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REAGENTS, INC.--MSDS—BARIUM CHLORIDE, AQUEOUS PAGE 1 BARIUM CHLORIDE SOLUTION, 1 - 36% Company Information Company's Name: REAGENTS, INC. Company's Address: P.O. Box 240746, Charlotte, NC 28224; USA Company's Info Ph #: 704/554-7474, 800/732-8484 Date MSDS Prepared/Revised/Reviewed: 13 October 2010 1. Product Identification CAS No.: 10326-27-9 [10361-37-2 (Anhydrous)] Chemical Formula: BaCl2.2H2O in H2O Product Codes: 7-14702; 7-14703; 853-R; B-1003; B-1004; B-1005; B-1006; B-1026; B-1028; B-1109; B-1112; B-1116; B-1118; B-1120; B-1121; B-1138; B-1139; B-1141; B-1144; B-1147; B-1153; B-1155 2. Composition/Information on Ingredients Ingredient CAS No Percent --------------------------------------- --------------- -----------Barium chloride dihydrate 10326-27-9 1 - 36% Deionized water 7732-18-5 Remainder EC No. -------------233-788-1 231-791-2 Index No. -------------------056-004-00-8 --- 3. Hazards Identification Emergency Overview: May be fatal if swallowed. Harmful if inhaled or absorbed through skin. May cause irritation to eyes, skin and respiratory tract. OSHA Hazards: Toxic by ingestion, Target Organ Effect Target Organs: Heart, Nerves, Kidneys, Gastrointestinal tract, Bone marrow, Spleen, Liver HMIS Classification NFPA Rating Health Hazard: 2 Health Hazard: 2 Chronic Health Hazard: * Fire: 0 Flammability: 0 Reactivity Hazard: 0 Physical hazards: 0 Lab Protective Equip: Goggles, Gloves, Lab Coat Storage Color Code: Blue (poison) Potential Health Effects: Inhalation: Irritates the respiratory tract. May produce sore throat, coughing and labored breathing. Other symptoms may parallel ingestion. Ingestion: Toxic! May cause severe gastroenteritis, including abdominal pain, vomiting and diarrhea. May cause tremors, faintness, paralysis of arms and legs, and slow or irregular heartbeat. Severe cases may produce collapse and death on respiratory failure. Estimated lethal dose in humans: 1 gram solid. Skin Contact: May cause irritation with redness and pain. Eye Contact: May cause irritation, redness, pain, or blurred vision. Chronic Exposure: No information found. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or impaired respiratory function may be more susceptible to the effects of the substance. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, give water or milk if conscious and induce vomiting as directed by medical personnel. Get immediate medical attention. After vomiting, a mixture of 1 tablespoon of sodium or magnesium sulfate (Epsom salts) dissolved in 8 oz. of water to drink maybe indicated to precipitate the barium as the nontoxic and insoluble barium sulfate. Skin Contact: In case of skin contact, immediately flush skin with large amounts of water while removing contaminated clothing and shoes. Get medical attention immediately. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. REAGENTS, INC.--MSDS—BARIUM CHLORIDE, AQUEOUS PAGE 2 Note to Physician: Monitor patients with significant ingestion for respiratory, cardiovascular, and blood pressure status. Watch for cardiac arrhythmias, respiratory failure due to flaccid paralysis of respiratory muscles, pulmonary edema, vocal cord paralysis, severe hypertension, and late effect kidney failure. Acute barium poisoning results in hypokalemia. The administration of fluids containing dilute concentrations of potassium salts may be indicated. 5. Fire Fighting Measures Fire: Not considered a fire hazard. Explosion: Not considered an explosion hazard. Fire Extinguishing Media: Use any means suitable for surrounding fire. Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full-face piece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Do not allow product to enter drains. Discharge to the environment must be avoided. 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Separate from incompatibilities. Containers of this material may be hazardous when empty since they retain product residues; observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: OSHA Permissible Exposure Limit (PEL): 0.5 mg (Ba)/m3 ACGIH Threshold Limit Value (TLV): 0.5 mg (Ba)/m3 A4 - not classifiable as a human carcinogen Ventilation System: A system of local and/or general exhaust is recommended. Personal Respirators: Where risk assessment shows air-purifying respirators are appropriate, use a full-face respirator with multipurpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. Skin Protection: Wear impervious protective clothing as appropriate to prevent skin contact. Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Clear liquid. Odor: Odorless. Solubility: Miscible. Boiling Point: No information found. Vapor Density (Air=1): No information found. Evaporation Rate (BuAc=1): No information found. Specific Gravity: 1.00 – 1.28. pH: 5.0 – 8.0. % Volatiles by volume @ 21C (70F): >65 (water) Melting Point: No information found. Vapor Pressure (mm Hg): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Barium oxide, hydrogen chloride. Hazardous Polymerization: Will not occur. Incompatibilities: Strong oxidizing agents, bromine trifluoride, 2 -furan percarboxylic acid. Conditions to Avoid: Incompatibles. 11. Toxicological Information Oral rat LD50: 118 mg/kg (anhydrous). Estimated lethal dose human is 1g. Investigated as a tumorigen (dihydrate). No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP, OSHA, ACGIH (A4 - not classifiable as a human carcinogen) or IARC. 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found. REAGENTS, INC.--MSDS—BARIUM CHLORIDE, AQUEOUS PAGE 3 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved RCRA waste facility. This material may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Proper Shipping Name: Toxic Liquid, Inorganic, N.O.S. (Barium Chloride) Hazard Class: 6.1 UN/NA: UN3287 Packing Group: III Marine pollutant: No Poison Inhalation Hazard: No 15. Regulatory Information OSHA Hazards: Toxic by ingestion, Target Organ Effect TSCA: All components are listed (barium chloride as anhydrous, CAS No. 10361-37-2). SARA 302 Components: None. SARA 313 Components: Barium Chloride (Barium Compounds), N040. SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard CERCLA Hazardous Substance: None. Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 or Class 2 Ozone depletors. Clean Water Act: Does not contain any Priority Pollutants. Massachusetts Right To Know Components: None. Pennsylvania Right To Know Components: Barium chloride dihydrate, CAS No. 10326-27-9; Water, CAS No. 7732-18-5. New Jersey Right To Know Components: Barium chloride dihydrate, CAS No. 10326-27-9; Water, CAS No. 7732-18-5. California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. DSL Status: All components of this product are on the Canadian DSL list (barium chloride as anhydrous, CAS No. 10361-37-2). 16. Other Information Product Use: Laboratory Reagent. Disclaimer: Reagents, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. Reagents, Inc. makes no representations or warranties, either express or implied, including without limitation any warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or the product to which the information refers. Accordingly, Reagents, Inc. will not be responsible for damages resulting from use of or reliance upon this information. ****************************************************************************************************