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Engineering Failure Analysis 57 (2015) 434–443 Contents lists available at ScienceDirect Engineering Failure Analysis journal homepage: www.elsevier.com/locate/efa Review Concerns of corrosive effects with respect to lightning protection systems Aidin Ghavamian a,⁎, Mohammad Reza Maghami b, Shayan Dehghan c, Chandima Gomes b a b c Department of Aerospace Engineering, Universiti Putra Malaysia, Serdang, 43400 Selangor, Malaysia Department of Electrical and Electronic Engineering, Universiti Putra Malaysia, Serdang, 43400 Selangor, Malaysia Department of Mechanical and Manufacturing Engineering, Universiti Putra Malaysia, Serdang, 43400 Selangor, Malaysia a r t i c l e i n f o Article history: Received 11 June 2015 Accepted 13 August 2015 Available online 16 August 2015 Keywords: Lightning protection system (LPS) Galvanic corrosion Down-conductor Air termination system Earth termination system a b s t r a c t Lightning protection system elements need to be selected from materials which are resistant to corrosion and should be protected from fast degradation. However, over the time corrosion will take place in the presence of galvanically dissimilar metals in the same electrolyte (moisture). Historically, copper, aluminium and copper alloys (including bronze and brass) have been used in lightning protection applications as these materials are highly conductive and abundantly available. Corrosive effects on system components are influenced by the environmental factors such as moisture, soil type and temperature that make the corrosion process highly complex in soil. As per many standards on the installation of lightning protection systems, combinations of materials that naturally form electrolytic couples shall not be used, for example copper and steel, especially in the presence of moisture, in which corrosion will be accelerated. Similarly, the conditions within soil will have adverse effects on the ground system elements. Down conductors entering corrosive soil must be protected against corrosion by a protective covering. The paper presents the causes of corrosion and recent developments in minimising the corrosion associated with lightning protection and grounding systems. © 2015 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/). Contents 1. Introduction . . . . . . . . . . . . . . . . . . . . . . . 2. Significant factors in a LPS system based on corrosion aspects. 2.1. LPS materials and coatings . . . . . . . . . . . . . 2.2. Material selection in a grounding system. . . . . . . 2.3. Environmental aspects of corrosion in LPS . . . . . . 3. Discussion . . . . . . . . . . . . . . . . . . . . . . . . 4. Conclusion. . . . . . . . . . . . . . . . . . . . . . . . Acknowledgement . . . . . . . . . . . . . . . . . . . . . . References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 434 435 435 437 438 439 440 442 442 1. Introduction Lightning is a charge of electricity that travels from a thunder cloud and can produce a very high current that can possibly damage any electrical component that it encounters. Therefore, all electrical components should be protected by a lightning protection system ⁎ Corresponding author. E-mail address: [email protected] (A. Ghavamian). http://dx.doi.org/10.1016/j.engfailanal.2015.08.019 1350-6307/© 2015 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/). A. Ghavamian et al. / Engineering Failure Analysis 57 (2015) 434–443 435 (LPS). The aim of a LPS is the transport of lightning current safely to ground [1–3]. An external LPS consists of an air termination system, a down conductor system and an earth termination system as shown in Fig. 1. The earth-termination system, also known as a lightning protection grounding system, is intended to provide a low resistance path to dissipate high current into the soil. The conductors that do this job are called down conductors [1,2,4]. The current passed by a down conductor should be dissipated securely in the soil without raising the potential of the down conductor to high values that could cause sparks. In other words, the integrity of this system is important and worthwhile for consideration [4,5]. The transient nature of lightning produces fast rise times and large magnitude currents, meaning the grounding system should perform effectively to limit the voltage imposed by the lightning [6,7]. Corrosion which occurs in the presence of different metals in the same electrolyte or similar metals in various electrolytes or various concentrations of the same electrolyte has caused many problems in electrical systems [8–11]. Among the different kinds of corrosion, galvanic corrosion has a high impact on the performance of a LPS. Galvanic corrosion is the outcome of the interaction of dissimilar metals with each other under specific environmental conditions, such as the same electrolyte. An example of common electrolyte would be rainwater [12–17]. Grounding normally refers to the connection of an electrical circuit to earth. A good grounding system would be expected to demonstrate high electrical conductivity, with the conductors being capable of withstanding large fault currents, have a long life, exhibit low ground resistance and impedance and have good corrosion resistance. A grounding system is important for human safety, reliability of the electrical equipment, fault current return and to limit the transient overvoltage. The grounding system components can be divided into a grounding conductor, grounding connector and grounding electrodes. An improper grounding system can lead to a dangerous situation which could be worse than having no grounding system at all [1,6,18–26]. The electrical engineer that designs the grounding system is often not knowledgeable of the corrosion issues. This subject comes also under the purview of the chemical engineer. Unfortunately, many practical designs only consider the electrical aspects of the best lightning protection and grounding systems and ignore possible corrosion effects [1,6,27]. Literature that discusses this issue is scarce, thus, in the work presented the cause of corrosion and recent developments in minimising the corrosion associated with lightning protection and grounding systems have been discussed. This paper also discusses the problems created by dissimilar metal bases. 2. Significant factors in a LPS system based on corrosion aspects 2.1. LPS materials and coatings Lightning protection elements are constructed from materials which are resistant to corrosion and should be protected from fast degradation. Over time, corrosion will occur in the presence of galvanically dissimilar metals in the same electrolyte (typically moisture). Historically, copper, aluminium and copper alloys (including bronze and brass) have been used in lightning protection applications as they are conductive [1,3,28]. The grounding rods that are used practically are made from copper bonded steel, galvanized steel, solid stainless steel, stainless-clad, solid copper, copper-clad and plain steel. Unfortunately, all of these materials are exposed to the corrosion issue and this reduces the performance of the grounding system [1,3,4,24,25]. Corrosion is one of the most destructive mechanisms in aluminium alloys. Corrosion pits typically start because of some chemical or physical heterogeneity on the surface, such as phase particles, defects, mechanical damage or dislocations [10,11,29–32]. Aluminium alloys include many constituent particles, which play an important role in the creation of pitting corrosion [3,32–38]. Other than aluminium, historically, bronze and copper materials have been utilised in lightning protection applications for all the surfaces on rooftops, due to their good conductivity, Fig. 1. Lightning protection system (LPS); transfer the lightning current safely to the ground. This system includes air termination, down conductor and earth termination system which is also known as a lightning protection grounding system that intended to provide a low resistance path to dissipate high current into the soil. 436 A. Ghavamian et al. / Engineering Failure Analysis 57 (2015) 434–443 Fig. 2. A multi-metal contact point (copper, iron and stainless steel) with paint coating layers, a copper conductor attached to painted iron plate with stainless steel nuts and bolts. durability and thermal characteristics. It is important that a properly installed LPS will last for a long time and maintain its integrity with only minimum repair. However, the first problem is that bronze and copper materials in contact with external painted steel or galvanized surfaces may create considerable corrosion over time and the effect is only partially alleviated by traditional methods such as repainting (Figs. 2 & 3) [12,18,39–42]. Fig. 2 shows a joint of a copper conductor made of painted iron plate with stainless steel nuts and bolts used for tightening the components. The coating of white paint of the plate is almost entirely removed by the swelling iron due to extensive corrosion. The stainless steel nuts and bolts are almost unaffected by the presence of both iron and Fig. 3. Copper-galvanized iron contact point with galvanized iron covered with a coating of paint. A painted galvanized iron box has been partially damaged by the corrosion. A. Ghavamian et al. / Engineering Failure Analysis 57 (2015) 434–443 437 copper. Fig. 3 also shows a similar situation where a painted galvanized iron box has been partially damaged by the corrosion. The corrosion process may have accelerated due to the galvanic effect between copper and galvanized iron and also the dampness of the environment. These cases clearly show that paint coating may not be a proper solution for the rapid corrosion of materials at bi-metal or multi-metal contact points. With respect to the grounding of down conductors, one of the most important factors is that the ground conductors should not be made of aluminium or aluminium alloys and if the soil is corrosive, then a corrosive protection cover must be applied to the grounding electrodes, including parts of the down conductor close to the ground [43]. Łoboda and Marciniak [3] in 2003 in Poland started a field corrosion test in a long term project of steel earthing rods. In this project several tens of rods, each having total length of 3 m with various protective coatings was embedded in various types of soil (Fig. 3). After two years of exposure in soil the rods with zinc and copper coating was removed from the soil. Subsequently, the other rods were removed (after four years of exposure in two different locations; Mielno and Inowroclaw sites (Figs. 4a, b, and 5a, b). The results depict better corrosion protection of steel earthing rods coated with pure copper compared to zinc coatings having various thicknesses of coating and using different kinds of technologies so that loss of zinc on galvanized steel rods caused extreme corrosion, while copper-bonded steel earth rods revealed little corrosion (Fig. 5a–c) [3]. 2.2. Material selection in a grounding system The materials used in the construction of a lightning protection grounding system should possess good electrical conductivity, have sufficient mechanical strength to withstand the electrodynamic stresses and electromagnetic effects of the lightning current, and demonstrate suitable resistance to corrosion in aggressive environments. Table 1 gives a general guide to materials that are normally used in a LPS based on IEC 62305-3 [3,44,45]. Gold and platinum show the best corrosion-resistance; however, the extreme high cost prevents them from using as components of grounding system. Consequently, steel, aluminium and copper are the three main metals used in grounding system applications [3]. Aluminium is subject to rapid corrosion attack due to the fact that aluminium is Fig. 4. (a) Condition of installation and (b) zinc galvanized rod exhumation's picture [3]. After two years of exposure in soil the rods with zinc and copper coating was removed from the soil. 438 A. Ghavamian et al. / Engineering Failure Analysis 57 (2015) 434–443 Fig. 5. The sample pictures show rods after removing from the soil after four years. (a) Copper-bonded coating. (b) Zinc galvanized coating. (c) Zinc electroplated coating [3]. The results depict better corrosion protection of steel earthing rods coated with pure copper compared to zinc coatings having various thicknesses of coating and using different kinds of technologies so that loss of zinc on galvanized steel rods caused extreme corrosion, while copper-bonded steel earth rods revealed little corrosion. always anodic in soil relative to other metals [46–48]. Table 1 provides information about lightning protection system materials using in different conditions. Referring to the table, the usable material in Earth is copper while aluminium is unsuitable. 2.3. Environmental aspects of corrosion in LPS In the United States, the National Fire Protection Association (NFPA 780: Standard for the Installation of Lightning Protection Systems [51]), makes it clear that copper should not be used in contact with aluminium surfaces, and vice versa. In other words, combinations of the materials should not be used that form electrolyte pairs of such a kind that in the presence of humidity galvanic corrosion is accelerated [52]. Down conductors entering corrosive soil should be protected against corrosion by a protective covering beginning at a point 0.9 m (3 ft) above grade level and extending for the entire length below grade [1,26,52]. In nature, soil corrosion of earth electrodes takes place at a rate relying on different environmental factors such as soil resistivity, dissolved salt forming an electrolyte, moisture, degree of aeration and temperature that make this situation very complex [3,53,54]. Moreover, Underwriters Laboratories (UL) Inc. says in its standard 96A Standard for Installation Requirements for Lightning Protection Systems, that copper should not be put in contact with any exterior painted steel surface [3,19,55,56]. It is obvious where steel and copper are in contact and subject to an electrolyte fluid such as rainwater, galvanic corrosion will take place. Fig. 6 shows a case where a copper conductor, fixed with brass clips to a galvanized steel roofing sheet. The site is located in a region with extremely high precipitation level in Malaysia. The figure depicts the seriousness of material degradation due to corrosion which has also been reported elsewhere [3,18]. Table 1 Lightning protection system materials and condition of use [3,5,44,45,49,50]. Material Use in open air Use in earth Use in concrete Resistance Increased by May be destroyed by galvanic coupling with Copper Solid stranded Sulphur compounds organic materials High content of chlorides – Solid stranded Solid stranded as a coating Solid stranded Good in many environments Hot galvanized steel Stainless steel Aluminium Solid stranded as a coating Solid Solid stranded Solid stranded Solid stranded Unsuitable Solid stranded Unsuitable High content of chlorides Alkaline solutions – Copper Lead Solid as a coating Unsuitable Unsuitable Acid soils Copper, stainless steel Acceptable in air, concrete and benign soil Good in many environments When low concentration of sulphur or chloride When high concentration of sulphate Copper This table shows a general guide to materials that are normally used in a LPS. Steel, aluminium and copper are the three main metals used in grounding system applications. A. Ghavamian et al. / Engineering Failure Analysis 57 (2015) 434–443 439 Fig. 6. Copper conductor in contact with galvanized steel roofing sheet fixed with brass clips in a region with extremely high precipitation level in Malaysia. In the selection process of the materials for the design of a lightning protection grounding system, the corrosion effect can be minimised by avoiding the use of unsuitable materials in an aggressive environment [1,3,57]. No combination of materials shall be used that will form an electrolytic junction, although it may be impractical to avoid a junction between dissimilar metals. The corrosion effect shall be reduced by the use of plating or special connectors, such as stainless steel connectors used between aluminium and copper or copper alloys [3,5,52]. 3. Discussion The abovementioned corrosion problems often do not constitute any danger to the function of the lightning protection system. Despite the fact that the boundaries to which LPS materials are connected will degrade, copper is considered nobler than aluminium or steel (Fig. 10). It cannot be avoided that there will be a very small effect on the efficiency of the main conductor. However, a lightning protection system cannot be presented as an independent system, but as an integral component of the whole building envelope. The importance of the LPS can only be realised in the event of a direct strike to the building and this may only happen once every few years [18]. In 1995, Durham and Durham [6] conducted research to show that variants exist concerning how to protect a tower. One approach is to place a lightning rod on top of the tower then a copper ground wire is run down the building [3,6,58–60]. However the different metals such as copper and steel cause a corrosion problem. In addition, the inductance of the long wire tends to create a highimpedance path [3,6,61]. Thus the effects of corrosion must be considered as part of the whole LPS. The deterioration of metals may not pose any immediate danger to the building materials. Roofing layers are usually overlapped, thus giving a layer of waterproofing for the second layer so that any penetration due to corrosion through the substructures will be very small at worst. On the other hand, for the case of standing-seam roofs, the primary penetration barrier is related to the metal itself. Fig. 6 shows metal corrosion on a standing-seam roof after less than 15 years in contact with a bare copper conductor [3,18,62,63]. Fig. 7. Copper in touch with a metallic standing-seam roof [18]. The suppliers have installed air-terminals grounded by bare copper strips laid on the metal roofing and facades. It is noted that the aluminium casing of the test joints that are fixed to the facades by nuts and bolts, has caused even worse corrosion problems due to the presence of various metals together. 440 A. Ghavamian et al. / Engineering Failure Analysis 57 (2015) 434–443 Likewise, sometimes it can be seen that opportunistic suppliers make unnecessary or sometimes even dangerous choices. Fig. 7 shows that the suppliers have installed air-terminals grounded by bare copper strips laid on the metal roofing and facades. It is noted that the aluminium casing of the test joints that are fixed to the facades by nuts and bolts, has caused even worse corrosion problems due to the presence of various metals together. This unnecessary installation of a LPS caused severe corrosion consequences that has damaged the building structure As is shown in (Fig. 8a, 8b) [3,4]. It is worth to note that preventative maintenance may alleviate a number of problems associated with corrosion by using different types of paint to influence the surface of the metals to slow down the oxidation process. However, as shown in Fig. 9, the prevention of any type of corrosion will not be permanently effective through painting. Due to the fact that the lightning conductor is normally braided, absorption of humidity via the spaces is unavoidable. There will always be penetration, and thus there will always be large amounts of corrosion. Even if the corrosion is very small, in accordance with the UL and LPS standards if galvanized or painted steel comes into contact with steel, it is sufficient for a lightning protection system to become non-compliant [3,27,52]. The maintenance/replacement cycle and the system life is dependent on the selection of materials and the local environment must be coordinated with the structural materials [3,18,52,64]. As mentioned before, in a LPS another fact to be taken into account is the effects of corrosive soil on the ground conductors. These conductors should not be made of aluminium and if the soil is corrosive then a corrosive protection cover should be applied to the ground rods, including part of the down conductor [18,26,43]. Also prohibited is the attachment of aluminium conductors to a surface coated with an alkaline-based paint, embedded in concrete, or set up in a location subject to high humidity [52,65]. Further, the only material allowed to be set up in contact with the earth at very humid locations is copper. Aluminium–copper alloys (including bronze and brass) and copper are the fundamental system component materials. These materials provide the best joining features in terms of weathering and current-carrying capacity. However, aluminium materials have reduced current-carrying capability and mechanical strength compared to the same sized copper products. Moreover, water will oxidise galvanized surfaces and aluminium if the water cannot run off. So coordination of system design and material selection must include consideration of galvanic corrosion as one of the problems of installation [3,64]. Since 2007, changes to the UL96A standard means that most lightning protection firms have taken up the practice of aluminium conductor installation and components on all non-copper external metal surfaces. As the conductivity of aluminium is less than copper, cables made of aluminium are larger and therefore more visible. This issue has the advantages of using materials that are less noble than the materials to which they are attached (Fig. 10) [3,18,52]. Despite the fact that the aluminium will tend to degrade over time instead of the substructure in practice, the impact of the lightning conductor will be minimal and the LPS performance will not be greatly hampered [18]. 4. Conclusion To ensure the integrity of a structure, both the LPS and the structure such as rooftop surfaces are considered as part of the building. In other words, the LPS should not be considered as a separate system so that it can maintain its full capability for as long as possible in-station. In this case, by improving the lightning protection materials by selecting only those materials suitable for the LPS and Fig. 8. An all-metal structure (supporting struts, roof, and facades) installed with ESE air terminations and bare copper down conductors in contact with the building material. The air termination and painted aluminium test joint could be seen in both pictures a and b. The picture has been taken soon after the installation of the system. A. Ghavamian et al. / Engineering Failure Analysis 57 (2015) 434–443 441 Fig. 9. Corrosion between a painted conductor and a painted unit [18]. adjusted for the substructure, the risk of galvanic corrosion can be reduced. This will ensure that both systems exceed or meet their anticipated service life. In this way, the safety of the building contents, its structural integrity, and the residents can be guaranteed. The importance of the choice of materials by making them a priority to ensure proper maintenance of their performance in the installed location is an essential factor. In some cases, persistent vendors insist on installing unnecessary LPS materials which can cause grave corrosion consequences that can damage the building structure and subsequently result in high-cost structural repairs. Despite the relevant costs, when the opportunity arises it would be beneficial in the long-run for building owners to replace the copper components on the external steel surfaces with aluminium. It is suggested that the bronze and copper materials that pose no immediate danger can be retained in place to protect the structure, as long as the whole system remains in conformance with the published standards. However, if substantial roof work is required, it is proposed that the lightning protection system should Fig. 10. The galvanic series, despite the fact that the boundaries to which LPS materials are connected will degrade. Copper is considered nobler than aluminium or steel. As the conductivity of aluminium is less than copper, cables made of aluminium are larger and therefore more visible. This issue has the advantages of using materials that are less noble than the materials to which they are attached. 442 A. Ghavamian et al. / Engineering Failure Analysis 57 (2015) 434–443 be brought into full compliance where possible. It may be helpful to note that notwithstanding the above, that bronze and copper will constantly be the materials of choice in places where corrosion is not possible such as with non-metallic surfaces. 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