for that chemical. Lastly, yellow colored boxes are used to show that the glove did not fail the testing, but that material is also not recommended for use with that chemical. The letter degradation rating is based on the percentage of change in glove condition, where an excellent rating (E) is based on a change of less than 10%, a good rating (G) is based on a change of between 11-20%, a fair rating (F) is based on a change of between 21-30%, a poor rating (P) is based on a change of between 31-50%, and finally if the change of the glove is more than 50% the glove is not recommended (NR) for that chemical. The Ansell degradation guideline primarily focuses on which glove is the best against permeation of a pure chemical using ATSM Method F 739 Standard Test Method for Permeation of Liquids and Gases through Protective Clothing Materials under Conditions of Continuous Contact.(15) A critical issue with the Ansell Guide is that many of the recommendations are based on permeation data only, without consideration of degradation testing. Because permeation is the molecular movement of chemicals through the polymer and degradation is the chemical changes of the polymer itself, the exclusion of degradation data means that if there are chemical changes, but no increased molecular movement, the recommendations will not change. The consequence can be the selection of a glove material that can perform once for 30 plus minutes, but may be unacceptable thereafter. Chemical 9 degradation testing is an essential component of chemically protective glove performance testing. The Forsberg et al. Quick Selection Guide to Chemical Protective Clothing(6) is a guide that shows roughly 1000 general polymer recommendations. The provided chart also shows the results in a color coded format dependent on permeation time and degradation rating of a pure chemical on polymer material. Although, this chart has more data than the Ansell chart, it is a little harder to use as there is no specific indication of chemical degradation or permeation data, whereas Ansell does provide separate guidelines and data for these two parameters, albeit degradation results are often not provided. The National Institute for Occupational Safety and Health (NIOSH) complies a database called Recommendations for Chemical Protective Clothing: A Companion to the NIOSH Pocket Guide to Chemical Hazards.(8) However, this guide is limiting in its actual recommendations for skin protection. The guide often states three levels of recommendations, which do not assist in conclusively recommending specific glove materials that will prevent skin contact. The first level of recommendation that the NIOSH uses is ”prevent skin contact”, which is defined as “wear appropriate personal protective clothing to prevent skin contact. Suggested barriers for use should be confirmed with the vendor and for additional information and use limitations”. The second NIOSH recommendation frequently used is ”Frostbite”, which is defined as “wear appropriate personal protective clothing to prevent the skin from becoming frozen from contact with the 10 evaporating liquid or from contact with the vessel containing the liquid”. Lastly, the NIOSH recommendation of ”N.R.“ is defined as “no specific recommendation can be made. Actual working conditions will determine the need for personal protective equipment.” These three recommendations do not provide clear guidelines or appropriate personal protective options. This lack of specificity in recommendations for determining glove use for skin protection means this particular guide for chemical protective clothing does not assist in making appropriate glove decisions. Polymer recommendations based solely on pure chemical use, mean that the glove manufacturer (e.g., Ansell), NIOSH, and Forsberg et al. Quick Selection Guide to Chemical Protective Clothing are limited in usage and do not benefit those who use complex chemical mixtures, not in pure form.(5,8,4) These guides do not often publish glove recommendations that include mixed chemical products for commercial or individual use. Examining the individual pure chemicals with a chemical mixture (e.g., using SDS information) may also not be helpful, as combined chemicals may enhance degradation of the gloves. This lack of mixed chemical and glove data creates an opportunity for further study. Hypothesis The MSDS, SDS, NIOSH, Ansell Guide, Forsberg et al. Quick Selection Guide to Chemical Protective Clothing, etc. all provide basic information on glove recommendations for primarily pure chemicals.(13,12,8,5,6) The results of the mixed 11 chemical weight and tensile strength tests will be compared with predicted performance to see if the current accepted standards or guides are adequate in determining polymer material recommendations. The data in these guides will also be used as a basis for comparing and contrasting polymer material recommendations for pure chemicals with complex mixed chemicals. This comparison will help to determine if current degradation testing methods on pure chemicals can be used to predict chemical resistance to complex chemical mixtures. If in comparing polymer material weight and tensile strength to 50 complex-mixed chemical solutions, there are significant differences between the predicted and actual results, then it would stand to reason that mixed-chemical testing should be done. If results conclude that degradation of polymer materials is different than those anticipated based on the pure chemical components, then additional studies could yield a more in-depth database that includes exposure to mixed chemical compositions and provides polymer material ratings for improved glove selection. 12 CHAPTER THREE MATERIALS AND METHODS Polymer Selection The five polymer materials tested were butyl, natural latex, neoprene, nitrile, and vinyl. These materials were chosen because similar non-disposable multi-use gloves of these same compositions appeal to both industrial workers and individual consumers, according to the US Department of Energy.(16) Sheets of the polymer material, rather than actual gloves, were used due to cost restrictions. Each sheet was 1/16 inch (0.16 cm) thick, which is near the actual glove thicknesses for similar products. The polymer material sheets were purchased from MSC Industrial Supply (Melville, NY). Natural latex gloves, which were 1/32 inch thick (0.32 cm) were used because they were less expensive than the sheet material. The brand of latex gloves used was Marigold, Manufacturer model #326Y, purchased from W. W. Grainger, Inc. (Chicago, IL). Each sheet of polymer material and the natural latex gloves were cut into 3.00 x 0.5 inch (7.62 x 1.27 cm) strips, as 155 strips of each material would be needed. The strip size was necessary for tensile strength testing according to methods used by Phalen and Wong (2012).(17) To cut the polymer material into exact 3.00 x 0.5 inch (7.62 x 1.27 cm) strips, a precision die cutting press made by W. R. Sharples Company, Inc. (North Attleboro, MA) was used. The die cutting press was used by placing the polymer materials onto a piece of wood, 13 between layers of paper, and then the die cutting press was placed on top of the material and struck with a mallet, producing exact 3.00 x .005 (7.62 x 1.27 cm) inch strips. Once the material was cut into uniform strips they were placed into humidifiers for a twenty four hour period to ensure uniformity of gravimetric and tensile testing results throughout the study. Chemical Selection Fifty assorted common products (complex mixed chemicals) were chosen. The product names and corresponding manufacturer, hazardous chemical composition information, specific health hazards, recommended PPE, and National Fire Protection Agency (NFPA) ratings for health, flammability, and instability/reactivity are provided in Appendix A. The provided information came from the SDS for each product. These chemicals were chosen because of their potential hazard and expansive range in uses, including pest control, cleaning, degreasing, automotive, and plumbing functions. The polymer materials and chemicals used were paid for or donated by private donors, California State University, San Bernardino Carpool Technicians, California State University, San Bernardino Plumbers, and California State University, San Bernardino Environmental Health Specialists. 14 Equipment A Fisher Scientific (Los Angeles, California) ALF104 analytical balance was used to weigh the strips. A calibrated Marathon Electronic Digital Micrometer with ratchet torque control (CO 030C25, Fisher Scientific, Los Angeles, California) was used to measure thickness. Tensile strength was measured using an Admet Expert 7601 tensiometer (Norwood, Massachusetts) with an eP2 Digital Controller and mechanical force grips. Gravimetric Analysis The test strips of each type of prepared polymer material were weighed using an analytical balance. Then the thickness was measured at three different places on the strips using a digital micrometer. The measurements were taken at the top, middle, and bottom of the strip, with the average of these three measurements calculated and recorded. As these measurements were taken, the polymer materials were also labeled using a numbering system that corresponded to the chemicals that they would be placed in. Five pieces of each polymer were then marked for use as the control and placed into a humidifier to prevent damage due to drying out in room temperature air. The 50 chemicals were poured into separate 15mL glass vials. Each vial was numbered and catalogued so that the contents could be easily identified. On the outside of each vial, the number ”1” was placed on the left side, ”2” was placed on the middle, and ”3” was placed on the right side. Three strips of 15 polymer material samples were then completely submerged into each of the 50 chemically filled 15mL glass vials and the sample polymer material was recorded according to which vial placement position it was placed in: 1, 2, or 3. The polymer material samples were then left to soak in the chemical vial for a period of twenty-four hours. After twenty-four hours the polymer material samples were removed from the vials and rinsed off using distilled water. This rinsing process was to prevent the assigned chemical from continuing to react with the sample and to prevent other containments from interfering with the study. After the polymer material samples were rinsed off, they were pat dried with a paper towel and were left for one hour for the outer surface to air dry. After the drying process was complete, the samples were again weighed and measured using the same process as the initial weighing and measuring. The samples were then placed into a humidifier to prevent further degradation from occurring due to damage that could be caused by the strips drying out in room temperature air. The average of the recorded pre-test weights of each polymer material sample per assigned chemical was then calculated using the formula, (sample polymer material 1 + sample polymer material 2 + sample polymer material 3) / 3 = ”Average Pre-Test Material Weight”. This calculation was repeated using the recorded post-test weights to determine the ”Average Post-Test Weight”. The percentage change in weight of sample polymer material was then calculated 16 using these calculated average weights and the formula, ((“Average Post-Test Weight”-“Average Pre-test Weight”) / ”Average Pre-test Weight” = Percentage Change (%). Tensile Testing First, the five controls for each polymer were tested as described by Phalen and Wong (2011)(18). The controls were taken out of the humidifier and tested using the tensiometer. The tensiometer digitally displayed the tensile strength (in MPa) and elongation at break (in percent). The average was calculated using the formula, (control 1 + control 2 + control 3 +control 4 + control 5) / 5 = “Average Control Tensile Strength”. This data was then recorded. Upon completion of the controls being tested and recorded, the test strips of each chemically exposed polymer material were individually tested, and the tensile strength and elongation at break recorded. The three data points recorded for each of the 50 chemical and polymer combinations were averaged using the formula, (sample polymer material 1 + sample polymer material 2 + sample polymer material 3) / 3 = ”Average Post-Test Tensile Strength”. The percentage change in tensile strength of each polymer material sample per assigned chemical was then calculated using these calculated average posttensile strength data points and the formula, ((“Average Post-Test Tensile Strength”-“Average Control Tensile Strength”) / ”Average Control Tensile Strength” = Percentage Change (%). 17 Mixed- and Pure- Chemical Analysis Determining Pure Chemical Composition Using the SDS The SDS was used to determine the top three hazardous pure chemical ingredients contained within each of the 50 mixed chemical products. These pure chemicals were then recorded and used to predict the chemical resistance of the polymer material. Determining Recommendations Using Available Guidelines The average percent change in weight for each of the 250 combinations of polymer materials and mixed chemical was compared to the Chemical Protective Clothing (Anna, 2003)(11) 5-tier rating system, based on ASTM Method F 471: Excellent (0-10% weight change), Good (11-20% weight change), Fair (21-30% weight change), Poor (31-50% weight change), and Not Recommended (over 50% weight change). This 5-tier system was used to determine polymer recommendation ratings for each of the mixed chemicals so there would be a greater breakdown in performance level than the 3-tier system. The Ansell Guide(5) and the Forsberg et al. Quick Selection Guide to Chemical Protective Clothing(6) were both used to research each pure chemical. These guides use a 3-tier rating systems: Excellent to Good (0-20% weight change), Fair to Poor (21-50% weight change), and Not Recommended (over 50% weight change) to determine polymer recommendation. They also use permeation data in their recommendations, but this is a common practice and 18 one that cannot be evaluated separately. These existing systems were used to determine the polymer recommendation rating for each of the pure chemical ingredients. Determining Degradation Based on Tensile Strength The ANSI/ISEA 105 Standard calculates the performance level of a material that has undergone puncture resistance testing, which is a form of tensile testing.(4) An equivalent test was performed using tensile strength measures instead of puncture resistance measures. The revised rating system was determined by calculating the average percentage change in tensile strength for each of the 50 chemical and polymer material experimental groups in comparison with the appropriate polymer control group. The same rating system as the ANSI/ISEA 105 standard was used, which was based on a 5-tier recommendation system: 4 - Excellent (<20% change), 3 - Good (<40% change), 2 - Fair (<60% change), 1 - Poor (<80% change), and 0 – Not Recommended (>80% change). The average results of the tensile strength tests of the experimental samples compared to the control group were calculated and recorded based on this 5-tier system. The 5-tier system was chosen to fulfill two objectives: 1) evaluating the chemical resistance associated with molecular changes in the polymer structure that would affect tensile properties and 2) providing an additional evaluation to gravimetric analysis, which serves to enhance a correct determination of chemical resistance. Ultimately, both tensile strength and gravimetric analyses will provide a better indication of chemical 19 degradation and result in a more accurate rating system than those currently in use. 20 CHAPTER FOUR RESULTS Gravimetric Analysis Results In total, 750 polymer material samples were tested in 50 different chemical products to determine the impact the chemicals would have on weight change. A significant weight change would indicate a reduction in user protection against the chemical. Table 1 summarizes the weight test results by categorizing the ”Average Pre-test Weight”, ”Average Post-Test Weight”, ”Percentage Change (%)“ and organizing it by ”Chemical” and ”Polymer Material Sample Type”. Table 1 also signifies which polymer per assigned chemical had the least percentage change, by designating the lowest percentage change result with an asterisk (*). For example, the results for Chemical 1 (Diversey’s Speed Track-Clean & Burnish Fragrance Free) clearly show that the butyl polymer material sample had an average pretest weight of 2.0753g, an average posttest weight of 2.0895g, yielding a percentage change equal to 0.68%. This result shows less change than the other polymer material samples; neoprene 0.85%, nitrile 1.04%, vinyl 1.28%, and latex 1.87%. This asterisk (*) designation helps to determine which polymer material option can best resist chemical action of the specific mixed chemical in comparison to the other polymer materials. 21 Table 1: Gravimetric Analysis Results Glove Material Chemical Sample Type Neoprene Butyl 1 Nitrile Vinyl Latex Neoprene Butyl 2 Nitrile Vinyl Latex Neoprene Butyl 3 Nitrile Vinyl Latex Neoprene Butyl 4 Nitrile Vinyl Latex Neoprene Butyl 5 Nitrile Vinyl Latex Neoprene Butyl 6 Nitrile Vinyl Latex Average Pre-Test Weight Average Post-Test Weight Percentage Change (%) 2.2878 2.0753 2.3872 2.2792 1.2224 2.2737 2.0700 2.4226 2.3651 1.1788 2.2820 2.0743 2.4177 2.3387 1.1858 2.2818 2.0816 2.3827 2.2904 1.1174 2.2878 2.0836 2.3706 2.3107 1.1591 2.2736 2.0514 2.3910 2.3230 1.1788 2.3072 2.0895 2.4120 2.3083 1.2453 2.3183 2.1025 2.4618 2.4185 1.4821 2.3147 2.0904 2.4659 2.3034 1.2568 2.2871 2.0999 2.4173 2.3092 1.1260 2.3072 2.1130 2.4173 2.3734 1.2211 2.2766 2.0597 2.4032 2.3441 1.2454 0.85% 0.68% 1.04% 1.28% 1.87% 1.96% 1.57% 1.62% 2.26% 25.73% 1.43% 0.78% 1.99% -1.51% 5.99% 0.23% 0.88% 1.45% 0.82% 0.77% 0.85% 1.41% 1.97% 2.71% 5.35% 0.13% 0.40% 0.51% 0.91% 5.66% 22 * * * * * * Table 1. Continued 7 8 9 10 11 12 13 Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex 2.2637 2.1199 2.5414 2.2708 1.1824 2.2686 2.0659 2.5809 2.2560 1.2591 2.2550 2.0584 2.5976 2.2862 1.2557 2.2823 2.0643 2.5204 2.1848 1.2357 2.2696 2.0491 2.4462 2.2722 1.1611 2.2560 2.0464 2.4611 2.2351 1.1870 2.2477 2.0864 2.4381 2.1396 1.1904 2.2730 2.1290 2.5501 2.2825 1.1971 2.2890 2.0673 2.6187 2.3103 1.1780 2.2637 2.0659 2.6469 2.2451 1.2651 2.3041 2.0820 2.5713 2.3072 1.2908 2.2857 2.0610 2.4823 2.2970 1.1898 2.6942 2.4918 2.9571 2.9996 1.7465 2.2590 2.1013 2.4437 2.1963 1.1991 23 0.41% 0.43% 0.34% 0.52% 1.24% 0.90% 0.07% 1.46% 2.41% -6.44% 0.39% 0.37% 1.90% -1.80% 0.75% 0.96% 0.86% 2.02% 5.60% 4.46% 0.71% 0.58% 1.47% 1.09% 2.47% 19.43% 21.76% 20.15% 34.20% 47.13% 0.50% 0.72% 0.23% 2.65% 0.73% * * * * * * * Table 1. Continued 14 15 16 17 18 19 20 Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex 2.2645 2.0420 2.4849 2.3007 1.2476 2.2789 2.0635 2.5571 2.2708 1.2267 2.2646 2.0574 2.4756 2.2700 1.2526 2.2721 2.0418 2.4995 2.2640 1.2527 2.2838 2.0754 2.4714 2.2370 1.2388 2.2882 2.0700 2.4883 2.2447 1.3066 2.2598 2.0504 2.5092 2.2630 1.1959 2.2778 2.0469 2.5191 2.2714 1.2733 2.7307 2.2816 3.2846 2.5537 1.6949 2.2841 2.0613 2.4923 2.3542 1.2843 3.3877 2.6353 2.6800 2.6573 2.3850 2.3130 2.7950 2.9832 2.7496 1.3488 3.0410 2.3075 2.5507 2.3664 1.4024 2.3225 2.1444 2.6318 2.3291 1.2100 24 0.59% 0.24% 1.38% -1.27% 2.06% 19.83% 10.57% 28.45% 12.46% 38.17% 0.86% 0.19% 0.68% 3.71% 2.53% 49.10% 29.07% 7.22% 17.37% 90.38% 1.28% 34.67% 20.71% 22.91% 8.88% 32.90% 11.48% 2.51% 5.42% 7.33% 2.77% 4.59% 4.88% 2.92% 1.18% * * * * * * * Table 1. Continued 21 22 23 24 25 26 27 Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex 2.2923 2.1437 2.4667 2.2030 1.1404 2.2476 2.0828 2.3984 2.2774 1.1739 2.2564 2.1094 2.4892 2.2032 1.1794 2.2715 2.0724 2.5678 2.2597 1.2271 2.2807 2.1925 2.4858 2.3236 1.2678 2.2461 2.0656 2.3853 2.1619 1.2084 2.2536 2.0863 2.4572 2.3097 1.2881 2.3721 2.1986 2.7016 2.3154 1.2654 4.3777 4.3477 4.2786 4.4669 3.2678 2.2881 2.1808 2.5120 2.2661 1.2458 3.2860 3.5388 3.5937 3.0929 3.0459 2.7210 2.3021 2.6027 2.3982 1.5844 2.2588 2.0711 2.3956 2.1724 1.3197 2.2825 2.3805 2.5086 2.3601 1.4245 25 3.48% 2.56% 9.52% 5.10% 10.96% 94.78% 108.74% 78.40% 96.14% 178.37% 1.40% 3.39% 0.92% 2.86% 5.62% 44.66% 70.76% 39.95% 36.87% 148.23% 19.31% 5.00% 4.70% 3.21% 24.97% 0.57% 0.26% 0.43% 0.49% 9.21% 1.28% 14.10% 2.09% 2.18% 10.59% * * * * * * * Table 1. Continued 28 29 30 31 32 33 34 Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex 2.2721 2.0802 2.4183 2.3671 1.2138 2.2381 2.1253 2.4601 2.2323 1.1985 2.2786 2.0523 2.4321 2.2473 1.1984 2.2553 2.0580 2.4232 2.3153 1.1530 2.2621 2.0816 2.4014 2.2854 1.2725 2.2891 2.0464 2.5081 2.2200 1.1880 2.2748 2.0961 2.4783 2.2286 1.1201 2.3071 2.1500 2.5781 2.4448 1.2995 2.3466 2.2794 2.5732 2.3439 1.5742 4.2623 2.7293 3.3599 3.4277 2.1140 2.9274 2.8473 3.0131 2.8783 1.9059 2.2833 2.0937 2.4172 2.2902 1.2999 3.0587 2.7425 2.7847 2.6430 2.6604 3.0039 3.2226 3.4146 3.2887 3.4174 26 1.54% 3.35% 6.61% 3.28% 7.06% 4.85% 7.25% 4.60% 5.00% 31.34% 87.06% 32.99% 38.14% 52.53% 76.40% 29.80% 38.35% 24.35% 24.32% 65.30% 0.94% 0.58% 0.66% 0.21% 2.15% 33.62% 34.02% 11.03% 19.05% 123.95% 32.05% 53.75% 37.78% 47.57% 205.11% * * * * * * * Table 1. Continued 35 36 37 38 39 40 41 Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex 2.2741 2.0731 2.4939 2.2532 1.2246 2.2748 2.1148 2.4668 2.2255 1.1705 2.2649 2.0911 2.5488 2.2914 1.1782 2.2595 2.0858 2.4694 2.2344 1.2771 2.2748 2.0693 2.4867 2.2357 1.2845 2.2607 2.0884 2.4644 2.2601 1.2478 2.2544 2.0646 2.4438 2.2472 1.2884 3.0398 3.1068 3.6566 3.1354 3.4698 2.3754 2.1415 2.5517 2.2950 1.2809 2.2666 2.0916 2.5685 2.2921 1.1820 2.7057 2.7651 2.7719 2.7420 2.1205 2.3920 3.1212 3.1489 3.1291 2.4995 2.5837 2.0916 2.6369 2.4120 2.4372 2.4628 2.2622 2.6776 2.5519 1.5044 27 33.67% 49.86% 46.62% 39.15% 183.34% 4.42% 1.26% 3.44% 3.12% 9.43% 0.08% 0.02% 0.77% 0.03% 0.32% 19.75% 32.57% 12.25% 22.72% 66.03% 5.15% 50.84% 26.63% 39.96% 94.59% 14.29% 0.15% 7.00% 6.72% 95.32% 9.25% 9.57% 9.57% 13.56% 16.77% * * * * * * * Table 1. Continued 42 43 44 45 46 47 48 Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex 2.2618 2.0975 2.4421 2.2557 1.2448 2.2844 2.0876 2.5064 2.1539 1.2146 2.2809 2.0483 2.5036 2.2309 1.1478 2.2611 2.0662 2.5659 2.2378 1.2749 2.2582 2.0272 2.5925 2.1985 1.1611 2.2602 2.0484 2.5358 2.2422 1.2267 2.2933 2.0726 2.5779 2.2707 1.1478 2.3179 2.2439 2.4634 2.3027 2.2781 2.3660 2.1142 2.5690 2.2035 1.3354 2.2998 2.0519 2.5359 2.2427 1.2178 3.4210 2.5608 2.6204 3.4256 4.5149 2.2794 2.0494 2.6435 2.2523 1.2019 2.3116 2.0753 2.5871 2.3535 1.0797 2.5999 3.1307 3.1286 3.4153 3.1645 28 2.48% 6.98% 0.87% 2.08% 83.01% 3.58% 1.28% 2.50% 2.30% 9.94% 0.83% 0.18% 1.29% 0.53% 6.10% 51.30% 23.94% 2.12% 53.08% 254.15% 0.94% 1.10% 1.97% 2.45% 3.51% 2.28% 1.31% 2.02% 4.96% -11.98% 13.37% 51.05% 21.36% 50.41% 175.71% * * * * * * * Table 1. Continued 49 50 Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex 2.2572 2.0769 2.6380 2.2328 1.1478 2.3117 2.0597 2.6160 2.2647 1.2194 2.3282 2.1330 2.6632 2.2866 1.5048 2.3202 2.1390 2.6922 2.3364 1.3340 3.14% 2.70% 0.96% 2.41% 31.11% 0.37% 3.85% 2.92% 3.17% 9.40% * * Tensile Strength Test Results In total, 750 polymer material samples were tested in 50 chemicals to determine the impact each chemical would have on a polymer material’s tensile strength, signifying a reduction in user protection against the chemical. Table 2 summarizes the tensile strength test results by categorizing the ”Average Pre-test Tensile Strength”, ”Average Post-Test Tensile Strength”, ”Percentage Change (%)“ and organizing it by ”Chemical” and ”Polymer Material Sample Type”. Table 2 also signifies which polymer had the lowest percentage change in tensile strength, by designating the lowest percentage change result with an asterisk (*). For example, the results for Chemical 1 (Diversey’s Speed Track-Clean & Burnish Fragrance Free) clearly show that the butyl polymer material sample had an average pretest tensile strength of 5.8283 MPa, an average posttest tensile strength of 5.8183 MPa, yielding a percentage change 29 equal to -0.17%. This result shows less change than the other polymer material samples; neoprene 1.96%, nitrile 5.02%, vinyl -6.08%, and latex -3.81%. Table 2: Tensile Strength Test Results Glove Material Chemical Sample Type Neoprene Butyl 1 Nitrile Vinyl Latex Neoprene Butyl 2 Nitrile Vinyl Latex Neoprene Butyl 3 Nitrile Vinyl Latex Neoprene Butyl 4 Nitrile Vinyl Latex Neoprene Butyl 5 Nitrile Vinyl Latex Average Control Tensile Strength 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 Average Post-Test Tensile Strength 4.6680 5.8183 2.5993 4.5283 7.3223 4.2787 5.3547 2.2747 4.0700 6.6987 4.7607 5.8447 2.4133 4.4993 8.2990 4.8153 5.9170 2.5663 4.1123 8.0883 4.0653 6.1580 2.5063 5.3523 6.6743 30 Percentage Change (%) 1.96% -0.17% 5.02% -6.08% -3.81% -6.54% -8.13% -8.10% -15.59% -12.00% 3.99% 0.28% -2.50% -6.68% 9.03% 5.18% 1.52% 3.68% -14.71% 6.26% -11.20% 5.66% 1.26% 11.01% -12.32% * * * * * Table 2. Continued 6 7 8 9 10 11 12 Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.7723 5.8773 2.4910 5.9223 9.0487 4.6427 6.3110 2.7050 5.7070 8.6427 4.1807 4.9497 2.5983 3.8457 7.0230 4.3377 6.2650 2.4843 4.3120 7.3650 4.3513 6.6537 2.5410 4.1653 6.0226 4.3427 6.6650 2.6003 4.2607 6.7917 2.3260 6.0440 2.3590 3.7800 5.5045 31 4.24% 0.84% 0.64% 22.83% 18.87% 1.41% 8.28% 9.29% 18.37% 13.54% -8.68% -15.08% 4.98% -20.24% -7.74% -5.25% 7.49% 0.37% -10.57% -3.24% -4.96% 14.16% 2.66% -13.61% -20.88% -5.15% 14.36% 5.06% -11.63% -10.78% -49.19% 3.70% -4.69% -21.60% -27.69% * * * * * * * Table 2. Continued 13 14 15 16 17 18 19 Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.4383 5.7910 2.6157 4.1997 6.7943 4.0310 6.1447 2.5370 4.0303 6.8021 3.4770 5.9840 2.3420 3.9907 6.0083 3.9767 6.1720 2.2737 4.5707 4.1767 2.4010 4.2163 2.3597 4.2743 4.8443 3.8713 4.6670 2.0215 3.0550 6.0610 2.8873 5.6603 2.3777 3.2693 4.3555 32 -3.06% -0.64% 5.68% -12.90% -10.74% -11.95% 5.43% 2.50% -16.41% -10.64% -24.05% 2.67% -5.38% -17.23% -21.07% -13.14% 5.90% -8.14% -5.20% -45.13% -47.56% -27.66% -4.67% -11.35% -36.36% -15.44% -19.93% -18.33% -36.64% -20.38% -36.93% -2.88% -3.94% -32.19% -42.78% * * * * * * * Table 2. Continued 20 21 22 23 24 25 26 Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.1697 5.2650 2.3260 3.7253 6.7103 4.5740 5.5200 2.1280 3.8280 6.5337 0.5910 2.2667 0.3305 1.3693 0.7953 4.6580 6.0703 1.9480 3.8870 7.4953 1.1227 2.4943 0.5140 1.5270 0.8723 2.3347 4.7543 2.5373 4.4110 4.8190 4.3067 5.2880 2.5373 3.3163 7.1290 33 -8.92% -9.67% -6.03% -22.73% -11.85% -0.09% -5.29% -14.03% -20.60% -14.17% -87.09% -61.11% -86.65% -71.60% -89.55% 1.74% 4.15% -21.30% -19.38% -1.53% -75.48% -57.20% -79.23% -68.33% -88.54% -49.00% -18.43% 2.51% -8.51% -36.69% -5.93% -9.27% 2.51% -31.22% -6.35% * * * * * * * Table 2. Continued 27 28 29 30 31 32 33 Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.0513 5.3453 2.2353 4.1447 7.6572 4.5873 5.0443 2.0307 2.1865 7.5177 3.8757 5.9783 1.6285 2.9840 6.2220 1.4977 4.9823 2.0365 3.1483 5.5925 1.7593 2.7463 2.1070 3.6667 4.1900 4.6480 3.2360 2.4405 3.8133 7.6370 1.7717 4.4057 2.1970 3.0880 3.5995 34 -11.51% -8.29% -9.69% -14.04% 0.59% 0.20% -13.45% -17.96% -54.65% -1.24% -15.35% 2.57% -34.21% -38.11% -18.26% -67.29% -14.52% -17.72% -34.70% -26.53% -61.57% -52.88% -14.87% -23.95% -44.96% 1.52% -44.48% -1.40% -20.91% 0.33% -61.30% -24.41% -11.24% -35.95% -52.71% * * * * * * * Table 2. Continued 34 35 36 37 38 39 40 Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 2.0857 6.2113 1.2313 2.1890 1.4117 2.1637 4.8513 1.0370 2.9050 3.6280 2.3337 5.8560 2.1315 3.6523 5.5863 4.9553 4.2190 2.5560 4.3445 7.4987 2.7307 5.3917 2.2170 3.5553 5.2400 3.5600 6.0350 1.9005 3.6173 5.5840 3.0507 6.0950 1.5750 2.7187 1.3150 35 -54.44% 6.57% -50.25% -54.60% -81.45% -52.74% -16.76% -58.10% -39.75% -52.34% -49.03% 0.47% -13.88% -24.25% -26.61% 8.24% -27.61% 3.27% -9.89% -1.49% -40.36% -7.49% -10.43% -26.26% -31.16% -22.24% 3.55% -23.22% -24.97% -26.64% -33.37% 4.58% -36.37% -43.61% -82.72% * * * * * * * Table 2. Continued 41 42 43 44 45 46 47 Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 2.9983 5.7790 2.5540 2.6140 4.2223 3.7003 2.2600 2.2530 2.8410 0.7687 4.0767 4.8803 2.4253 3.7458 6.1627 3.9307 5.6577 2.3030 2.9415 7.2907 3.7087 4.2907 1.4077 1.7203 2.9757 4.5500 4.9803 2.4265 1.6880 7.5480 4.2777 5.1527 2.2567 2.9687 7.1673 36 -34.51% -0.85% 3.18% -45.78% -44.53% -19.18% -61.22% -8.98% -41.08% -89.90% -10.96% -16.27% -2.01% -22.31% -19.04% -14.14% -2.93% -6.96% -38.99% -4.22% -18.99% -26.38% -43.13% -64.32% -60.91% -0.62% -14.55% -1.97% -64.99% -0.84% -6.56% -11.59% -8.83% -38.43% -5.84% * * * * * * * Table 2. Continued 48 49 50 Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex Neoprene Butyl Nitrile Vinyl Latex 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 4.5782 5.8283 2.4752 4.8214 7.6120 3.5510 4.0557 2.3855 3.2640 5.6417 4.2037 6.1710 2.3347 2.2373 3.3283 3.9547 6.2663 2.4100 3.7997 8.2567 37 -22.44% -30.41% -3.62% -32.30% -25.88% -8.18% 5.88% -5.68% -53.60% -56.28% -13.62% 7.52% -2.63% -21.19% 8.47% * * * CHAPTER FIVE DATA ANALYSIS Organizing Results to Establish a New Library To best determine the most appropriate polymer material to minimize a chemical exposure, the data sets were reorganized. Appendix B is a proposed format for a new library that displays both mixed chemical and pure chemical data results and a polymer recommendation. The 50 mixed chemicals are listed down the left side of the table. Usually they would be listed in alphabetical order, but for the ease of data flow within this study they are listed in order of their assigned sample number. Under each mixed chemical are the most abundant SDS pure chemical ingredients that are contained within each mixed chemical product. Across the top of each section are the five polymer material types that were studied. Under the polymer type the ”Test” preformed and ”Percentage Change” is listed for each polymer material’s weight, thickness, tensile strength, and elongation at break. The ”Weight Test” ratings are listed for the polymer’s change in weight in both the mixed chemical and the corresponding pure chemicals. Also listed are the tensile strength ratings of each polymer’s tensile strength test results for each tested mixed chemical. Appendix B also has a column titled ”Recommendation”. In this column the overall usage recommendation for chemical resistance to degradation is listed. To appropriately recommend polymer materials for mixed chemicals, the 38 recommendation is based on a comparison of both the weight test ratings and the tensile strength test ratings, using the most conservative recommendation rating. Although elongation to break and thickness measurements are shown on Appendix B, this data was not used to determine mixed chemical polymer recommendations, as they could not be compared with preexisting methods common to industry. These observed mixed chemical recommendations are based on a 3-tier system: 1. Recommended (both weight and tensile tested at Excellent or Good), a. Weight change within 0% to 20% change b. Tensile strength with Less than 40% change 2. Use Caution (one or both tests received a score rating of Fair or Poor, but neither test received a rating score of Not Recommended), and a. Weight change between 21% and 50%. b. Tensile strength between 41% and 80% change. 3. Not Recommended (one or both tests received a score rating of Not Recommended). a. Weight change greater than 50%. b. Tensile strength greater than 80% change. The recommendation level of the polymer material exposed to the pure chemicals is based on either the Ansell Guide(5) or the Forsberg et al. Quick 39 Selection Guide to Chemical Protective Clothing(6) rating systems. For clarification purposes, on Appendix B this is designated as ”Pure Chemical (Index Guide Rating)”, and is based on the corresponding 3-tier system: Recommended (Excellent to Good, 0-20% weight change), Use Caution (Fair to Poor, 21-50% weight change), and Not Recommended (Not Recommend, over 50% weight change), or the permeation criteria used by the rating system. Pure- and Mixed- Chemical Analysis for Polymer Selection Comparing the recommendation levels of the mixed chemicals to those of the pure chemical ingredients provides an understanding of how the selection based on chemical composition can vary between the two data sets. By analyzing the data in Appendix B, we can compare the ”Recommendation” values of the mixed chemicals to those of the pure chemical components. Appendix B shows that there are 104 mixed chemicals (41.6%) whose polymer material recommendations are the same as the pure chemicals contained within. However, there are 146 polymer material recommendations (58.4%) that vary between the mixed- and pure chemical compositions. This illustrates the lack of agreement between the two methods. In 108 of the 146 above variances (43.2% overall), mixed chemical polymer recommendations are more favorable than those of one or more of the pure chemicals contained within. For example, chemical 1 – Diversey: Speed Track – Clean & Burnish, Fragrance Free contains both sodium 40 dodecylbenezene sulfonate and alcohol ethoxylate. Latex material has a recommendation rating of ”Recommended” when exposed to Diversey: Speed Track – Clean & Burnish, Fragrance Free, whereas, latex has a ”Recommended” rating when exposed to sodium dodecylbenezene sulfonate and a ”Use Caution” rating when exposed to alcohol ethoxylate. This more favorable recommendation rating given to the mixed chemical signifies that the chemical composition changed drastically when combined and that there is less degradation with the final mixed chemical product. In 20 of the 146 above variances (8% overall), the mixed chemical has a lower and less favorable rating than one or more of the pure chemicals contained within. For example, chemical 16 – Sevin: Concentrated Bug Killer contains carbaryl, 1,2-propanediol, and salt. Latex was found to have a ”Use Caution” recommendation when exposed to Sevin: Concentrated Bug Killer. However, the latex polymer material has a ”Recommended” rating for use against exposure to any of the three pure chemical ingredients individually. This lower and less favorable recommendation rating means that the final mixed chemical product demonstrates higher degradation than the individual pure ingredients it contains. It is important to understand the implications of degradation integrity on polymer materials.(19) The 20 variances in mixed chemical and pure chemical recommendations that warrant a lower recommendation level are: chemical 16 – Sevin: Concentrated Bug Killer (latex), chemical 18 – Ranger: Pro-Herbicide (butyl and vinyl), chemical 22 – Main Tech: Penetrating Oil (neoprene, nitrile, and 41 vinyl), chemical 24 – Winner Industrial Supply: EZ Seal (nitrile), chemical 35 – Kingsford Charcoal Lighter Fluid (nitrile), chemical 36 – Henry: Easy Release Adhesive remover (neoprene), chemical 38: Liquid Performance: Spray Cleaner and Polish (latex), chemical 39 – Truefuel: Truefuel 40:1 Engineered Fuel + Oil (butyl and nitrile), chemical 40: Craftsman: Fuel Stabilizer (latex), chemical 42 – Valvoline: DOT 3&4 (butyl and vinyl), chemical 45 – Amazing!: Liquid Fire (neoprene and butyl), chemical 46 – Clorox: Outdoor Bleach Concentrate (vinyl), and chemical 48 – White Lightning: Clean Streaks (nitrile and latex). Finally, in 18 of the 146 above total variances (7.2% overall) the mixed chemical recommendations were both higher and lower than those of their corresponding individual pure chemical ingredients. For example, chemical 12 – Homax: Oops Amazing Remover contains petroleum ether, ethanol, and xylene. When neoprene is exposed to the mixed chemical it has a recommendation rating of ”Use Caution”. However, neoprene material exposed to ethanol is rated at ”Recommended” and both petroleum ether and xylene are rated as ”Not Recommended”. The 18 variances that have mixed chemical recommendations that are both higher and lower than their corresponding pure chemical ingredients are: chemical 12 – Homax: Oops Amazing Remover (neoprene, butyl, and nitrile), chemical 15 – Jasco: Varnish and Stain Remover (nitrile), chemical 17 – Jasco: Paint and Apoxy Cleaner (butyl), chemical 29 – Relton: Rapid Tap (latex), chemical 30 – Weld-On P-70 Primer (butyl), chemical 31 – Ecoline: Dry Teflon (neoprene and butyl), chemical 34 – WD-40 (nitrile), chemical 42 38 – Liquid Performance: Spray Cleaner and Polish (neoprene, butyl, and vinyl), chemical 40 – Craftsman: Fuel Stabilizer (vinyl), chemical 41 – Valvoline: Heavy Duty Brake Parts Cleaner (vinyl and latex), and chemical 49 – Turtle Wax: Bug and Tar Remover (vinyl and latex). Weight and Tensile Strength Data It is important to note differences in polymer material recommendations between weight and tensile strength tests, in comparison to the other polymer materials exposed to the same chemical. Table 3 is a compilation of the 36 chemicals whose polymer material recommendation is exclusively dependent on which test was performed. It is a comparative analysis of the polymer material recommendations denoted by the asterisks shown in Table 1 and Table 2. Table 3: Weight and Tensile Strength Variances in Polymer Recommendation Chemical 2 4 5 6 7 8 9 Best Best Weight Tensile Test Result Test Result Butyl Neoprene Neoprene Butyl Neoprene Nitrile Neoprene Nitrile Nitrile Neoprene Butyl Nitrile Butyl Nitrile 43 Table 3. Continued 10 11 12 13 14 16 19 20 21 22 23 24 25 26 27 29 31 32 34 35 37 38 39 41 43 45 47 48 50 Butyl Butyl Neoprene Neoprene Butyl Butyl Nitrile Latex Butyl Nitrile Nitrile Vinyl Vinyl Butyl Neoprene Nitrile Vinyl Vinyl Neoprene Neoprene Butyl Nitrile Neoprene Neoprene Butyl Nitrile Butyl Neoprene Neoprene Nitrile Nitrile Butyl Butyl Nitrile Vinyl Butyl Nitrile Neoprene Butyl Latex Butyl Nitrile Nitrile Latex Butyl Nitrile Latex Butyl Butyl Latex Butyl Butyl Butyl Nitrile Neoprene Latex Nitrile Nitrile Only 14 chemicals (28%) resulted in the same polymer material recommendations in both the weight and tensile strength testing in comparison to 44 the other polymer materials tested. These 14 chemicals are: chemical 1 – Diversey: Speedtrack Clean and Burnish, fragrance free, chemical 3 - Practical Solutions: Reflecta Natural Floor Cleaner, chemical 15 – Jasco: Varnish & Stain Remover, chemical 17 – Jasco: Paint Epoxy Cleaner, chemical 18 – Ranger: Pro Herbicide, chemical 28 - Nexgen Chemstar Line: Nexbac, chemical 30 - WeldOn: P-70 Primer, chemical 33 – Maxima: Chain Wax, chemical 36 – Henry: Easy Release Adhesive Remover, chemical 40 – Craftsman: Fuel Stabalizer, chemical 42 – Valvoline: Dot 3 & 4, chemical 44 – Clorox: Liquid Plumber, chemical 46 – Clorox: Clorox Bleach, and chemical 49 – Turtle: Bug and Tar Remover. The 36 chemical and polymer material recommendation results, that are dependent on which test was preformed, need to be better analyzed to make a more informed choice for polymer material selection. For example, Table 3 shows that for chemical 2, butyl had the best weight test result, but neoprene had the best tensile test result. Because both weight and tensile strength changes are indicators of degradation and chemical action, it stands to reason that both are important considerations when selecting a polymer material for chemical resistance. Weight and Tensile Strength Ratings for Polymer Selection The mixed chemical polymer recommendations in Appendix B are conservative recommendations based on the lesser (more conservative) rating received from either the weight test rating or the tensile strength test rating. Table 45 3 is a compilation of the 36 chemicals whose polymer material recommendation is dependent on the results of either the weight test or the tensile test independently, not a comparison of the test results with each other. It does not indicate which test result has the better recommendation level and therefore cannot be used to determine which polymer should be used as PPE when handling that chemical. For example, chemical 24 in Table 3 shows that the polymer with the least percentage of change based solely on the results from the weight test was vinyl and based solely on the results of the tensile test was butyl. To determine which polymer material should be considered, one must also know which test result had the best recommendation, which can be seen in Appendix B. With Appendix B, the weight test rating recommendation for the use of vinyl material in the weight test is ”Poor”, but the tensile strength test rating recommendation for the use of butyl in the tensile test is ”Fair”. By looking at these test results independently you may chose the wrong polymer and chose Butyl. By looking at the overall recommendation column in Appendix B, it can be observed that the recommendation level of butyl is actually ”Not Recommended”, which would mean that the vinyl polymer is likely a more appropriate choice for a PPE. This is because the comparison of the weight test and the tensile test results are independent of each other and do not exclusively determine the best choice in polymer material. To determine which material is the most appropriate PPE with regards to chemical degradation resistance, one must consider both the weight and tensile strength test results for each of the polymer materials. 46 In this study there were 45 combinations (18% overall) that resulted in a lower (less favorable) weight test rating than tensile strength rating, meaning that the recommendation was lowered because of a higher percent change in weight than tensile strength. The 45 mixed chemical and polymer material combinations that were affected by the lower weight test rating, and therefore lower recommendation, are: chemical 2 - Practical Solutions: Power Bolt Spray(latex), chemical 12 - Homax: Oops Amazing Remover (butyl, nitrile, vinyl, and latex), chemical 15 – Jasco: Varnish & Stain Remover (nitrile and latex), chemical 17 – Jasco: Paint and Epoxy Cleaner (butyl and latex), chemical 18 – Ranger: ProHerbicide (butyl and vinyl), chemical 19 – Kimball Midwest: Inter-lube Penetrating Grease (neoprene), chemical 22 - Main Tech: Penetrating Oil (butyl and latex), chemical 24 - Winner Industrial Supply: EZ Seal (butyl), chemical 29 – Relton: Rapid Tap (latex), chemical 30 – Weld-On P-70 Primer (neoprene, butyl, nitrile, vinyl, and latex), chemical 31 – Ecoline: Dry Teflon (nitrile, vinyl, and latex), chemical 33 – Maxima: Chain Wax (butyl and latex), chemical 34 – WD40 (butyl), chemical 35 – Kingsford: Charcoal Lighter Fluid (butyl, vinyl, and latex), chemical 38 – Liquid Performance: Spray Cleaner and Polish (butyl, vinyl, and latex), chemical 39 – Truefuel: Truefuel 40:1 Engineered Fuel + Oil (butyl, nitrile, vinyl, and latex), chemical 45 – Amazing! Liquid Fire (neoprene, butyl, vinyl, and latex), and chemical 48 – White Lightning: Clean Streaks (butyl, nitrile, vinyl, and latex). There were 14 combinations (5.6% overall) which resulted in a lower (less favorable) tensile strength rating than weight test rating, meaning that the 47 recommendation was lowered because of a higher percent change in tensile strength than weight. The 14 mixed chemical and polymer material combinations that were affected by the lower tensile strength test rating, and therefore lower recommendation, are: chemical 12 – Homax: Oops Amazing Remover (neoprene), chemical 16 – Sevin: Concentrated Bug Killer (latex), chemical 19 – Kimball Midwest: Inter-lube Penetrating Grease (latex), chemical 25 – Oaty: ABS Cement (neoprene), chemical 36 – Henry: Easy Release Adhesive Remover (neoprene), chemical 40 – Craftsman: Fuel Stabilizer (vinyl), chemical 41 – Valvoline: Heavy Duty Brake Parts Cleaner (vinyl and latex), chemical 42 – Valvoline DOT 3&4 (butyl and vinyl), chemical 43 – Easy Off: Oven Cleaner (vinyl), chemical 45 – Amazing!: Liquid Fire (nitrile), chemical 46 – Clorox: Outdoor Bleach Concentrate (vinyl),and chemical 49 – Turtle Wax: Bug and Tar Remover (vinyl). Out of a possible 250 polymer material and mixed chemical combinations, 191 combinations (76.4% overall) resulted in equal weight and tensile strength ratings, which indicates that there is a level of agreement between the two methods. However, the combined use of both weight change and tensile strength change data has distinct advantages when evaluating resistance to chemical degradation. It is a conservative approach that takes into account the various changes occurring within the polymer that could indicate chemical degradation. The results of this study support this notion. 48 CHAPTER SIX DISCUSSIONS Pure Chemicals and Mixed Chemicals By comparing the recommendation levels, 38 of the 250 mixed chemicals (15.2%) have higher degradation ratings (less favorable) than their respective pure chemicals, and the need for a new library index is made immediately clear. In 104 of the polymer material recommendations that are the same (41.6%), the mixed chemical and corresponding pure chemicals would not alter the final decision on which polymer material to use as a PPE. In 108 of the polymer materials (43.2%) whose mixed chemical recommendation ratings are higher (more favorable) than those of its pure chemicals, we would have less need for caution in glove recommendation. This last scenario is likely due the fact that the pure chemical components in a commercial product are often present at lower concentrations and not in a pure form. Nevertheless, the need for a new index is made clear when comparing the 146 variations that were observed between the predicted ratings using pure chemical components and the actual degradation results for the mixture. The importance of analyzing the 38 combinations that have higher degradation ratings (less favorable recommendations) than their respective pure chemicals is that someone could improperly identify a polymer material to use for a specific chemical product by researching the pure chemical ingredients as they 49 are provided in the Ansell Guide(5) or the Forsberg et al. Quick Selection Guide to Chemical Protective Clothing(6). This means that a polymer deemed as ”Recommended” based on its pure chemical composition may in fact have a recommendation rating of ”Use Caution” or ”Not Recommended” as a mixed chemical in its final product form. This altered chemical composition and increased degradation of the polymer material could result in harmful exposure to the skin if the incorrect material was chosen as a PPE. For example, chemical 46 – Clorox: Outdoor Bleach Concentrate is made up two main pure chemical components according to the SDS: sodium hypochlorite and sodium hydroxide. Individually, the ratings for these two pure chemicals would indicate a recommendation of vinyl gloves. However, actual degradation testing for Clorox: Outdoor Bleach Concentrate results in a vinyl glove listed as ”Use Caution”. This lower recommendation level is likely because of the chemical reaction that occurs when sodium hypochlorite and sodium hydroxide combine. When these two chemicals are combined together sodium hydroxide slows the decomposition of sodium hypochlorite, it also results in a more caustic final chemical with quickened PPE material degradation. This explains why the vinyl polymers showed a greater percent change for both tests after continuous exposure to the final product, rather than the recommendation made by the weight test (or potentially permeation). Without a new rating system, there is no way to foresee that the degradation of the final mixed bleach product is more hazardous to vinyl polymers than its pure chemical ingredients individually. This lack of final mixed 50 chemical information could lead to the use of the wrong polymer materials and result in undue injury, illness or death. Weight versus Tensile Results The Ansell Guide(5) and the Forsberg et al. Quick Selection Guide to Chemical Protective Clothing(6) index systems determine which polymer materials act as the best PPE based primarily on pure chemicals and their corresponding weight and/or permeation test results. The current indexes also do not account for other testing methods, such as the tensile strength tests, which could provide valuable information on the molecular changes occurring within the polymer. Fourteen of the 250 recommendations (5.6%) made for polymer material and mixed chemicals combinations completed in this study were changed due to the tensile strength test results. This demonstrates that tensile strength can play a vital role in choosing the most appropriate polymer material to use when handling a chemical hazard. The Ansell Guide(5) and the Forsberg et al. Quick Selection Guide to Chemical Protective Clothing(6) index systems do not effectively take into account the results of tensile tests and other test methods. This lack of information results in an index that is limited in its scope of PPE recommendations. The more conservative the data sets are that are taken into consideration for PPE recommendations, the less likely that the improper PPE will be chosen. 51 More Conservative Polymer Recommendations The use of conservative recommendations provide improved safety and health standards of practice, more so than those currently implemented in most chemical resistance glove indexes. Additional test results provide for a more accurate and appropriate recommendation of chemical degradation resistance. For example, the butyl polymer material sample gave conflicting results when tested in chemical 24 - Winner Industrial Supply’s EZ Seal. Butyl’s weight test rating is ”Not Recommended” due to a test result of having over 50% change in weight; however, the tensile strength test rating is ”Fair” due to having less than 60% change in tensile strength. Given the knowledge that the polymer material was ”Not Recommended” because of weight test results, the overall recommendation for the polymer is ”Not Recommended” regardless of the ”Fair” tensile strength recommendation. This conservative approach allows for a more practical and protective recommendation, so that a consumer can make a more appropriate decision on the polymer material best for the exposure scenario. Conservative polymer material selection offers the consumer a “safer” glove and more appropriate PPE recommendation. 52 CHAPTER SEVEN CONCLUSIONS The current polymer material indexes on chemical resistance and degradation are lacking critical information and are limited in scope. According to the American Chemical Society, there have been about 89 million chemicals that have been found or manufactured by humans, most of which have been developed in the past several decades.(7) Each of these chemicals must have an SDS sheet that can provide information as to the chemical composition of the product. However, the Ansell Guide has only 167 chemicals listed in its 8th edition,(5) and the Sixth edition Forsberg et al. Quick Selection Guide to Chemical Protective Clothing boasts that it includes information on over 1000 chemicals(6). It is easy to see that there is a large gap between the quantity of products that exist and the number of chemicals that offer PPE recommendations. Singularly depending on weight test results, or permeation data for that matter, for polymer recommendation ratings is not appropriate. If degradation testing of final mixed chemical products were added into the current library system of testing and identifying appropriate PPE materials, then it would still continue to implement mostly weight test based recommendations. By failing to include tensile strength test recommendations, there were 14 combinations (5.6%), out of 250, whose polymer recommendation could have led to injury, illness or death due to the original test results indicating a higher chemical 53 resistance rating and recommendation than the tensile test results warranted. Ultimately, the material was likely affected by the chemical mixture, but this was not detected by gravimetric analysis. Because many of the chemical protective glove products are re-used, tensile testing becomes an important evaluation tool for chemical resistance and degradation. Relying solely on the SDS and the resulting pure chemical compositions to determine polymer recommendation also leads to false polymer recommendation information. By cataloguing pure chemicals and not evaluating the final mixed chemical products, 38 total polymer recommendations out of 250 studied would have been changed. The fact that 15.2% of the polymer material recommendations would change, because the final mixed chemical product has different chemical properties, shows that there is something glaringly wrong with the current system. This study was successful in showing that there are many issues with both the Ansell Guide(5) and the Forsberg et al. Quick Selection Guide to Chemical Protective Clothing(6) glove guide index systems. The new proposed library takes into consideration two types of recommendations: weight and tensile strength. However, the index should be expanded to include known chemical hazards, especially common commercial products and complex mixtures. There is an opportunity for more research and experimental testing methods to minimize chemical exposures and improve the PPE recommendations. The risk for 54 chemical exposure is significant, and can lead to permanent injury, illness or death, so there is urgency in the creation of a new, more inclusive database. 55 APPENDIX A PROPERTIES OF THE 50 MIXED CHEMICALS TESTED 56 Amount of Chemical Product Vial # Chemical Name Used 1 15ml Speedtrack Clean & Burnish (fragrance free) 2 15ml Power Bolt Spray Cleaner 3 15ml 4 15ml 5 15ml 6 15ml 7 15ml 8 15ml 9 15ml 10 15ml 11 15ml 12 15ml 13 15ml 14 15ml 15 15ml 16 15ml 17 Chemical Manufacturer Hazardous Chemicals (weight %) NFPA NFPA NFPA Specific Hazards Health Flammability Instability Recommended PPE Diversey Sodium dodecylbenzene sulfonate, Alcohol ethoxylates 2 0 0 Practical Solutions Alcohol ethoxylates, Monoethanolamine, Propylene glycol 3 0 0 Reflecta Neutral Floor Cleaner Ramsey Wide Rance II (nonacidic washroom cleaner, concentrated) Speedball 200 (heavy duty spray cleaner, concentrated) Virex II 256 (one step disinfectant cleaner and deoderant) Foaming Acid Restroom Cleaner Practical Solutions Practical Solutions Sodium xylene sulfate, Alcohol ethoxylates 2 0 0 Octyl decyl dimethyl ammonium chloride, n-Alkyl dimethyl benzyl ammonium chloride, Nonylphenol ethoxylate, Tetrasodium 3 1 0 Diversey Benzyl alcohol, 2-Butoxyethanol, Diethykene glycol momoethyl ether 1 1 0 eye and skin irritant none required Diversey N-Alkyl dimethyl benzyl ammonium chloride, Didecyl dimethyl ammonium chloride, Ethyl alcohol 3 1 0 Corrosive, eye and Chemical resistant: skin burns, Harmful Goggles, gloves and or fatal if swallowed shoes Diversey Diethylene glycol butyl ether 3 0 0 Strip and Wallpaper and Paste Remover 409 (all purpose cleaner) Tile and Vinyl (floor cleaner) Resolve Triple Oxy Advance Oops Amazing Remover Super Algea Guard Romans golden Diethylene glycol, Alcohols ethoxylated, Harvest Sorbitol, Sodium benzoate 2 1 0 Corrosive, eye and skin burns, Harmful or fatal if swallowed Eye, skin and Inhalation Alkyl, Dimethyl benzyl ammonium chloride, Lauramine oxide Modified Acrylic Polymer, Ethoxylated linear alcohol, Ammoium hydroxide Alcohol ethoxylate, Hydrogen peroxide, Sulfuric acid petroleum ether, xylene, ethanol 1 0 0 1 0 0 eye and skin iritation Chemical resistant goggles and gloves eye irritation Goggles 2 2 0 Skin and eye irritant goggles 3 3 0 Quaternary ammonium compounds, Alkyl dimethyl ethylbenzyl ammonium chloride, Alcohol denat. 3 1 0 Eye, skin and Gloves, goggles and Inhalation respiratory protection Skin and eye irritant Eye, skin, and respiratory protection Super Water clarifier Varnish & Stain Remover aqua chem Clorox Armstrong Resolve Homax Products, Inc. HTH Eye and Skin irritant. May cause burns Corrosive, eye and skin burns, Harmful or fatal if swallowed Skin and eye irritant Chemical-splash goggles and Chemical resistant Gloves Chemical resistant: Goggles, gloves and shoes None under normal use conditions Eye and Skin Burns Chemical resistant goggles and gloves Chemical resistant goggles and gloves Gloves, goggles and respiratory protection Sodium tripolyphosphate, sodium Hydroxide (caustic soda) Toulene, Methanol, Dichloromethane 3 1 0 3 3 0 Concentrated Bug Sevin Killer Carboyl, 1,2-Propanediol, Salt 2 1 1 15ml Paint Apoxy Cleaner Jasco Dichloromethane, Methanol, Stoddard solvent 2 1 0 18 15ml Pro Herbecide Ranger Isopropylamine Salt of Glyphosate , Surfactent 2 1 1 19 15ml Inter-lube Kimball Midwest Paraffinic petroleum distillates, Hexane, Glycol 1 Penetrating Grease 0 0 Skin and eye irritant Eye protection, protective gloves, respiratory equipment Skin and eye irritant Gloogles, protective clothing Skin and eye irrirtant Gloves and goggles 20 15ml Hydraulic Oil Olympus Petroleum distillates, Hydrotreated heavy paraffinic, Zinc alkyl dithiophosphate 1 1 0 Skin, eye, 21 15ml Sizzle Hercules Hydrogen Chloride, Water 3 0 2 Inhalation, eye and skin 22 15ml Penetrating Oil 23 24 15ml 15ml Cold Shield EZ Seal Main Techllc(MT) MT Winner Industrial Supply Petroleum distillates, Sodium sulfate alkyl ether, Polyetoxilated stearilic ether Water, clay mineral, salt Bentonite, Hydrotreated light petroleum distillate 25 15ml ABS Cement Oaty Methyl ethyl ketone, ABS resin, Acetone Jasco 57 Skin and eye irritant Eye, skin, and respiratory protection Skin and Eye Burns Eye, skin, and respiratory protection and other protective clothing Eye, skin and Nitile Gloves, chemical Inhalation restistant goggles, tight fitting clothing Nitrile or neoprene gloves, Chemical Restistant goggles rubber or plastic gloves, full resperator and chemical restistant gloves Gloves and goggles 1 4 0 Skin, eye irrantant 0 1 0 0 0 0 Skin and eye Skin and Eye irratent Gloves and goggles Gloves and goggles 2 3 1 Eyes, skin and inhalation Rubber gloves, Safety goggles and respirator Amount of Chemical Product Chemical Vial # Chemical Name Manufacturer Used 26 15ml Germicidal Bleach Clorox Hazardous Chemicals (weight %) NFPA NFPA NFPA Specific Hazards Health Flammability Instability Sodium hypochlorite, Sodium hydroxide 1 0 0 Eyes and skin irrantant 2‐Butoxyethanol, 1 Ethoxylated alcohol, Tetrapotassium pyrophos phate no hazardous material 1 0 0 Eye and Skin 0 0 Eyes and skin 3 1 1 Eyes and Skin 2 3 0 Eyes and Skin Recommended PPE Rubber gloves or neoprene gloves and safety glasses protective gloves, protective glasses 27 15ml All Purpose Cleaner Simply Green 28 15ml Nexbac 29 15ml Rapid Tap 30 15ml P-70 Primer Nexgen Chemstar Line Relton 1,1,1 -Trichloroethane (methyl chloroform), Glycol Methylene Ether, sec Butanol Weld-On Tetrahydrofuran (THF), Methyl ethyl ketone (MEK), Cyclohexanone 31 15ml Dry Teflon Ecoline Isopropyl alcohol, heptane, Isopropyl alcohol 1 3 0 Eyes and Skin 32 15ml Oasis 266 Ecolab 0 0 Inhalation, eye and skin irritant 33 15ml Chain Wax Maxima poly(oxy-1,2-ethanediyl), alpha-(nonylphenyl)- 1 omega-hydroxy-acetic acid, sodium salt, tetra(ethylenedinitrilo)tetrasodium salt Liquified petroleum, n-Hexane, 2-Propanone 2 3 0 34 15ml WD-40 WD-40 4 0 35 15ml Kingsford 2 0 36 15ml Henry Ethanolamine, 2-butoxyethanol 3 0 0 37 15ml 38 15ml 39 15ml 40 15ml Charcoal Lighter Fluid Easy Realease Adhesive Remover Mole and Gopher Repellent Spray Cleaner and Polish Tru Fuel 40:1 Engineered Fuel + Oil Fuel Stabilizer Aliphatic hydrocarbon, Petroleum base oil, lvp 1 aliphatic hydrocarbon Aliphatic petroleum solvent (100%) 2 eye and skin irritant Chemical resistant: Goggles, gloves and shoes Inhalation, eye and Eye, skin, and skin irritant respiratory protection Inhalation, eye and Chemical resistant skin irritant goggles and gloves Inhalation, eye and Chemical resistant skin irritant goggles and gloves Inhalation, eye and Chemical resistant skin irritant goggles and gloves Inhalation, eye and Chemical resistant skin irritant goggles and gloves Inhalation, eye and Chemical resistant skin irritant goggles and gloves 41 15ml 15ml Heavy Duty Brake Parts Cleaner Dot 3 & 4 Valvoline 42 43 15ml oven cleaner 44 15ml 45 15ml 46 Rubber gloves, Safety goggles if desired None needed Butyl rubber gloves, chemical restant goggles Chemical resisant gloves, chemical goggles Chemical resistant goggles and gloves Sweeney's Caster oil (100%) 2 0 0 Liquid Performance Trufuel Heptane, Acetone, Carbon dioxide 2 2 0 Petroleum distillates, Octane, Pentane 3 2 0 Craftmen Hydrotreated naphthenic oil, Hydroxyethylated 1 aminoethylamide proprietary, Petroleum naphtha xylene, methyl alcohol, carbo dioxide 2 1 0 Inhalation, eye and skin irritant Chemical resistant goggles and gloves 1 0 1 0 Inhalation, eye and skin irritant Inhalation, eye and skin irritant Eye, skin, and respiratory protection Chemical resistant goggles and gloves Easy Off Triethylene glycol monobutyl ether,Diethylene 1 gylcol monobutyl ether, Diethylene glycol monopropyl ether Ethanol, 2-(2-butoxyethoxy), Petroleum gases 3 2 0 Liquid Plummer Clorox Sodium hypochlorite, Sodium hydroxide 3 0 1 Liquid Fire Amazing! Sulfuric Acid, Rodine 31A 3 0 2 15ml Clorox Bleach Clorox Sodium hypochlorite, Sodium hydroxide 1 0 0 Eye, skin and Inhalation Eye, skin and ingestion Eyes, skin and inhalation Eyes, skin and inhalation Long Rubber gloves and safety glasses Safety glasses and gloves Rubber Gloves gloves and safety glasses Rubber or nitrile gloves and safety googles 47 48 15ml 15ml Spray and Wash Cleans Streaks Reckitt White Lightening Hydrogen peroxide, Alcohol ethoxyl Heptane, Propane, Isobutane 2 1 0 0 1 0 49 15ml Bug and Tar Remover Turtle Petroleum disillates, Isopropyl alcohol, Ethylene glycol mono butyl ether 1 2 0 50 15ml 3:1 Oil WD-40 paraffinic petroleum distillate, Naptha, petroleum 1 2 0 Valvoline 58 Eye and skin irritant None needed Eyes, skin and Rubber, nitrile, neoprene inhalation gloves and safety googles Eyes and skin solvent resistant gloves irritant and safety googles eye and skin irritant Gloves and goggles APPENDIX B PROPOSED NEW GLOVE MATERIAL INDEX 59 60 Recommended Recommended Recommendatio n Recommended Use Caution Fair to Poor (21-50%) Excellent to Good (0-20%) Pure Chemical (Index Guide Rating): 2-Butoxyethanol Pure Chemical (Index Guide Rating): Diethylene monoethyl ether Recommended Use Caution Recommended Fair to Poor (21-50%) (0-10%) Excellent Recommended Recommended Recommended Recommended Use Caution (<20%) (0-10%) (<20%) Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent Excellent Recommended Recommended Recommended Recommended (<20%) Excellent Butyl Percent Change (%) 1.41% 0.84% 5.66% 1.99% Recommendatio Tensile Test Rating Weight Test Rating n (0-10%) Fair to Poor (21-50%) Excellent to Good (0-20%) (<20%) Test Weight Thickness Tensil Elongation Excellent Recommendatio n Recommended 1.27% 1.52% -6.33% Excellent Excellent (<20%) (<20%) Excellent Recommended Use Caution -1.14% 3.68% 5.95% Nitrile Percent Change (%) 1.45% Recommended Recommended Excellent (<20%) (<20%) Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent to Good (0-20%) (0-10%) Excellent Recommended Recommended Recommended Recommended (<20%) Excellent Recommended Recommended Excellent (<20%) Use Caution Recommended Excellent (<20%) Recommended Recommended Recommended (<20%) Excellent Excellent (0-10%) Not Recommended (over 50%) Not Recommended (over 50%) Fair to Poor (21-50%) (<20%) Not Recommended Use Cation Not Recommended (0-10%) Not Recommended (over 50%) (<20%) Fair to Poor (21-50%) Fair to Poor (21-50%) Excellent Excellent Use Caution Use Cation Not Recommended (<20%) Excellent Recommended Test Weight Thickness Tensil Elongation (0-10%) Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent Latex Percent Change (%) 0.77% 0.23% 6.26% -1.73% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Excellent (0-10%) Fair to Poor (21-50%) Latex Percent Change (%) 5.99% 3.60% 9.03% 6.15% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Recommended (<20%) (<20%) Excellent Latex Percent Change (%) 5.35% 4.70% -12.32% -2.00% Recommendatio Weight Test Rating Tensile Test Rating n Recommended Use Caution Use Caution Recommended Recommended Latex Percent Change (%) 25.73% 2.41% -12.00% -2.99% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Fair Use Caution (21-30%) (<20%) Fair to Poor Use Caution (21-50%) Excellent to Good Recommended (0-20%) Fair to Poor Use Caution (21-50%) Test Weight Thickness Tensil Elongation (0-10%) Excellent to Good (0-20%) Fair to Poor (21-50%) Excellent Latex Percent Change (%) 1.87% 1.58% -3.81% -0.27% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Vinyl Percent Change (%) 2.71% -0.16% 11.01% 9.21% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation (0-10%) Fair to Poor (21-50%) Excellent to Good (0-20%) Thickness Tensil Elongation Test Weight Excellent (0-10%) Excellent to Good (0-20%) Vinyl Percent Change (%) -1.51% -0.77% -6.68% 4.31% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Excellent Nitrile Percent Change (%) 1.97% -0.62% 1.26% 6.56% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation (0-10%) Fair to Poor (21-50%) Excellent to Good (0-20%) Thickness Tensil Elongation Test Weight Excellent (0-10%) Excellent to Good (0-20%) Nitrile Percent Change (%) 1.99% -0.27% -2.50% 0.12% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Recommended Recommended Recommended Vinyl Percent Change (%) 2.26% 0.14% -15.59% -5.03% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Fair to Poor Use Cation (21-50%) Test Weight Thickness Tensil Elongation (0-10%) Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent Vinyl Percent Change (%) 1.28% 0.59% -6.08% -5.66% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Vinyl Percent Change (%) 0.82% -0.45% -14.71% -3.42% Recommendatio Recommendatio Tensile Test Rating Weight Test Rating Tensile Test Rating Weight Test Rating Tensile Test Rating n n Excellent Recommended Excellent Excellent Recommended Excellent Excellent Butyl Percent Change (%) 0.88% Thickness Tensil Elongation Recommended Recommended Test Weight Excellent (0-10%) Excellent to Good (0-20%) Butyl Percent Change (%) 0.78% 1.08% 0.28% 13.21% Recommendatio Tensile Test Rating Weight Test Rating n Test Weight Thickness Tensil Elongation Recommended Recommended Recommended Nitrile Percent Change (%) 1.62% -0.62% -8.10% -8.96% Recommendatio Weight Test Rating Tensile Test Rating n Recommended Excellent Excellent (<20%) (0-10%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Excellent (0-10%) Excellent to Good (0-20%) Excellent to Good (0-20%) (<20%) Nitrile Percent Change (%) 1.04% -0.99% 5.02% 0.55% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Excellent Butyl Percent Change (%) 1.57% 1.04% -8.13% 3.78% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation (0-10%) Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent Butyl Percent Change (%) 0.68% 0.11% -0.17% -12.33% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Tensile Test Rating Weight Test Rating Excellent (<20%) Neoprene Percent Change (%) 0.85% 1.17% -11.20% -3.15% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation (0-10%) Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent Weight Test Rating 0.00% 5.18% -1.55% Neoprene Percent Change (%) 0.23% Pure Chemical (Index Guide Rating): Benzyl alcohol Mixed Chemical: Diversey: Speedball 200-Heavy Duty Spray Cleaner Conc Diversey: Speedball 200-Heavy Duty Spray Cleaner Conc (Experimental Chemical 5) Mixed Chemical: Practical Solutions: Ramsey Wide RangeII Non Acidic Washroom Cleaner Conc Pure Chemical (Index Guide Rating): Octyl Decyl Dimethyl Ammonium-Chloride Pure Chemical (Index Guide Rating): N-Alkyl dimethyl benzylammonium-chloride Thickness Tensil Elongation Practical Solutions: Ramsey Wide RangeII Non Acidic Washroom Cleaner Conc (Experimental Chemical 4) Test Weight Recommended Recommended Excellent (0-10%) Excellent to Good (0-20%) Test Weight Thickness Tensil Elongation Mixed Chemical: Practical Solutions: Reflecta Neutral Floor Cleaner Pure Chemical (Index Guide Rating): Alcohol ethoxylate Mixed Chemical: Practical Solutions: PowerBolt Spray Pure Chemical (Index Guide Rating): Alcohol ethoxylate Pure Chemical (Index Guide Rating): Monoethanolamine Pure Chemical (Index Guide Rating): Propylene glycol Neoprene Percent Change (%) 1.43% 1.10% 3.99% 11.01% Recommendatio Weight Test Rating Tensile Test Rating n (<20%) Excellent Practical Solutions: Reflecta Neutral Floor Cleaner (Experimental Chemical 3) Recommended Recommended Recommended Neoprene Percent Change (%) 1.96% 1.68% -6.54% -4.16% Recommendatio Weight Test Rating Tensile Test Rating n Recommended Excellent Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Use Caution Fair to Poor (21-50%) Test Weight Thickness Tensil Elongation (0-10%) Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent Neoprene Percent Change (%) 0.8509 1.168 1.96% -0.31% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Practical Solutions: PowerBolt Spray (Experimental Chemical 2) Mixed Chemical: Diversey, Speed Track-Clean & Burnish Fragrance Free Pure Chemical (Index Guide Rating): Sodium dodecylbenzene sulfonate Pure Chemical (Index Guide Rating): Alcohol ethoxylate Diversey, Speed Track-Clean & Burnish Fragrance Free (Experimental Chemical 1) 61 Recommended Recommended Pure Chemical (Index Guide Rating): Ethoxylated linear alcohol Pure Chemical (Index Guide Rating): Ammoium hydroxide Modified acrylic polymer Pure Chemical (Index Guide Rating): Mixed Chemical: Armstrong: Tile and Vinyl Floor Cleaner Armstrong: Tile and Vinyl Floor Cleaner (Experimental Chemical 10) Mixed Chemical: Clorox: 409 All Purpose Cleaner Pure Chemical (Index Guide Rating): Alkyl Pure Chemical (Index Guide Rating): Dimethyl benzyl ammonium chloride Pure Chemical (Index Guide Rating): Lauramine oxide Neoprene Percent Change (%) 0.39% 0.01% -5.25% 9.00% Recommendatio Weight Test Rating Tensile Test Rating n Clorox: 409 All Purpose Cleaner (Experimental Chemical 9) Use Caution Recommended Not Not recommended (over 50%) Recommended Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) -20.85% Recommendatio Weight Test Rating n Excellent Recommended (0-10%) Excellent (<20%) Recommended Recommended Recommended (<20%) Recommended Recommended Recommended Excellent (<20%) Recommended Recommended Recommended (<20%) Elongation Weight Thickness Tensil Test 0.86% 0.66% 14.16% Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent to Good (0-20%) Recommended Recommended Recommended Excellent (<20%) Recommended Recommended Recommended Excellent (<20%) Recommended Recommended Recommended (<20%) Recommended Excellent (<20%) (<40%) Recommended Recommended Recommended Excellent (<20%) Recommended Recommended Recommended Excellent (<20%) Not Recommended Recommended Recommended (<20%) Elongation Weight Thickness Tensil Test 5.60% 0.95% -13.61% Not recommended Not (over 50%) Recommended Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Elongation Weight Thickness Tensil Test Excellent (<20%) 4.34% Recommendatio n Recommended 4.46% 1.89% -20.88% Excellent (<20%) Good (<40%) Tensile Test Rating Latex Percent Change (%) Not Not recommended (over 50%) Recommended Fair to Poor Use Caution (21-50%) Fair to Poor Use Caution (21-50%) Excellent (0-10%) Tensile Test Rating Weight Test Rating Vinyl Percent Change (%) Excellent (<20%) Recommended Excellent (0-10%) Not Not recommended Recommended (over 50%) Fair to Poor Use (21-50%) Caution Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation (0-10%) Excellent to Good (0-20%) Not Recommended (Over 50%) Excellent to Good (0-20%) Latex Percent Change (%) -6.44% 2.97% -7.74% -1.62% Recommendatio Weight Test Rating Tensile Test Rating n Recommended Excellent Excellent Test Weight Thickness Tensil Elongation Excellent (0-10%) Excellent to Good (0-20%) Excellent to Good (0-20%) Recommended Excellent (0-10%) Not recommended Not Recommended (over 50%) Fair to Poor Use (21-50%) Caution Excellent to Good Recommended (0-20%) (<40%) (<20%) Latex Percent Change (%) 0.75% 0.33% -3.24% 2.67% Recommendatio Weight Test Rating Tensile Test Rating n Use Caution Recommended Recommended Not Recommended Use Caution Not Recommended Latex Percent Change (%) 1.24% 0.15% 13.54% -8.42% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation (0-10%) Not Recommended (over 50%) Not Recommended (over 50%) Fair to Poor (21-50%) Latex Percent Change (%) 5.66% 25.52% 18.87% -5.08% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent Test Weight Thickness Tensil Elongation Vinyl Percent Change (%) -1.80% -0.09% -10.57% -11.31% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Fair to Poor (21-50%) Excellent to Good (0-20%) (0-10%) Excellent to Good (0-20%) Vinyl Percent Change (%) 2.41% 0.92% -20.24% -26.67% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Good Test Weight Thickness Tensil Elongation Excellent (0-10%) Excellent to Good (0-20%) Excellent to Good (0-20%) 210.84% Recommendatio Tensile Test Rating Weight Test Rating n Recommended Excellent Excellent (0-10%) (<20%) 2.02% -0.15% 2.66% Elongation Nitrile Percent Change (%) Weight Thickness Tensil Use Caution Recommended Recommended Test Excellent (0-10%) Excellent to Good (0-20%) Fair to Poor (21-50%) Excellent to Good (0-20%) Nitrile Percent Change (%) 1.90% 0.16% 0.37% 6.38% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Excellent to Good (0-20%) (0-10%) Excellent to Good (0-20%) Nitrile Percent Change (%) 1.46% -0.19% 4.98% 6.74% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Excellent Recommended Test Weight Thickness Tensil Elongation Excellent (0-10%) Excellent to Good (0-20%) Excellent to Good (0-20%) Use Caution Recommended Use Caution Vinyl Percent Change (%) 0.52% 0.14% 18.37% -10.36% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Fair to Poor (21-50%) Excellent to Good (0-20%) Use Caution Recommended (0-10%) Fair to Poor (21-50%) (<20%) Vinyl Percent Change (%) 0.91% 48.73% 22.83% -1.25% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Good Test Weight Thickness Tensil Elongation Use Caution Nitrile Percent Change (%) 0.34% -0.25% 9.29% 17.61% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Fair to Poor (21-50%) Excellent to Good (0-20%) Fair to Poor (21-50%) (0-10%) Nitrile Percent Change (%) 0.51% -0.48% 0.64% -4.22% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent Test Weight Thickness Tensil Elongation 35.02% Recommendatio Tensile Test Rating Weight Test Rating n Excellent Excellent Recommended (<20%) (0-10%) Not Recommended Not Recommended (over 50%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Butyl Percent Change (%) Recommended Excellent (0-10%) Not Not recommended Recommended (over 50%) Fair to Poor Use Caution (21-50%) Excellent to Good Recommended (0-20%) Butyl Percent Change (%) 0.37% 0.93% 7.49% 6.63% Recommendatio Tensile Test Rating Weight Test Rating n Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Excellent to Good (0-20%) (0-10%) Excellent to Good (0-20%) Butyl Percent Change (%) 0.07% 0.39% -15.08% 1.56% Recommendatio Tensile Test Rating Weight Test Rating n Excellent Recommended Excellent Test Weight Thickness Tensil Elongation Excellent (0-10%) Excellent to Good (0-20%) Excellent to Good (0-20%) Butyl Percent Change (%) 0.43% 0.58% 8.28% 11.79% Recommendatio Tensile Test Rating Weight Test Rating n Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent to Good (0-20%) (0-10%) Butyl Percent Change (%) 0.40% 0.15% 0.84% 1.03% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent Test Weight Thickness Tensil Elongation 5.15% Recommendatio Tensile Test Rating Weight Test Rating n Excellent Excellent Recommended (<20%) (0-10%) 0.96% 0.40% -4.96% Weight Thickness Tensil Elongation Neoprene Percent Change (%) Test Excellent Recommended (0-10%) Not Not recommended Recommended (over 50%) Fair to Poor Use (21-50%) Caution Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Fair to Poor (21-50%) Excellent to Good (0-20%) (<20%) Pure Chemical (Index Guide Rating): Alcohols ethoxylated Pure Chemical (Index Guide Rating): Sodium benzoate Recommended (0-10%) Excellent to Good (0-20%) Neoprene Percent Change (%) 0.90% 1.24% -8.68% 20.66% Recommendatio Tensile Test Rating Weight Test Rating n Excellent Excellent Recommended Test Weight Thickness Tensil Elongation Excellent (0-10%) Excellent to Good (0-20%) Excellent to Good (0-20%) Mixed Chemical: Romans Golden Harvest: Strip and Wall Paper & Paste Remover Pure Chemical (Index Guide Rating): Diethylene glycol Romans Golden Harvest: Strip and Wall Paper & Paste Remover (Experimental Chemical 8) Recommended Mixed Chemical: Diversey: Foaming Acid Restroom Cleaner Pure Chemical (Index Guide Rating): Diethylene glycol butyl ether Pure Chemical (Index Guide Rating): Phosphoric acid Excellent (<20%) Neoprene Percent Change (%) 0.41% -0.03% 1.41% 17.28% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Diversey: Foaming Acid Restroom Cleaner (Experimental Chemical 7) Recommended Recommended Excellent to Good (0-20%) Excellent to Good (0-20%) (<20%) Pure Chemical (Index Guide Rating): Didecyl dimethyl ammonium chloride Pure Chemical (Index Guide Rating): Ethyl alcohol Recommended Excellent to Good (0-20%) (0-10%) Neoprene Percent Change (%) 0.13% -0.46% 4.24% 1.05% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Excellent Recommended Test Weight Thickness Tensil Elongation Pure Chemical (Index Guide Rating): N-Alkyl dimethyl benzyl ammonium chloride Mixed Chemical: Diversey: Virex II 256 One Step Disinfectant Cleaner and Deoderant Diversey: Virex II 256 One Step Disinfectant Cleaner and Deoderant (Experimental Chemical 6) 62 Neoprene Percent Change (%) 19.83% 8.99% -24.05% -12.55% Recommendatio Weight Test Rating Tensile Test Rating n Good Recommended Good (11-20%) (<40%) Fair to Poor Use Caution (21-50%) Data Fair to Poor Use Caution (21-50%) Data Not recommended (over 50%) Pure Chemical (Index Guide Rating): Alcohol denat Jasco: Varnish & Stain Remover (Experimental Chemical 15) Mixed Chemical: Jasco: Varnish & Stain Remover Pure Chemical (Index Guide Rating): Toulene Pure Chemical (Index Guide Rating): Methanol Pure Chemical (Index Guide Rating): Dichloromethane Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Pure Chemical (Index Guide Rating): Alkyl dimethyl ethylbenzyl ammonium chloride Not Recommended Recommended Recommended Excellent to Good (0-20%) Mixed Chemical: Aqua Chem: Super Water Clarifier Pure Chemical (Index Guide Rating): Quaternary ammonium compounds Recommended Recommended Recommended Recommendatio n Recommended Excellent (<20%) Thickness Tensil Elongation Test Weight Excellent to Good (0-20%) Fair to Poor (21-50%) Excellent (0-10%) No Data 0.11% 5.43% 19.96% Fair to Poor (21-50%) Use Caution Recommended Excellent (<20%) Not recommended (over 50%) Not Recommended Butyl Percent Change (%) 10.57% 5.75% 2.67% -17.33% Recommendatio Weight Test Rating Tensile Test Rating n Good Recommended Excellent (11-20%) (<20%) Not recommended Not (over 50%) Recommended Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Excellent (<20%) Recommended Recommended Recommended Recommendatio n Recommended 1.47% -0.15% 5.06% 16.92% Excellent (<20%) Thickness Tensil Elongation Test Weight Fair to Poor (21-50%) Excellent (0-10%) No Data Not Recommended (over 50%) Use Caution Not Recommended No Data Recommendatio n Recommended Excellent (<20%) Not recommended (over 50%) Not Recommended Nitrile Percent Change (%) 28.45% 5.54% -5.38% -2.61% Recommendatio Weight Test Rating Tensile Test Rating n Fair Use Excellent (21-30%) Caution (<20%) Fair to Poor Use (21-50%) Caution Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Fair to Poor (21-50%) Excellent (0-10%) No Data Not Recommended (over 50%) -1.71% 2.50% 8.94% Excellent (<20%) Excellent (<20%) Vinyl Percent Change (%) 34.20% 17.97% -21.60% -6.89% Recommendatio Tensile Test Rating n Use Good Caution (<40%) Not Recommended Not Recommended Not Recommended Recommended Recommended Recommended Recommendatio n Recommended Not Recommended Use Caution No Data Recommended Excellent (<20%) Not Recommended Use Caution No Data Recommended Excellent (<20%) Vinyl Percent Change (%) 12.46% 1.90% -17.23% -27.90% Recommendatio Weight Test Rating Tensile Test Rating n Good Recommended Excellent (11-20%) (<20%) Not recommended Not (over 50%) Recommended Excellent to Good Recommended (0-20%) Not Recommended Not (over 50%) Recommended Test Weight Thickness Tensil Elongation Fair to Poor (21-50%) Not Recommended (over 50%) Excellent (0-10%) No Data Test Weight Fair to Poor (21-50%) Not Recommended (over 50%) Excellent (0-10%) No Data Excellent (<20%) Latex Percent Change (%) 47.13% 14.22% -27.69% -19.96% Recommendatio Tensile Test Rating n Use Good Caution (<40%) Not Recommended Not Recommended Not Recommended Recommended Use Caution Recommended Recommended Not Recommended Recommended No Data Recommended Excellent (<20%) Not Recommended Recommended No Data Recommended Excellent (<20%) Not recommended (over 50%) Not Recommended Latex Percent Change (%) 38.17% 12.48% -21.07% -21.50% Recommendatio Weight Test Rating Tensile Test Rating n Poor Use Good (31-50%) Caution (<40%) Not recommended Not (over 50%) Recommended Fair to Poor Use (21-50%) Caution Test Weight Thickness Tensil Elongation Not recommended (over 50%) Excellent to Poor (0-20%) Excellent (0-10%) No Data Latex Percent Change (%) 2.06% 1.62% -10.64% -19.18% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Not recommended (over 50%) Excellent to Poor (0-20%) Excellent (0-10%) No Data Latex Percent Change (%) 0.73% 0.08% -10.74% -11.55% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Poor (31-50%) Not recommended (over 50%) Not recommended (over 50%) Not recommended (over 50%) Weight Test Rating Test Weight Thickness Tensil Elongation Excellent (0-10%) Fair to Poor (21-50%) Excellent to Good (0-20%) Excellent to Good (0-20%) Weight Thickness Tensil Elongation Test Latex Percent Change (%) 2.47% 1.32% -10.78% -4.09% Recommendatio Tensile Test Rating Weight Test Rating Tensile Test Rating n Vinyl Percent Change (%) 2.65% -0.60% -12.90% -21.70% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Poor (31-50%) Not recommended (over 50%) Not recommended (over 50%) Not recommended (over 50%) Weight Test Rating Test Weight Thickness Tensil Elongation Excellent (0-10%) Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent to Good (0-20%) 1.09% 0.55% -11.63% -10.07% Vinyl Percent Change (%) Vinyl Percent Change (%) -1.27% Thickness -0.42% Tensil -16.41% Elongation -8.49% Recommendatio Tensile Test Rating Weight Test Rating Tensile Test Rating n Nitrile Percent Change (%) 1.38% Use Caution Not Recommended No Data Recommended Nitrile Percent Change (%) 0.23% -1.20% 5.68% 6.25% Recommendatio Tensile Test Rating Weight Test Rating n Test Weight Thickness Tensil Elongation Weight Thickness Tensil Elongation Test Tensile Test Rating Weight Test Rating Nitrile Percent Change (%) Nitrile Percent Change (%) 20.15% 10.37% -4.69% -2.20% Recommendatio Weight Test Rating Tensile Test Rating n Fair Use Excellent (21-30%) Caution (<20%) Excellent to Good Recommended (0-20%) Fair to Poor Use (21-50%) Caution Not Not recommended (over 50%) Recommended Test Weight Thickness Tensil Elongation Excellent (0-10%) Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent to Good (0-20%) Tensile Test Rating Weight Test Rating Butyl Percent Change (%) 0.24% Recommended Use Caution No Data Recommended Butyl Percent Change (%) 0.72% -0.77% -0.64% 25.63% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Weight Thickness Tensil Elongation Test Tensile Test Rating Weight Test Rating Butyl Percent Change (%) 21.76% 12.02% 3.70% 28.20% Recommendatio Weight Test Rating Tensile Test Rating n Fair Use Excellent (21-30%) Caution (<20%) Not recommended Not (over 50%) Recommended Excellent to Good Recommended (0-20%) Not recommended Not (over 50%) Recommended Test Weight Thickness Tensil Elongation Excellent (0-10%) Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent to Good (0-20%) 0.58% 0.55% 14.36% 7.96% Butyl Percent Change (%) Recommendatio Tensile Test Rating Weight Test Rating n Excellent Excellent Recommended (<20%) (0-10%) No No Data Data 0.51% -11.95 -26.13% Thickness Tensil Elongation Excellent (<20%) Recommendatio Weight Test Rating n Excellent Recommended (0-10%) No No Data Data Neoprene Percent Change (%) 0.59% Recommended Recommended No Data Recommended Test Weight Excellent to Good (0-20%) Aqua Chem: Super Water Clarifier (Experimental Chemical 14) Excellent to Good (0-20%) Pure Chemical (Index Guide Rating): Alcohol denat Excellent (0-10%) No Data Neoprene Percent Change (%) 0.50% -0.36% -3.06% -2.71% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Pure Chemical (Index Guide Rating): Alkyl dimethyl ethylbenzyl ammonium chloride Mixed Chemical: HTH: Super Algea Guard Pure Chemical (Index Guide Rating): Quaternary ammonium compounds HTH: Super Algea Guard (Experimental Chemical 13) Mixed Chemical: Homax: Oops Amazing Remover Pure Chemical (Index Guide Rating): Petroleum ether Pure Chemical (Index Guide Rating): Ethanol Pure Chemical (Index Guide Rating): Xylene Neoprene Percent Change (%) 19.43% 9.61% -49.19% -28.78% Recommendatio Weight Test Rating Tensile Test Rating n Good Use Fair (11-20%) Caution (<60%) Not recommended Not (over 50%) Recommended Excellent to Good Recommended (0-20%) Not recommended Not (over 50%) Recommended Test Weight Thickness Tensil Elongation Excellent (<20%) Homax: Oops Amazing Remover (Experimental Chemical 12) Recommended Recommended Recommended Weight Thickness Tensil Elongation Test Tensile Test Rating Weight Test Rating Excellent (0-10%) Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent to Good (0-20%) Recommendatio n Recommended 0.71% 0.49% -5.15% 15.37% Weight Thickness Tensil Elongation Weight Test Rating Neoprene Percent Change (%) Test Mixed Chemical: Resolve: Triple Oxy Advance Pure Chemical (Index Guide Rating): Alcohol ethoxylate Pure Chemical (Index Guide Rating): Hydrogen peroxide Pure Chemical (Index Guide Rating): Salts Resolve: Triple Oxy Advance (Experimental Chemical 11) 63 Not Recommended Not Recommended Recommended Excellent (<20%) Excellent (0-10%) Not recommended (over 50%) Not recommended (over 50%) Excellent to Good (0-20%) Mixed Chemical: Olympus: Hydrolic Oil Pure Chemical (Index Guide Rating): Petroleum distillates Pure Chemical (Index Guide Rating): Hydrotreated heavy paraffinic petroleum Pure Chemical (Index Guide Rating): Zinc alkyldithiophosphate Recommended Neoprene Percent Change (%) 2.77% 1.09% -8.92% -20.39% Recommendatio Tensile Test Rating Weight Test Rating n Test Weight Thickness Tensil Elongation Olympus: Hydrolic Oil (Experimental Chemical 20) Mixed Chemical: Kimball Midwest: Inter-lube Penetrating Grease Pure Chemical (Index Guide Rating): Paraffinic petroleum distillate Pure Chemical (Index Guide Rating): Hexane Pure Chemical (Index Guide Rating): Glycol Neoprene Percent Change (%) 32.90% 9.65% -36.93% -33.34% Recommendatio Weight Test Rating Tensile Test Rating n Poor Use Good (31-50%) Caution (<40%) Not recommended Not (over 50%) Recommended Not recommended Not (over 50%) Recommended Fair to Poor Use (21-50%) Caution Test Weight Thickness Tensil Elongation Kimball Midwest: Inter-lube Penetrating Grease (Experimental Chemical 19) Mixed Chemical: Ranger: Pro-Herbecide Pure Chemical (Index Guide Rating): Isopropylamine salt of glyphosate Pure Chemical (Index Guide Rating): Surfactants Use Caution Use Caution Fair (<60%) Neoprene Percent Change (%) 1.28% 0.33% -15.44% -31.87% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Fair to Poor (21-50%) Test Weight Thickness Tensil Elongation Fair to Poor (21-50%) Pure Chemical (Index Guide Rating): Stoddard solvent Ranger: Pro-Herbicide (Experimental Chemical 18) Use Caution Not Recommended Not (over 50%) Recommended Poor (31-50%) Neoprene Percent Change (%) 49.10% 16.97% -47.56% -24.71% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Neoprene Percent Change (%) 0.86% 1.46% -13.14% -36.09% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Pure Chemical (Index Guide Rating): Methanol Pure Chemical (Index Guide Rating): Dichloromethane Jasco: Paint and Epoxy Cleaner Mixed Chemical: Jasco: Paint and Epoxy Cleaner (Experimental Chemical 17) Mixed Chemical: Sevin: Concentrated Bug Killer Pure Chemical (Index Guide Rating): Carboyl Pure Chemical (Index Guide Rating): 1,2-Propanediol Pure Chemical (Index Guide Rating): Salt Sevin: Concentrated Bug Killer (Experimental Chemical 16) Not Recommended Recommended Not Recommended Use Caution Good (<40%) Butyl Percent Change (%) 11.48% 4.26% -2.88% 2.48% Recommendatio Tensile Test Rating n Recommended Excellent (<20%) Not Recommended Not Recommended Recommended Excellent Recommended (0-10%) Not recommended Not (over 50%) Recommended Not recommended Not (over 50%) Recommended Fair to Poor Use (21-50%) Caution Excellent (<20%) Butyl Percent Change (%) 4.59% 2.28% -9.67% -10.86% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Good (11-20%) Not recommended (over 50%) Not recommended (over 50%) Excellent to Good (0-20%) Weight Test Rating Test Weight Thickness Tensil Elongation Butyl Percent Change (%) 34.67% 26.10% -19.93% 10.55% Recommendatio Weight Test Rating Tensile Test Rating n Poor Use Excellent (31-50%) Caution (<20%) Excellent to Good Recommended (0-20%) Fair to Poor Use Caution (21-50%) Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Not Recommended (over 50%) Fair (21-30%) Not Recommended (over 50%) Butyl Percent Change (%) 29.07% 21.22% -27.66% 30.85% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Butyl Percent Change (%) 0.19% 0.07% 5.90% 16.80% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Recommended Not Recommended Not Recommended Recommended Excellent (<20%) Excellent (0-10%) Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent to Good (0-20%) Recommended Recommended Recommended Recommended Excellent (<20%) Nitrile Percent Change (%) 4.88% 0.22% -6.03% 52.92% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Nitrile Percent Change (%) 2.51% -1.12% -3.94% 23.64% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Nitrile Percent Change (%) 20.71% 1.03% -18.33% -8.25% Recommendatio Weight Test Rating Tensile Test Rating n Good Recommended Excellent (11-20%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Excellent (0-10%) Not Recommended (over 50%) Not Recommended (over 50%) Nitrile Percent Change (%) 7.22% 0.44% -4.67% 21.00% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Nitrile Percent Change (%) 0.68% -0.39% -8.14% 16.44% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Use Caution Not Recommended Not Recommended Recommended Excellent (<20%) Excellent (0-10%) Not recommended (over 50%) Not recommended (over 50%) Excellent to Good (0-20%) Not Recommended Not Recommended Recommended Recommended Good (<40%) Vinyl Percent Change (%) 2.92% 0.04% -22.73% -23.11% Recommendatio Tensile Test Rating Weight Test Rating n Test Weight Thickness Tensil Elongation Vinyl Percent Change (%) 5.42% 0.97% -32.19% -35.12% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Good (0-10%) (<40%) Not recommended Not (over 50%) Recommended Not recommended Not (over 50%) Recommended Fair to Poor Use (21-50%) Caution Test Weight Thickness Tensil Elongation Vinyl Percent Change (%) 22.91% 2.16% -36.64% -28.22% Recommendatio Weight Test Rating Tensile Test Rating n Poor Use Good (31-50%) Caution (<40%) Excellent to Good Recommended (0-20%) Fair to Poor Use Caution (21-50%) Test Weight Thickness Tensil Elongation Fair to Poor (21-50%) Good (11-20%) Not Recommended (over 50%) Not Recommended (over 50%) Vinyl Percent Change (%) 17.37% -0.60% -11.35% -26.04% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Vinyl Percent Change (%) 3.71% 0.45% -5.20% -10.52% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Excellent (0-10%) Not recommended (over 50%) Not recommended (over 50%) Excellent to Good (0-20%) Not Recommended Not Recommended Recommended Recommended Excellent (<20%) Latex Percent Change (%) 1.18% 8.30% -11.85% -13.78% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Latex Percent Change (%) 7.33% 2.84% -42.78% -9.30% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Use Fair (0-10%) Caution (<60%) Not recommended Not (over 50%) Recommended Not recommended Not (over 50%) Recommended Fair to Poor Use (21-50%) Caution Test Weight Thickness Tensil Elongation Latex Percent Change (%) 8.88% 1.43% -20.38% -18.24% Recommendatio Tensile Test Rating Weight Test Rating n Excellent Recommended Good (0-10%) (<40%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Latex Percent Change (%) 90.38% 8.50% -36.36% 1.84% Recommendatio Weight Test Rating Tensile Test Rating n Not Recommended Not Good (over 50%) Recommended (<40%) Not Recommended Not (over 50%) Recommended Not Recommended Not (over 50%) Recommended Not Recommended Not (over 50%) Recommended Test Weight Thickness Tensil Elongation Latex Percent Change (%) 2.53% 2.39% -45.13% -10.79% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Use Fair (0-10%) Caution (<60%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation 64 Use Caution No Data Thickness Tensil Elongation Test Weight Recommended Recommended Excellent to Good (0-20%) Excellent to Good (0-20%) Not Not Recommended (over 50%) Recommended Not Not Recommended Recommended (over 50%) Pure Chemical (Index Guide Rating): Acetone Recommended Recommendatio n Recommended Pure Chemical (Index Guide Rating): ABS resin Excellent (0-10%) Excellent to Good (0-20%) Fair (<60%) 3.17% -18.43% -42.97% Excellent (<20%) Recommended Use Caution Recommended Not Recommended Not Recommended (>80%) Thickness Tensil Elongation Test Weight Recommended Excellent to Good (0-20%) No Data Excellent (0-10%) Not Recommended (over 50%) Not Recommended (over 50%) Not Recommended (over 50%) Not Recommended Not Recommended Not Recommended Recommendatio n Recommended -3.34% 2.51% 36.88% Poor (<80%) Use Caution Recommended Recommended Good (<40%) Not Recommended Not Recommended Use Caution Not Recommended Poor (<80%) Excellent (<20%) Excellent (0-10%) Not Recommended (over 50%) Not Recommended (over 50%) Not Recommended (over 50%) Thickness Tensil Elongation Test Weight Poor (31-50%) No Data Not Recommended (over 50%) No Data Not Recommended No Data Use Caution No Data Poor (<80%) Vinyl Percent Change (%) 36.87% 7.21% -68.33% -53.68% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Vinyl Percent Change (%) 2.86% -0.89% -19.38% -11.36% Recommendatio Weight Test Rating Tensile Test Rating n Recommended Excellent Excellent (<20%) (0-10%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Not Recommended (over 50%) Not Recommended (over 50%) Fair to Poor (21-50%) Not Recommended (over 50%) Vinyl Percent Change (%) 96.14% 20.84% -71.60% -63.96% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Excellent (0-10%) Fair to Poor (21-50%) Excellent to Good (0-20%) Vinyl Percent Change (%) 5.10% 3.88% -20.60% -24.72% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Not Recommended Not Recommended Not Recommended Recommended Excellent (<20%) Vinyl Percent Change (%) 3.21% 1.27% -8.51% -3.53% Recommendatio Tensile Test Rating Weight Test Rating Tensile Test Rating n Nitrile Percent Change (%) 4.70% No Data Use Caution No Data Poor (31-50%) No Data Nitrile Percent Change (%) 39.95% -0.96% -79.23% -67.66% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Tensile Test Rating Weight Test Rating Butyl Percent Change (%) 5.00% Excellent (<20%) Nitrile Percent Change (%) 0.92% 1.56% -21.30% 26.76% Recommendatio Weight Test Rating Tensile Test Rating n Recommended Good Excellent (0-10%) (<40%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Not Recommended Not Recommended (over 50%) Excellent to Good (0-20%) Fair to Poor (21-50%) Poor (<80%) Use Caution Recommended Recommended Nitrile Percent Change (%) 78.40% -2.80% -86.65% -71.41% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Excellent (0-10%) Fair to Poor (21-50%) Excellent to Good (0-20%) Nitrile Percent Change (%) 9.52% 7.08% -14.03% 5.02% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Not Recommended Not Data Not Recommended Butyl Percent Change (%) 70.76% 12.93% -57.20% -57.82% Recommendatio Tensile Test Rating Weight Test Rating n Not Recommended Not Fair (<60%) (over 50%) Recommended No No Data Data Not Recommended Not Recommended (over 50%) No No Data Data Test Weight Thickness Tensil Elongation Tensile Test Rating Weight Test Rating Poor (<80%) Excellent (<20%) Butyl Percent Change (%) 3.39% -1.14% 4.15% -8.96% Recommendatio Tensile Test Rating Weight Test Rating n Recommended Excellent Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Not Recommended (over 50%) Not Recommended (over 50%) No Data Not Recommended (over 50%) Not Not Recommended (over 50%) Recommended Good (11-20%) Recommendatio n Use Caution 10.32% -49.00% -31.19% Thickness Tensil Elongation Weight Test Rating Neoprene Percent Change (%) 19.31% Test Weight Not Recommended Not Recommended (over 50%) No No Data Data Poor (31-50%) No Data Neoprene Percent Change (%) 44.66% 4.98% -75.48% -69.61% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Recommended Recommended Recommended Butyl Percent Change (%) 108.74% 33.05% -61.11% -51.03% Recommendatio Tensile Test Rating Weight Test Rating n Test Weight Thickness Tensil Elongation Excellent (0-10%) Excellent to Good (0-20%) Excellent to Good (0-20%) Butyl Percent Change (%) 2.56% 0.90% -5.29% 8.23% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Pure Chemical (Index Guide Rating): Methyl ethyl keytone Mixed Chemical: Oaty: ABS Cement Oaty: ABS Cement (Experimental Chemical 25) Pure Chemical (Index Guide Rating): Hydrotreated light petroleum distillate Pure Chemical (Index Guide Rating): Crystalline silica Winner Industrial Supply: EZ Seal Pure Chemical (Index Guide Rating): Bentonite clay Mixed Chemical: Winner Industrial Supply: EZ Seal (Experimental Chemical 24) Mixed Chemical: MT: Cold Shield Pure Chemical (Index Guide Rating): Clay material Pure Chemical (Index Guide Rating): Salt Neoprene Percent Change (%) 1.40% 0.68% 1.74% -14.39% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (<20%) (0-10%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) MT: Cold Shield (Experimental Chemical 23) Test Weight Thickness Tensil Elongation Not Recommended Not (over 50%) Recommended Pure Chemical (Index Guide Rating): Polyetoxilated stearilic ether Not Recommended (>80%) Not Recommended Not (over 50%) Recommended Excellent to Good Recommended (0-20%) Not Recommended Not (over 50%) Recommended Pure Chemical (Index Guide Rating): Petroleum distillate Pure Chemical (Index Guide Rating): Sodium sulfate alkyl ether Penetrating Oil Mixed Chemical: Neoprene Percent Change (%) 94.78% 14.47% -87.09% -78.01% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Main Tech LLC: Penetrating Oil (Experimental Chemical 22) Recommended Recommended Excellent (<20%) Excellent (0-10%) Excellent to Good (0-20%) Excellent to Good (0-20%) Mixed Chemical: Hercules: Sizzle Pure Chemical (Index Guide Rating): Hydrogen chloride Pure Chemical (Index Guide Rating): Water Recommended Neoprene Percent Change (%) 3.48% 2.35% -0.09% -5.36% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Hercules: Sizzle (Experimental Chemical 21) No Data Recommended Recommended Excellent (<20%) Not Recommended Not Recommended Not Data Not Recommended Not Recommended (>80%) Fair (21-30%) Not Recommended (over 50%) Not Recommended (over 50%) Not Recommended (over 50%) Not Recommended Not Recommended Not Recommended Use Caution Fair (<40%) Latex Percent Change (%) 24.97% 12.97% -36.69% -8.07% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Latex Percent Change (%) 148.23% -8.49% -88.54% -75.97% Recommendatio Weight Test Rating Tensile Test Rating n Not Recommended Not Not Recommended (>80%) (over 50%) Recommended No No Data Data Not Not Recommended (over 50%) Recommended No No Data Data Test Weight Thickness Tensil Elongation Latex Percent Change (%) 5.62% 3.00% -1.53% -8.76% Recommendatio Weight Test Rating Tensile Test Rating n Recommended Excellent Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Not Recommended (over 50%) Not Recommended (over 50%) No Data Not Recommended (over 50%) Latex Percent Change (%) 178.37% 26.95% -89.55% -76.39% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Good (11-20%) No Data Excellent to Good (0-20%) Latex Percent Change (%) 10.96% 6.90% -14.17% -11.21% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation 65 Neoprene Percent Change (%) 4.85% 1.76% -15.35% -25.80% Recommendatio Weight Test Rating Tensile Test Rating n Relton: Rapid Tap (Experimental Chemical 29) Not Recommended Not (over 50%) Recommended Not Recommended Not (over 50%) Recommended Not Recommended Not (over 50%) Recommended Not Recommended Not (over 50%) Recommended Weld-On P-70 Primer Pure Chemical (Index Guide Rating): Tetrahydrofuran (THF) Pure Chemical (Index Guide Rating): Methy ethal keytone (MEK) Pure Chemical (Index Guide Rating): Cyclohexanone Mixed Chemical: Poor (<80%) Neoprene Percent Change (%) 87.06% 29.47% -67.29% -59.47% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Weld-On P-70 Primer (Experimental Chemical 30) Recommended Excellent to Good (0-20%) Excellent (<20%) Pure Chemical (Index Guide Rating): Sec butanol Recommended Not Recommended Not (over 50%) Recommended Excellent to Good Recommended (0-20%) Excellent (0-10%) Test Weight Thickness Tensil Elongation Recommended Recommended Pure Chemical (Index Guide Rating): 1,1,1-Trichloroethane (methyl chloroform) Pure Chemical (Index Guide Rating): Glycol methylene ether Mixed Chemical: Relton: Rapid Tap Excellent (0-10%) Excellent to Good (0-20%) Mixed Chemical: Nexgen Chemstar Line: Nexbac Pure Chemical (Index Guide Rating): No hazardous materials Excellent (<20%) Neoprene Percent Change (%) 1.54% -0.02% 0.20% -9.54% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Nexgen Chemstar Line: Nexbac (Experimental Chemical 28) Use Caution Recommended Fair to Poor (21-50%) Excellent to Good (0-20%) Use Caution Fair to Poor (21-50%) Pure Chemical (Index Guide Rating): Ethoxylated alcohol Pure Chemical (Index Guide Rating): Tetrapotassium pyrophoshate Neoprene Percent Change (%) 1.28% 0.95% -11.51% 5.97% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Test Weight Thickness Tensil Elongation Neoprene Percent Change (%) 0.57% 0.06% -5.93% -11.94% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Pure Chemical (Index Guide Rating): 2-Butoxyethanol Mixed Chemical: Simply Green: All Purpose Cleaner Simply Green: All Purpose Cleaner (Experimental Chemical 27) Mixed Chemical: Clorox: Germicidal Bleach Pure Chemical (Index Guide Rating): Sodium hypochlorite Pure Chemical (Index Guide Rating): Sodium hydroxide Clorox: Germicidal Bleach (Experimental Chemical 26) Recommended Recommended Recommended Recommended Recommended Excellent (<20%) Recommended Not Recommended Recommended Recommended Excellent (<20%) Excellent to Good (0-20%) Excellent to Good (0-20%) Poor (31-50%) Not Recommended (over 50%) Recommended Recommended Not Recommended Use Caution Excellent (<20%) Butyl Percent Change (%) 32.99% 10.27% -14.52% -3.01% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Excellent (0-10%) Not Recommended (over 50%) Excellent to Good (0-20%) Butyl Percent Change (%) 7.25% 1.44% 2.57% 0.29% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Excellent (0-10%) Excellent to Good (0-20%) Butyl Percent Change (%) 3.35% 1.28% -13.45% -15.12% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent to Good (0-20%) Butyl Percent Change (%) 14.10% 3.13% -8.29% -12.33% Recommendatio Weight Test Rating Tensile Test Rating n Good Recommended Excellent (11-20%) (<20%) Test Weight Thickness Tensil Elongation Butyl Percent Change (%) 0.26% -0.19% -9.27% -8.78% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Recommended Recommended Recommended Recommended Recommended Excellent (<20%) Recommended Not Recommended Recommended Recommended Good (<40%) Fair to Poor (21-50%) Poor (31-50%) Not Recommended (over 50%) Not Recommended (over 50%) Use Caution Not Recommended Not Recommended Use Caution Execellent (<20%) Nitrile Percent Change (%) 38.14% 16.03% -17.72% 27.13% Recommendatio Tensile Test Rating Weight Test Rating n Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Excellent (0-10%) Not Recommended (over 50%) Excellent to Good (0-20%) Nitrile Percent Change (%) 4.60% 1.73% -34.21% 26.16% Recommendatio Tensile Test Rating Weight Test Rating n Test Weight Thickness Tensil Elongation Excellent (0-10%) Excellent to Good (0-20%) Nitrile Percent Change (%) 6.61% 0.32% -17.96% 16.41% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent to Good (0-20%) Nitrile Percent Change (%) 2.09% 1.86% -9.69% 1.55% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Test Weight Thickness Tensil Elongation Nitrile Percent Change (%) 0.43% 0.01% 2.51% 33.58% Recommendatio Tensile Test Rating Weight Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Use Caution Recommended Recommended Recommended Excellent (<20%) Recommended Not Recommended Recommended Recommended Good (<40%) Vinyl Percent Change (%) 52.53% 20.05% -34.70% -24.87% Recommendatio Weight Test Rating Tensile Test Rating n Not Recommended Not Good (over 50%) Recommended (<40%) Not Recommended Not (over 50%) Recommended Not Recommended Not (over 50%) Recommended Not Recommended Not (over 50%) Recommended Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Excellent (0-10%) Not Recommended (over 50%) Excellent to Good (0-20%) Vinyl Percent Change (%) 5.00% 0.91% -38.11% -37.70% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Excellent (0-10%) Excellent to Good (0-20%) Vinyl Percent Change (%) 3.28% 0.62% -5.47% -6.37% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Fair to Poor (21-50%) Excellent to Good (0-20%) Vinyl Percent Change (%) 2.18% 0.54% -14.04% -6.94% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Not Recommended Not (over 50%) Recommended Test Weight Thickness Tensil Elongation Vinyl Percent Change (%) 0.49% -0.06% -31.22% -41.31% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Good (0-10%) (<40%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Recommended Recommended Excellent (<20%) Not Recommended Not Recommended Recommended Use Caution Excellent (<20%) Latex Percent Change (%) 76.40% 25.17% -26.53% 12.62% Recommendatio Weight Test Rating Tensile Test Rating n Not Recommended Not Good (over 50%) Recommended (<40%) Not Recommended Not (over 50%) Recommended Not Recommended Not (over 50%) Recommended Not Recommended Not (over 50%) Recommended Test Weight Thickness Tensil Elongation Poor (31-50%) Not Recommended (over 50%) Excellent to Good (0-20%) Not Recommended (over 50%) Latex Percent Change (%) 31.34% 5.52% -18.26% -17.29% Recommendatio Tensile Test Rating Weight Test Rating n Test Weight Thickness Tensil Elongation Excellent (0-10%) Excellent to Good (0-20%) Latex Percent Change (%) 7.06% 0.76% -1.24% -9.78% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Latex Percent Change (%) 10.59% 1.58% 0.59% 7.71% Recommendatio Tensile Test Rating Weight Test Rating n Good Recommended Excellent (11-20%) (<20%) Not Recommended Not (over 50%) Recommended Not Recommended Not (over 50%) Recommended Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Latex Percent Change (%) 9.21% 0.23% -6.35% -0.76% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation 66 Neoprene Percent Change (%) 33.67% 12.78% -52.74% -56.23% Recommendatio Weight Test Rating Tensile Test Rating n Poor Use Fair (31-50%) Caution (<60%) Not recommended Not (over 50%) Recommended Not recommended Not (over 50%) Recommended Kingsford: Charcoal Lighter Fluid (Experimental Chemical 35) Mixed Chemical: Kingsford: Charcoal Lighter Fluid Pure Chemical (Index Guide Rating): Aliphatic hydrocarbon Pure Chemical (Index Guide Rating): Petroleum Solvents Poor (31-50%) Not recommended (over 50%) Fair to Poor (21-50%) Not recommended (over 50%) Mixed Chemical: WD-40 Pure Chemical (Index Guide Rating): Aliphatic hydrocarbon Pure Chemical (Index Guide Rating): Petroleum base oil Pure Chemical (Index Guide Rating): Ivp aliphatic hydrocarbon Test Weight Thickness Tensil Elongation Fair (<60%) Neoprene Percent Change (%) 32.05% 6.80% -54.44% -30.19% Recommendatio Weight Test Rating Tensile Test Rating n WD-40 (Experimental Chemical 34) Use Caution Not Recommended Use Caution Not Recommended Not Recommended Not (over 50%) Recommended Pure Chemical (Index Guide Rating): Petroleum hydrocarbon Test Weight Thickness Tensil Elongation Not Recommended Not (over 50%) Recommended Poor (<80%) Recommended Not Recommended Not Recommended Use Caution Fair (<60%) Weight Thickness Tensil Elongation Test (21-50%) Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent (0-10%) Fair to Poor Not Recommended Not Recommended Not Recommended Use Caution Recommendatio n Good (<40%) Not Recommended Not Recommended Not Recommended Not Recommended Excellent (<20%) Butyl Percent Change (%) 49.86% 14.89% -16.76% -10.84% Recommendatio Weight Test Rating Tensile Test Rating n Poor Use Excellent (31-50%) Caution (<20%) Not recommended Not (over 50%) Recommended Not recommended Not (over 50%) Recommended Test Weight Thickness Tensil Elongation Not recommended (over 50%) Not recommended (over 50%) Not recommended (over 50%) Not recommended (over 50%) Recommended Recommended Recommended Use Caution Excellent (<20%) Weight Thickness Tensil Elongation Test (21-50%) Excellent to Good (0-20%) Fair to Poor (21-50%) Excellent (0-10%) Fair to Poor Recommended Recommended Recommended Recommended Recommendatio n Excellent (<20%) Not Recommended Recommended Use Caution Recommended Fair (<60%) Nitrile Percent Change (%) 46.62% 3.52% -58.10% -42.56% Recommendatio Tensile Test Rating Weight Test Rating n Poor Use Fair (31-50%) Caution (<60%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Poor (31-50%) Excellent to Good (0-20%) Excellent to Good (0-20%) Not recommended (over 50%) Use Caution Not Recommended Not Recommended Use Caution Good (<40%) Weight Thickness Tensil Elongation Test (21-50%) Excellent to Good (0-20%) Fair to Poor (21-50%) Excellent (0-10%) Fair to Poor Not Recommended Not Recommended Not Recommended Recommended Recommendatio n Good (<40%) Use Caution Not Recommended Not Recommended Not Recommended Fair (<60%) Vinyl Percent Change (%) 39.15% 12.19% -39.75% -29.02% Recommendatio Weight Test Rating Tensile Test Rating n Poor Use Good (31-50%) Caution (<40%) Not recommended Not (over 50%) Recommended Not recommended Not (over 50%) Recommended Test Weight Thickness Tensil Elongation Poor (31-50%) Not recommended (over 50%) Not recommended (over 50%) Not recommended (over 50%) Not Recommended Not Recommended Not Recommended Not Recommended Fair (<60%) Weight Thickness Tensil Elongation Test (0-20%) Excellent to Good (0-20%) Fair to Poor (21-50%) Excellent (0-10%) Excellent to Good Not Recommended Not Recommended Not Recommended Not Recommended Recommendatio n Fair (<60%) Tensile Test Rating Excellent (<20%) Not recommended (over 50%) Not recommended (over 50%) Not recommended (over 50%) Weight Test Rating Test Weight Thickness Tensil Elongation Not recommended (over 50%) Not recommended (over 50%) Not recommended (over 50%) Not recommended (over 50%) Not Recommended (>80%) Latex Percent Change (%) 183.34% 14.17% -52.34% 29.20% Recommendatio Tensile Test Rating n Not Fair Recommended (<60%) Not Recommended Not Recommended Not Recommended Not Recommended Not Recommended Not Recommended Latex Percent Change (%) 205.11% 3.67% -81.45% -50.89% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Not Recommended (over 50%) Not Recommended (over 50%) Not Recommended (over 50%) Not Recommended (over 50%) 123.95% 51.40% -52.71% 34.85% Latex Percent Change (%) Use Caution Recommended Recommended Recommended Latex Percent Change (%) 2.15% 1.84% 0.33% -4.60% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Not Recommended (over 50%) Not Recommended (over 50%) Not Recommended (over 50%) Not Recommended (over 50%) Latex Percent Change (%) 65.30% 42.98% -44.96% 2.79% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Tensile Test Rating Weight Test Rating Excellent (<20%) Vinyl Percent Change (%) 47.57% 13.41% -54.60% -49.51% Recommendatio Tensile Test Rating Weight Test Rating n Test Weight Thickness Tensil Elongation Good (11-20%) Not Recommended (over 50%) Not Recommended (over 50%) Not Recommended (over 50%) 19.05% 18.87% -35.95% -20.95% Vinyl Percent Change (%) Use Caution Caution Recommended Use Recommended Vinyl Percent Change (%) 0.21% 0.08% -20.91% -15.06% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Fair to Poor (21-50%) Fair (21-30%) Not Recommended (over 50%) Not Recommended (over 50%) Vinyl Percent Change (%) 24.32% 15.13% -23.95% -2.69% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Tensile Test Rating Weight Test Rating Excellent (<20%) Nitrile Percent Change (%) 37.78% -1.61% -50.25% -19.69% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent to Good (0-20%) Good (11-20%) 11.03% 8.74% -11.24% 16.75% Nitrile Percent Change (%) Use Caution Caution Recommended Use Recommended Nitrile Percent Change (%) 0.66% 0.34% -1.40% 19.72% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent to Good (0-20%) Fair (21-30%) Nitrile Percent Change (%) 24.35% 13.70% -14.87% 23.16% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Tensile Test Rating Weight Test Rating Excellent (<20%) Butyl Percent Change (%) 53.75% 23.44% 6.57% -2.39% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Poor (31-50%) Not Recommended (over 50%) Not Recommended (over 50%) Not Recommended (over 50%) 34.02% 20.29% -24.41% -19.37% Butyl Percent Change (%) Recommended Caution Recommended Use Recommended Butyl Percent Change (%) 0.58% -1.20% -44.48% -18.28% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Poor (31-50%) Not Recommended (over 50%) Not Recommended (over 50%) Butyl Percent Change (%) 38.35% 20.50% -52.88% -24.46% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Tensile Test Rating Weight Test Rating Not Recommended Not (over 50%) Recommended Use Caution Pure Chemical (Index Guide Rating): N-Hexane Poor (31-50%) Recommendatio n 33.62 15.35% -61.30% -41.11% Weight Test Rating Neoprene Percent Change (%) Weight Thickness Tensil Elongation Recommended Recommended Test (0-20%) Excellent to Good (0-20%) Excellent to Good (0-20%) Pure Chemical (Index Guide Rating): Liquefied petroleum Maxima: Chain Wax Mixed Chemical: Maxima: Chain Wax (Experimental Chemical 33) Tetra-(ethylenedinitrilo)tetrasodium salt Pure Chemical (Index Guide Rating): Sodium salt Pure Chemical (Index Guide Rating): Recommended Recommended Excellent (<20%) Excellent (0-10%) Excellent to Good Mixed Chemical: Ecolab: Oasis Pure Chemical (Index Guide Rating): Poly(oxy-1,2-ethanediyl), .alpha.-(nonylphenyl).omega.-hydroxy-acetic acid Neoprene Percent Change (%) 0.94% 1.19% 1.52% -11.47% Recommendatio Weight Test Rating Tensile Test Rating n Ecolab: Oasis (Experimental Chemical 32) Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Pure Chemical (Index Guide Rating): Isopropyl alcohol Recommended Not Recommended Not (over 50%) Recommended Poor (<80%) Not Recommended Not (over 50%) Recommended Use Caution Pure Chemical (Index Guide Rating): Heptane Fair (21-30%) Neoprene Percent Change (%) 29.80% 14.66% -61.57% -41.53% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Pure Chemical (Index Guide Rating): Isoparaffinic hydrocarbon Ecoline: Dry Teflon Mixed Chemical: Ecoline: Dry Teflon (Experimental Chemical 31) 67 Pure Chemical (Index Guide Rating): Petroleum naphtha Pure Chemical (Index Guide Rating): Hydrotreated naphthetic oil Pure Chemical (Index Guide Rating): Hydroxyethylated aminoethylamide proprietary Craftman: fuel stabilizer Mixed Chemical: Craftman: fuel stabilizer (Experimental Chemical 40) Use Caution Good (<40%) Recommended Fair to Poor (21-50%) Use Caution Not Recommended Not (over 50%) Recommended Excellent to Good Recommended (0-20%) Good (11-20%) Good (<40%) Neoprene Percent Change (%) 14.29% 7.02% -33.37% -37.95% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Fair to Poor (21-50%) Recommended Excellent to Good (0-20%) Pure Chemical (Index Guide Rating): Pentane Recommended Pure Chemical (Index Guide Rating): Octane Excellent (0-10%) Not Recommended Not (over 50%) Recommended Pure Chemical (Index Guide Rating): Petroleum distillates Truefuel: Truefuel 40:1 Engineered Fuel + Oil Mixed Chemical: Neoprene Percent Change (%) 5.15% 1.70% -22.24% -5.94% Recommendatio Tensile Test Rating Weight Test Rating n Truefuel: Truefuel 40:1 Engineered Fuel + Oil (Experimental Chemical 39) Test Weight Thickness Tensil Elongation Fair to Poor (21-50%) Excellent to Good (0-20%) Use Caution Recommended Not Recommended Not (over 50%) Recommended Pure Chemical (Index Guide Rating): Acetone Pure Chemical (Index Guide Rating): Carbon dioxide Poor (31-50%) Pure Chemical (Index Guide Rating): Heptane Liquid Performance: Spray Cleaner and Polish Mixed Chemical: Test Weight Thickness Tensil Elongation Fair (<60%) Neoprene Percent Change (%) 19.75% 6.32% -40.36% -37.20% Recommendatio Weight Test Rating Tensile Test Rating n Liquid Performance: Spray Cleaner and Polish (Experimental Chemical 38) Mixed Chemical: Sweeney's: Mole and Gopher Repellant Pure Chemical (Index Guide Rating): Caster oil Use Caution Neoprene Percent Change (%) 0.07% -1.17% 4.95% 36.88 Recommendatio Weight Test Rating Tensile Test Rating n Excellent to Good Recommended Excellent (0-20%) (<20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Sweeney's: Mole and Gopher Repellant (Experimental Chemical 37) Mixed Chemical: Henry: Easy Release Adhesive Remover Pure Chemical (Index Guide Rating): Ethanolamine Pure Chemical (Index Guide Rating): 2-Butoxyethanol Neoprene Percent Change (%) 4.42% 2.24% -49.03% -47.93% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Use Fair (0-10%) Caution (<60%) Excellent to Good Recommended (0-20%) Fair to Poor Use (21-50%) Caution Test Weight Thickness Tensil Elongation Henry: Easy Release Adhesive Remover (Experimental Chemical 36) Recommended Recommended Not Recommended Use Caution Excellent (<20%) Recommended Excellent (0-10%) Not Recommended (over 50%) Fair to Poor (21-50%) Not Recommended (over 50%) Not Recommended Not Recommended Use Caution Recommended Excellent (<20%) Butyl Percent Change (%) 0.15% -1.73% 4.58% 1.24% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Butyl Percent Change (%) 50.84% 19.44% 3.55% 7.64% Recommendatio Weight Test Rating Tensile Test Rating n Not Recommended Not Excellent (over 50%) Recommended (<20%) Not Recommended Not (over 50%) Recommended Not Recommended Not (over 50%) Recommended Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Excellent to Good (0-20%) Poor (31-50%) Not Recommended (over 50%) Butyl Percent Change (%) 32.57% 4.65% -7.49% 9.63% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Butyl Percent Change (%) 0.02% -2.17% -27.61% -26.57% Recommendatio Weight Test Rating Tensile Test Rating n Excellent to Good Recommended Good (0-20%) (<40%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Butyl Percent Change (%) 1.26% 0.38% 0.47% 1.42% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Not Recommended Recommended Recommended Recommended Excellent (<20%) Use Caution Recommended Recommended Recommended Good (<40%) Excellent to Good (0-20%) Excellent (0-10%) Not Recommended (over 50%) Excellent to Good (0-20%) Recommended Not Recommended Recommended Recommended Good (<40%) Nitrile Percent Change (%) 7.00% 0.73% -36.37% -15.47% Recommendatio Tensile Test Rating Weight Test Rating n Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent to Good (0-20%) Fair (21-30%) Nitrile Percent Change (%) 26.63% 4.41% -23.22% -3.11% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Not Recommended (over 50%) Excellent to Good (0-20%) Good (11-20%) Nitrile Percent Change (%) 12.25% -4.55% -10.43% 32.03% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Nitrile Percent Change (%) 0.77% -1.08% 3.27% 41.74% Recommendatio Weight Test Rating Tensile Test Rating n Excellent to Good Recommended Excellent (0-20%) (<20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Nitrile Percent Change (%) 3.44% 0.74% -13.88% 19.74% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Not Recommended Recommended Not Recommended Use Caution Good (<40%) Not Recommended Not Recommended Not Recommended Use Caution Good (<40%) Fair to Poor (21-50%) Excellent (0-10%) Not Recommended (over 50%) Excellent to Good (0-20%) Use Caution Not Recommended Recommended Use Caution Fair (<60%) Vinyl Percent Change (%) 6.72% 2.23% -43.61% -38.48% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Poor (31-50%) Not Recommended (over 50%) Not Recommended (over 50%) Not Recommended (over 50%) Vinyl Percent Change (%) 39.96% 14.92% -24.97% -15.84% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Fair (21-30%) Not Recommended (over 50%) Not Recommended (over 50%) Excellent to Good (0-20%) Vinyl Percent Change (%) 22.72% 5.06% -26.26% -16.55% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Vinyl Percent Change (%) 0.03% -1.41% -9.89% -5.93% Recommendatio Weight Test Rating Tensile Test Rating n Excellent to Good Recommended Excellent (0-20%) (<20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Vinyl Percent Change (%) 3.12% 0.56% -24.25% -12.63% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Good (0-10%) (<40%) Excellent to Good Recommended (0-20%) Not recommended Not (over 50%) Recommended Test Weight Thickness Tensil Elongation Use Caution Recommended Not Recommended Not Recommended Good (<40%) Latex Percent Change (%) 95.32% 3.04% -82.72% -53.90% Recommendatio Weight Test Rating Tensile Test Rating n Not Recommended Not Not Recommended (over 50%) Recommended (>80%) Not Recommended Not (over 50%) Recommended Fair to Poor Use (21-50%) Caution Not Recommended Not (over 50%) Recommended Test Weight Thickness Tensil Elongation Latex Percent Change (%) 94.59% 28.26% -26.64% -11.47% Recommendatio Tensile Test Rating Weight Test Rating n Not Recommended Not Good (over 50%) Recommended (<40%) Not Recommended Not (over 50%) Recommended Not Recommended Not (over 50%) Recommended Not Recommended Not (over 50%) Recommended Test Weight Thickness Tensil Elongation Fair to Poor (21-50%) Excellent to Good (0-20%) Not Recommended (over 50%) Not Recommended (over 50%) Latex Percent Change (%) 66.03% 13.85% -31.16% -12.81% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Latex Percent Change (%) 0.32% -6.89% -1.49% -4.49% Recommendatio Weight Test Rating Tensile Test Rating n Excellent to Good Recommended Excellent (0-20%) (<20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Latex Percent Change (%) 9.43% 5.51% -26.61% -13.52% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Good (0-10%) (<40%) Fair to Poor Use (21-50%) Caution Not recommended Not (over 50%) Recommended Test Weight Thickness Tensil Elongation 68 Excellent to Good (0-20%) Not Recommended (over 50%) Excellent to Good (0-20%) Pure Chemical (Index Guide Rating): Sulfuric acid Pure Chemical (Index Guide Rating): Rodine 31A Amazing!:Liquid Fire Mixed Chemical: Amazing!:Liquid Fire (Experimental Chemical 45) Mixed Chemical: Liquid Plumber: Hair Clog Eliminator Pure Chemical (Index Guide Rating): Sodium hypochlorite Pure Chemical (Index Guide Rating): Sodium hydroxide Neoprene Percent Change (%) 0.83% 0.48% -14.14% -37.36% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Liquid Plumber: Hair Clog Eliminator (Experimental Chemical 44) Recommendatio n Weight Test Rating Fair to Poor (21-50%) No Data Use Caution No Data Not Recommended Not (over 50%) Recommended 51.30% 12.63% -18.99% -90.91% Weight Thickness Tensil Elongation Excellent (<20%) Not Recommended Recommended Recommended Excellent to Good (0-20%) No Data Fair (21-30%) No Data Recommended Use Caution Good (<40%) Not Recommended Recommended Not Recommended Recommendatio n Recommended 9.57% -3.01% 3.18% 20.66% Excellent (<20%) Use Caution Recommended Recommended Recommended Excellent (<20%) Use Caution Recommended Recommended Weight Thickness Tensil Elongation Test Excellent (0-10%) Not Recommended (over 50%) No Data Not Recommended No Data Use Caution Recommendatio n 2.12% 5.35% -43.13% -25.60% Fair (<60%) Not Recommended Recommended Not Recommended Recommendatio n Use Caution 13.56% 54.75% -45.78% -25.55% Fair (<60%) Use Caution Use Caution Recommended Use Caution Fair (<60%) Weight Thickness Tensil Elongation Test Not Recommended (over 50%) Not Recommended (over 50%) No Data Not Recommended No Data Not Recommended Recommendatio n 53.08% 24.54% -64.32% -94.32% Poor (<80%) Not Recommended Recommended Not Recommended Recommendatio n Use Caution 16.77% 7.56% -44.53% -44.38% Fair (<60%) Tensile Test Rating Latex Percent Change (%) Not Recommended Not Recommended Not Recommended Not Recommended Not Recommended (>80%) Weight Thickness Tensil Elongation Test Not Recommended (over 50%) Not Recommended (over 50%) No Data Not Recommended No Data Not Recommended Recommendatio n 254.15% -42.51% -60.91% -68.70% Poor (<80%) Tensile Test Rating Latex Percent Change (%) Latex Percent Change (%) 6.10% -1.42% -4.22% -0.02% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Latex Percent Change (%) 9.94% -5.17% -19.04% 0.43% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Not Recommended Not (over 50%) Recommended Not Recommended Not (over 50%) Recommended Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Not Recommended (over 50%) Not Recommended (over 50%) Not Recommended (over 50%) Not Recommended (over 50%) Latex Percent Change (%) 83.01% 1.73% -89.90% -44.04% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Good (11-20%) Not Recommended (over 50%) Not Recommended (over 50%) Excellent to Good (0-20%) Tensile Test Rating Weight Test Rating Vinyl Percent Change (%) Vinyl Percent Change (%) 0.53% -0.15% -38.99% -44.31% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Good (0-10%) (<40%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Vinyl Percent Change (%) 2.30% -0.14% -22.31% -10.80% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Good (0-10%) (<40%) Not Recommended Not (over 50%) Recommended Not Recommended Not (over 50%) Recommended Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Fair to Poor (21-50%) Fair to Poor (21-50%) Excellent to Good (0-20%) Excellent (0-10%) Weight Thickness Tensil Elongation Test Tensile Test Rating Weight Test Rating Vinyl Percent Change (%) Vinyl Percent Change (%) 2.08% -0.71% -41.08% -37.36% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Good (11-20%) Not Recommended (over 50%) Not Recommended (over 50%) Excellent to Good (0-20%) Tensile Test Rating Weight Test Rating Nitrile Percent Change (%) Nitrile Percent Change (%) 1.29% -1.92% -6.96% 10.88% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Excellent to Good (0-20%) Fair to Poor (21-50%) Nitrile Percent Change (%) 2.50% -1.74% -2.01% 12.95% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Test Weight Thickness Tensil Elongation Fair to Poor (21-50%) Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent (0-10%) Weight Thickness Tensil Elongation Test Tensile Test Rating Weight Test Rating Nitrile Percent Change (%) Nitrile Percent Change (%) 0.87% -2.85% -8.98% 19.33% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Excellent (0-10%) Not Recommended (over 50%) Not Recommended (over 50%) Excellent to Good (0-20%) Tensile Test Rating Weight Test Rating 23.94% 6.72% -26.38% 26.66% Weight Thickness Tensil Elongation Recommendatio n Butyl Percent Change (%) Test Butyl Percent Change (%) 0.18% -0.78% -2.93% 20.98% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Tensile Test Rating Weight Test Rating Neoprene Percent Change (%) Test Test Weight Thickness Tensil Elongation Pure Chemical (Index Guide Rating): Petroleum gases Pure Chemical (Index Guide Rating): Sodium hydroxide Recommended Excellent to Good (0-20%) Not Recommended Not (over 50%) Recommended Excellent to Good Recommended (0-20%) Pure Chemical (Index Guide Rating): Ethanol, 2-(2-butoxyethoxy) Mixed Chemical: Easy Off: Oven Cleaner Test Weight Thickness Tensil Elongation Recommended Butyl Percent Change (%) 1.28% -1.94% -16.27% 21.47% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Fair (<60%) Neoprene Percent Change (%) 3.58% 3.17% -10.96% 2.55% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Recommended Recommended Use Caution Easy Off: Oven Cleaner (Experimental Chemical 43) Recommended Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent (0-10%) Fair to Poor (21-50%) Use Caution Excellent (<20%) Excellent to Good (0-20%) Excellent (<20%) Weight Thickness Tensil Elongation Test Tensile Test Rating Weight Test Rating Pure Chemical (Index Guide Rating): Diethylene glycol monopropyl ether Recommended Recommended Recommended Recommended Not Recommended Recommendatio n Recommended Butyl Percent Change (%) 6.98% -1.84% -61.22% -84.87% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent (0-10%) Not Recommended (over 50%) 9.57% 3.88% -0.85% 10.24% Butyl Percent Change (%) Pure Chemical (Index Guide Rating): Diethylene glycol monobutyl ether Excellent to Good (0-20%) Excellent (0-10%) Pure Chemical (Index Guide Rating): Triethylene glycol monobutyl ether Valvoline: DOT 3&4 Mixed Chemical: Neoprene Percent Change (%) 2.48% 0.37% -19.18% -14.63% Recommendatio Weight Test Rating Tensile Test Rating n Valvoline: DOT 3&4 (Experimental Chemical 42) Test Weight Thickness Tensil Elongation Fair to Poor (21-50%) Excellent to Good (0-20%) Good (<40%) Pure Chemical (Index Guide Rating): Methyl alcohol Pure Chemical (Index Guide Rating): Carbod dioxide Use Caution Recommended Weight Thickness Tensil Elongation Test Tensile Test Rating Weight Test Rating Not Recommended Not (over 50%) Recommended Good (11-20%) Recommendatio n Recommended 9.25% 6.19% -34.51% 1.89% Weight Thickness Tensil Elongation Weight Test Rating Neoprene Percent Change (%) Test Pure Chemical (Index Guide Rating): Xylene Mixed Chemical: Valvoline: Heavy Duty Brake Parts Cleaner Valvoline: Heavy Duty Brake Parts Cleaner (Experimental Chemical 41) 69 Not Not Recommended Recommended (over 50%) Recommended Excellent to Good (0-20%) Excellent to Good (0-20%) Neoprene Percent Change (%) 0.37% 3.16% -13.62% -20.85 Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (<20%) (0-10%) Not Not Recommended Recommended (over 50%) Pure Chemical (Index Guide Rating): Petroleum distillate Pure Chemical (Index Guide Rating): Isopropyl alcohol Pure Chemical (Index Guide Rating): Ethylene glycol mono butyl ether 3-in-ONE: Motor Oil (Experimental Chemical 50) Pure Chemical (Index Guide Rating): Paraffinic petroleum distillate Pure Chemical (Index Guide Rating): Naptha, petroleum Mixed Chemical: 3-in-ONE: Motor Oil Mixed Chemical: Turtle Wax: Bug and Tar Remover Neoprene Percent Change (%) 3.143 3.023 -8.18% -12.83% Recommendatio Weight Test Rating Tensile Test Rating n Recommended Excellent Excellent (<20%) (0-10%) Fair to Poor (21-50%) Test Weight Thickness Tensil Elongation Test Weight Thickness Tensil Elongation Turtle Wax: Bug and Tar Remover (Experimental Chemical 49) Use Caution Recommended No Data Recommended Excellent to Good (0-20%) No Data Pure Chemical (Index Guide Rating): Propane Pure Chemical (Index Guide Rating): Isobutane Good (<40%) Not Not Recommended Recommended (over 50%) Excellent (0-10%) Pure Chemical (Index Guide Rating): Heptane White Lightning: Cleans Streaks Mixed Chemical: Recommended Neoprene Percent Change (%) 13.37% 7.69% -22.44% -15.07% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation White Lightning: Cleans Streaks (Experimental Chemical 48) Mixed Chemical: Resolve: Spray and Wash Laundry Stain Remover Pure Chemical (Index Guide Rating): Hydrogen peroxide Pure Chemical (Index Guide Rating): Alcohol ethoxyl Neoprene Percent Change (%) 2.28% 0.74% -6.56% 7.97% Recommendatio Weight Test Rating Tensile Test Rating n Recommended Excellent Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Neoprene Percent Change (%) 1.10% 0.44% -0.62% -16.12% Recommendatio Weight Test Rating Tensile Test Rating n Recommended Excellent Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Resolve: Spray and Wash Laundry Stain Remover (Experimental Chemical 47) Mixed Chemical: Clorox: Outdoor Bleach Concentrate Pure Chemical (Index Guide Rating): Sodium hypochlorite Pure Chemical (Index Guide Rating): Sodium hydroxide Clorox: Outdoor Bleach Concentrate (Experimental Chemical 46) Recommended Butyl Percent Change (%) 3.85% -0.15% 7.52% 5.15% Recommendatio Tensile Test Rating Weight Test Rating n Excellent Excellent Recommended (<20%) (0-10%) Not Not Recommended Recommended (over 50%) Not Not Recommended Recommended (over 50%) Test Weight Thickness Tensil Elongation Recommended Recommended Excellent to Good (0-20%) Excellent to Good (0-20%) Nitrile Percent Change (%) 2.92% -1.42% -2.63% 35.02% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Test Weight Thickness Tensil Elongation Recommended Excellent to Good (0-20%) Excellent to Good (0-20%) Recommended Recommended Excellent to Good (0-20%) Excellent to Good (0-20%) Excellent to Good (0-20%) Recommended Excellent (<20%) Nitrile Percent Change (%) 0.96% -0.86% -5.68% 51.01% Recommendatio Weight Test Rating Tensile Test Rating n Recommended Excellent Excellent (<20%) (0-10%) Test Weight Thickness Tensil Elongation No Data Recommended Excellent to Good (0-20%) No Data Not Recommended No Data Use Caution Recommended Fair (21-30%) Excellent to Good (0-20%) Good (<40%) Not Recommended Not Recommended Nitrile Percent Change (%) 21.36% -1.90% -3.62% 82.92% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Nitrile Percent Change (%) 2.02% -1.86% -8.83% 37.11% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Nitrile Percent Change (%) 1.97% -0.88% -1.97% 48.28% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Butyl Percent Change (%) 2.70% -0.27% 5.88% 0.34% Recommendatio Tensile Test Rating Weight Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Not Not Recommended Recommended (over 50%) Test Weight Thickness Tensil Elongation Not Recommended (over 50%) Not Recommended (over 50%) Not Recommended (over 50%) No Data Butyl Percent Change (%) 51.05% 26.23% -30.41% -21.34% Recommendatio Tensile Test Rating Weight Test Rating n Test Weight Thickness Tensil Elongation Butyl Percent Change (%) 1.31% -2.08% -11.59% 0.76% Recommendatio Tensile Test Rating Weight Test Rating n Recommended Excellent Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Butyl Percent Change (%) 1.10% -0.79% -14.55% 5.60% Recommendatio Tensile Test Rating Weight Test Rating n Excellent Excellent Recommended (<20%) (0-10%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Not Recommended No Data Not Recommended Not Recommended Good (<40%) Use Caution Recommended Fair to Poor (21-50%) Use Caution Vinyl Percent Change (%) 3.17% -0.30% -21.19% 210.84% Recommendatio Weight Test Rating Tensile Test Rating n Good Recommended Excellent (<40%) (0-10%) Not Not Recommended (over 50%) Recommended Test Weight Thickness Tensil Elongation Fair to Good (21-50%) Excellent to Good (0-20%) Vinyl Percent Change (%) 2.41% 0.09% -53.60% -70.91% Recommendatio Weight Test Rating Tensile Test Rating n Fair Excellent Use (<60%) (0-10%) Caution Not Not Recommended Recommended (over 50%) Test Weight Thickness Tensil Elongation Not Recommended (over 50%) Not Recommended (over 50%) Not Recommended (over 50%) No Data Vinyl Percent Change (%) 50.41% 14.05% -32.30% 0.57% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Vinyl Percent Change (%) 4.96% 2.73% -38.43% -26.85% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Good (0-10%) (<40%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Vinyl Percent Change (%) 2.45% -0.77% -64.99% -61.19% Recommendatio Weight Test Rating Tensile Test Rating n Use Poor Excellent (0-10%) Caution (<80%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation No Data Recommended Not Recommended Not Recommended Good (<40%) Latex Percent Change (%) 9.40% 0.40% 8.47% 4.34% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Excellent Recommended (<20%) (0-10%) Not Not Recommended (over 50%) Recommended Not Not Recommended Recommended (over 50%) Test Weight Thickness Tensil Elongation Latex Percent Change (%) 31.11% -3.10% -56.28% -57.81% Recommendatio Weight Test Rating Tensile Test Rating n Fair Poor Use (<60%) Caution (31-50%) Not Not Recommended Recommended (over 50%) Not Not Recommended Recommended (over 50%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation Excellent to Good (0-20%) No Data Not Recommended (over 50%) Not Recommended (over 50%) Latex Percent Change (%) 175.71% -12.85% -25.88% 16.61% Recommendatio Weight Test Rating Tensile Test Rating n Test Weight Thickness Tensil Elongation Latex Percent Change (%) -11.98% 4.31% -5.84% -7.19% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (<20%) (0-10%) Excellent to Good Recommended (0-20%) Fair to Poor Use (21-50%) Caution Test Weight Thickness Tensil Elongation Latex Percent Change (%) 3.51% -1.23% -0.84% -6.98% Recommendatio Weight Test Rating Tensile Test Rating n Excellent Recommended Excellent (0-10%) (<20%) Excellent to Good Recommended (0-20%) Excellent to Good Recommended (0-20%) Test Weight Thickness Tensil Elongation REFERENCES 1. United States Department of Labor, Occupational Safety and Health Administration (OSHA). Dermal Exposure. https://www.osha.gov/SLTC/dermalexposure/ (accessed July 2014). 2. Reuscher, E. Chemical Contact. J Ind Hyg Toxicol. (2012), 46(1), 34-35. 3. American Society for Testing and Materials (ATSM): Standard Test Method for Rubber Property – Effect of Liquids (D471). [Standard] Philadelphia: ATSM, 2006. 4. American National Standards Institute, International Safety Equipment Association (ANSI/ISEA): American National Standard for Hand Protection Selection Criteria (105). [Standard] Virginia: ISEA, 2011. 5. Ansell Healthcare Limited. Chemical Resistance Guide: Permeation and Degradation Data, 8th ed. http://www.ansellpro.com/download/Ansell_8thEditionChemicalResistanceGui de.pdf (accessed May 2014). 6. Forsberg, K.; Van Den Borre, A.; Henry III, N.; and Zeigler, J. P. Quick Selection Guide to Chemical Protective Clothing, 6th ed. New Jersey: John Wiley & Sons, Inc., 2014 7. American Chemical Society, Chemical Abstracts Services (CAS): CAS Registry. http://www.cas.org/content/chemical-substances (accessed May 2014). 70 8. Centers for Disease Control and Prevention (CDC), National Institute for Occupational Safety and Health (NIOSH): Recommendations for Chemical Protective Clothing: A Companion to the NIOSH Pocket Guide to Chemical Hazards. http://www.cdc.gov.niosh/ncpc/pcpc.html (accessed Jun 2014). 9. Goa, P.; Tomasovic, B. Change in Tensile Properties of Neoprene and Nitrile Gloves after Repeated Exposures to Acetone and Thermal Decomposition. J Occup Environ Hyg 2005, 2, 543-552. 10. Hatada, K.; Fox, R. B.; Kahovec, J.; Maréchal, E.; Mita, I.; and Shibaev, V. Definitions of Terms Relating to Degradation, Aging, and Related Chemical Transformations of Polymers. Pure & Appl. Chem 1996, 68(11), 2313-2323. 11. Anna, D. H. Chemical Protective Clothing, 2nd ed.; American Industrial Hygiene Association: Fairfax, VA, 2003. 12. Occupational Safety and Health Administration (OSHA). Hazard Communication Safety Data Sheet Quick Card. https://www.osha.gov.Publications/Hazcomm_QuickCard_SafetyData.html (accessed June 2014). 13. International Labor Organization. The Chemical Safety Data Sheet or the Material Safety Data Sheet (MSDS). http://www.ilo.org/oshenc/part-ix/usingstoring-and-transporting-chemicals/item/1242-case-study-hazardcommunication-the-chemical-safety-data-sheet-or-the-material-safety-datasheet-msds (accessed May 2014). 71 14. United States Department of Labor, Occupational Safety and Health Administration (OSHA). Occupational Chemical Database. https://www.osha.gov/chemicaldata/ (accessed June 2014). 15. American Society for Testing and Materials (ATSM): Standard Test Method for Permeation of Liquids and Gases through Protective Clothing Materials under Conditions of Continuous Contact, (F 739). [Standard] Philadelphia: ATSM, 2006. 16. US Department of Energy. Glove Selection Guide. http://www.aps.anl.gov/Safety_and_Training/User_Safety/gloveselection.html (accessed May 2014). 17. Phalen, R.; Wong, W. Tensile Properties and Integrity of Clean Room and Low-Module Disposable Nitrile Gloves: A Comparison of Two Dissimilar Glove Types. Ann Occup Hyg 2012, 56(3), 450-457. 18. Phalen, R.; Wong, W. Integrity of Disposable Nitrile Exam Gloves Exposed to Simulated Movement. J Occup Environ Hyg 2011, 8(8), 289-299. 19. Dai, G.; Raheel, M. Chemical Resistance and Structural Integrity of Protective Glove Materials. J Environ Sci Heal A 1997, A32(1), 567-566. 72