Download Material Safety Data Sheet

Material Safety Data Sheet
Regulation (EC) No 1907/2006
Version 3.0 Revision Date 01/09/2014
Date 13.03.2015
1. IDENTIFICATION OF THE MIXTURE AND COMPANY IDENTIFICATION
1.1 Product Tags
Product Name: MetZyme®Suno™
Item number: 936
REACH Pre-registration: WN406904-16
CLP Number: 647-017-00-5
1.2 Identification of the substance or mixture Relevant identified uses and
uses advised against
Identified uses: Use the industrial production of biochemicals, biofuel- or
Pulp and paper industry as an excipient.
1.3 Material Safety Data Sheet supplier details
seller / producer: MetGen Ltd
Rakentajantie 26,
20780 Kaarina, Finland
Phone +358 (0) 22377077
Email [email protected]
1.4 Emergency telephone number
Emergency telephone number: Poison Information Centre 358 9 4711
2. HAZARDS IDENTIFICATION
2.1 Identification of the substance or mixture
Classification with Regulation (EC) No 1272/2008 [EU-GHS / CLP].
Respiratory sensitization (Category 1)
EU Directives 67/548 / EEC or 1999/45 / EC Classification
Inhalation may cause sensitization.
2.2 Label elements
The labeling of the regulation (EC) No 1272/2008 [CLP].
Warning sign
Word
Danger
Hazard statement (s)
H334 May cause allergy or asthma symptoms or difficulty in breathing.
Precautionary statement (s)
P261 Avoid breathing dust / fume / gas / mist / vapors / spray
P285 Wear respiratory protection if ventilation is inadequate.
P304 + P341. IF INHALED: If breathing is difficult, remove victim to fresh air
and keep at rest in a position comfortable for breathing.
P342 + P311 If experiencing respiratory symptoms: Call POISON CENTER or
physician.
P501 Dispose of contents / container to hazardous waste
Directive 67/548 / EEC and as amended.
Indication of danger
/ Xn /
Harmful
R-phrases
R42 May cause sensitization by inhalation.Phrases
S23 Do not breathe gas / fumes / vapor / spray.
2.3 Other hazards - no other risk factors for non-PBT or vPvB
3 COMPOSITION AND INGREDIENTS
3.1 Substances
Component Concentration
enzyme protein
CAS-No.
80498-15-3
EC-No.
420-150-4
Index-No. 647-017-00-5
4. FIRST AID MEASURES
4.1 Description of first aid measures
Special instructions
Consult a physician. Show this safety data sheet to the doctor in attendance.
Inhalation
If breathed in, move person to fresh air. If not breathing, give artificial
respiration. If the patient is allergic symptoms consult doctor.
Skin contact
Wash off with soap and plenty of water. Remove contaminated clothing and
wash.
Eye contact
Flush eyes with water for at least 15 minutes, may not be chemically neutralize,
if irritation persists, consult a doctor.
After ingestion
The patient is given plenty of water to an unconscious person or convulsions
Never give anything by mouth and immediately consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The substance is irritating to the respiratory tract, excessive exposure may lead
to sensitization and allergic symptoms such as henkitysvaikeuksia especially
lung diseases and allergy sufferers.
4.3 Indication of any immediate medical attention and special treatment
needed
If breathing is difficult patient to fresh air breathing guarantee a position to rest.
If hengityoireet persist / worsen should contact a POISON CENTER or
physician.
5. FIRE-FIGHTING MEASURES
5.1 Extinguishing media
foam, powder or carbon dioxide ABC
5.2 Special hazards arising from substance or mixture
The carbon and nitrogen fire decomposition products are harmful to the
environment.
5.3 Advice for firefighters
Wear a self-contained breathing apparatus (NIOSH / MSHA), and protective
equipment for fire fighting. Packages can be cool with water.
6. ACCIDENTAL RELEASE MEASURES IN
6.1 Personal precautions, protective equipment and emergency
procedures
Isolate the accident in the area and use the personal protective equipment.
Avoid dust formation. Avoid breathing vapors / fumes / gas inhalation. Ensure
adequate ventilation. Evacuate personnel to the area. Wash or abandoned
polluted clothes.
6.2 Environmental precautions
Remove mechanically, it is recommended for downloading (note: the HEPA
filter) The solid is collected in appropriate containers for disposal. Small
amounts may be diluted with plenty of water while preventing aerosol formation
and to flush a suitable drain.
6.3 Clean-up methods
Remove mechanically, it is recommended for downloading (note: the HEPA
filter). The solid is collected in appropriate containers for disposal. Small
amounts may be diluted with plenty of water while preventing aerosol formation
and to flush a suitable drain. Contaminated materials stored in closed
containers for disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Keep away from acids, bases, combustible organic substances or other easily
oxidizable materials. Do not freeze, keep away from open flames and heat
sources.
7.2 Conditions for safe storage, including any incompatibilities
Keep in a cool place. Keep container tightly closed in a dry state.
7.3 Specific end use
no data available
8. EXPOSURE AND PERSONAL SAFETY
8.1 Control parameters
Contains no substances with limit values.
8.2 Exposure controls
8.2.1 Appropriate engineering controls
The substance must be handled in well ventilated areas, with good industrial
hygiene and safety practice. Wash hands before breaks and after work.
8.2.2. Personal protective equipment
Eye and face protection
Face shield and safety glasses Use equipment for eye protection tested and
approved under appropriate government standards such as NIOSH (US) or EN
166 (EU) with appropriate protective equipment.
Skin and body protection
Wear protective gloves when handling. (EN 374) neoprene or polyvinyl alcohol
Body protection
Wear long-sleeved Uniforms. Type of protective equipment must be selected at
the specific workplace
of the dangerous substance according to the concentration and amount.
Respiratory protection
Normal dust protection, use type P95 (US) or type P1 (EU EN 143)
a better level of protection of use type OV / AG / P99 (US) or type ABEK -P2
(EU EN 143) respirator.
8.2.3 Environmental exposure controls
Eye removed immediately and prevent aerosol formation.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 The basic physical and chemical characteristics of the product
a state: Brown liquid
b Odor: Sweet, earth like
c Odor threshold: Not specified
d pH 7 +/- 0.5
e Not specified
f Not specified
g Not specified
h Not specified
i Not specified
j Not specified
k Not specified
l Not specified
m Relative density: Fixed
Solubility: Soluble in water, also in other solvents
n Not specified
p Not specified
q Not specified
r Not specified
s Not specified
t Not specified
9.2 Other safety instructions
no data available
10. STABILITY AND REACTIVITY
10.1 Reactivity
No data available
10.2 Chemical stability
Stable
10.3 Possibility of hazardous reactions
Not observed; not hazardous reactions
10.4 Conditions to avoid
Not found
10.5 Incompatible materials
No known
10.6 Hazardous decomposition products
There is none
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute toxicity
The product is not toxic
Skin corrosion / irritation
The product is not a primary skin irritant, but prolonged contact with the skin
should be avoided.
Serious eye damage / eye irritation
Exposure to the substance causes irritation.
Respiratory or skin sensitization
Inhalation may cause sensitization and / or an allergic reaction in susceptible
people. Does not cause skin symptoms.
Germ cell mutagenicity
no data available
Carcinogenicity
This product is no ingredient which is at least 0.1% is identified as probable,
possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity
single exposure no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration
May cause allergy or asthma symptoms or breathing difficulties sensitized
12. ECOLOGICAL INFORMATION
12.1 Toxicity
data are not available, however, the enzymes are not known to be particularly
dangerous to the environment
12.2 Persistence and degradability
data are not available, however, the product is an enzyme and the enzyme is
known to be soluble in water and is unlikely to permanent. In addition, the
enzymes are 100% biodegradable
12.3 Bioaccumulative
data are not available, however, the product is completely soluble in water,
therefore, is not likely to bioaccumulate, in addition to the enzymes are 100%
biodegradable.
12.4 Mobility in the soil
no data available
12.5 Results of PBT and vPvB assessment
no data available
12.6 Other adverse effects
no data available
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
The product and its surplus is not classified as hazardous waste EU Directive
91/689 / EC. Contaminated packaging should be rinsed before disposal.
14. TRANSPORT INFORMATION
14.1 UN number
ADR / RID: - IMDG: - IATA: 2.14 shipping name
ADR / RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
14.3 Transport hazard class
ADR / RID: - IMDG: - IATA: -
14.4 Packaging class
ADR / RID: - IMDG: - IATA: 14.5 Environmental hazards
ADR / RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
no data available
15. REGULATORY INFORMATION
This Material Safety Data Sheet Conforms to Regulation (EC) No 1907/2006.
15.1 specific for the substance or mixture Safety, health and
environmental codes or legislation
Conforms to EU Directives 67/548 / EEC and 1999/45 / EC requirements when
used in the textile, biofuel- or paper and pulp industry.
15.2 Chemical Safety Assessment
Information not yet available
16. OTHER INFORMATION
More information
Copyright 2015 MetGen Ltd. Unlimited copying of internal use,
The above information is correct to the best of the current knowledge, but they
should be used only as a guide. Metgen Ltd is not responsible for any kind of
damage caused by the handling or from contact with the substance.