Download 6М072100 – chemical technology of organic compounds

AL-FARABI KAZAKH NATIONAL UNIVERSITY
Faculty of Chemistry and Chemical Technology
Education programme on specialty
«6М072100 – chemical technology of organic compounds»
Approved at the meeting of Academic Council of
Chemistry and Chemical Technology Faculty
(the protocol № 1, August 28, 2014)
Dean of Chemistry and Chemical Technology Faculty
_______________E.K. Ongarbayev
SYLLABUS
Base elective module №1 MPOT
«Modern technologies of processing of organic substances»
STPOV 5503 «Modern technologies of processing of organic substances»
I year magistracy, e/g, spring semester, 3 credits
Lecturer:
Chopabayeva Nazira Nabievna, doctor of chemical sciences, associated professor
Department of chemistry and technology of organic substances, natural compounds and
polymers.
Mob.: +7 701 2332837
e-mail: [email protected]
room: 525
Teacher of seminar lessons:
Chopabayeva Nazira Nabievna, doctor of chemical sciences, associated professor,
Department of chemistry and technology of organic substances, natural compounds and
polymers.
Mob.: +7 701 2332837
e-mail: [email protected]
room: 525
Aim and tasks of discipline:
Aim: studying of technological features of industrial methods of synthesis and processing of
various organic compounds.
Tasks: giving knowledge about various sources of obtaining of industrially important organic
compounds, up-to-date methods of their obtaining and processing, general and special chemical
properties of these compounds and methods of manufacturing control on each technological
stage.
Competences:
instrumental: possession of ability to use and transform of cognitive abilities and innovative
technologies for searching nonstandard, creative decisions in professional activity;
interpersonal: ability to generate innovative creative ideas, promot reasoned conclusions;
system: ability to be guided and adapt to new working conditions.
object: ability to describe open scientific researches and projects on chemistry of synthetic and
natural organic compounds.
Prerequisites: organic chemistry, chemistry of natural and high molecular compounds, physical
chemistry, chemical technology and catalysis.
STRUCTURE AND CONTENT OF DISCIPLINE
Title of subject
Week
Hours
Ball
Module 1
1
Lecture.
Introduction. Sources of organic compounds. Current
development of organic synthesis. Fundamental and practical significance.
1
2
2
Seminar. Methods of industrial processing of organic compounds.
Updated classical and novel synthetic methods. Retrosynthetic analysis.
Lecture. Strategy and tactic of organic synthesis.
Seminar. Technological processes and devices.
2
Lecture. 12 Principles of green chemistry.
1
Seminar. “Green” chemical processes and technologies.
2
9
SWM 1. Use of computer programs in organic synthesis.
1
6
4
Lecture. Application of microwave methods in green chemical
1
5
technologies.
Seminar. "Green chemical technologies” part 1. Green chemistry of
silicon-containing compounds.
Lecture. Technology of application of green mechanochemical methods.
3
Seminar. "Green chemical technologies” part 2. Green chemistry of nitrogencontaining compounds: achievements and application.
SWM 2. Chemistry of acetylene: achievements and prospects.
6
Lecture. Application of ultrasonic methods in green chemical
7
technologies.
Seminar. "Green chemical technologies” part 3. Green chemistry of
oxygen-containing compounds: achievements and application.
Lecture. New ways of phosphorus activation.
Seminar. "Green chemical technologies” part 4. Phosphorus-containing
compounds. Traditional and “green” methods of synthesis, application and
significance for development of Kazakhstan economy.
SWM 3. Sulphur-, phosphorus-containing compounds: thiophosphates,
9
1
2
9
9
1
2
9
1
1
6
2
9
1
2
9
1
6
phosphorus pentasulphides.
Colloquium
8
19
100
Lecture. New ways of sulfur activation: mechanical, microwave, using
superbasic medium.
Seminar. "Green chemical technologies” part 5. Green chemistry of
1
2
8
sulphur-containing compounds: achievements and application.
100
MidTermExam
Module 2
Lecture. Nanochemistry and nanomaterials: classification, preparation,
stabilization, investigation and application.
1
Seminar. Nanotechnology.
2
8
SWM 4. Carbon nanotubes: synthesis, investigation and application.
1
5
Lecture. Supramolecular chemistry.
1
Seminar. Supramolecules: synthesis and properties.
2
Lecture. Chemistry and technology of dendrimers.
1
Seminar. Synthetic methods for dendritic molecules. Special chemical
2
8
1
5
12
reactions of dendritic molecules. Special properties and potential
application.
SWM 5. Rotaxanes and polyrotaxanes: synthesis and supramolecular
structures.
Lecture. Chemistry of calixarenes.
2
13
Seminar. Thiacalixarenes, calixarenes: synthesis, structure, application in
chemistry and biology.
Lecture. Combinatorial synthesis: principles, tools and advantages.
Seminar. Design of pharmaceuticals molecules. Combinatorial synthesis
2
8
1
1
5
2
8
9
10
11
14
15
of acyclic structures.
SWM 6. Single molecular chemistry.
Lecture. Ionic liquids: structure, activation, application in science,
biotechnology, energy, chemistry.
Seminar. Laboratory and industrial methods of preparation and
purification of ionic liquids.
Lecture. Superacids and superbases: structure, activation mechanisms
and application.
Seminar. Superacids and superbases for organic synthesis.
SWM 7. Femtochemistry.
Colloquium
Exam
8
1
8
1
1
2
8
1
5
16
100
100
REFERENCES
Basic
1. Смит В.А., Дильман А.Д. Основы современного органического синтеза. М.: Бином,
2009. – 750с.
2. Смит В.А., Бочков А., Кейпл Р. Органический синтез. М.: 2001.
3. Tsutomu Ishikawa. Superbases for Organic Synthesis: Guanidines, Amidines,
Phosphazenes and Related Organocatalysts. John Wiley & Sons, 2009. – 340 р.
4. Guozhong Cao, Ying Wang. Nanostructures and Nanomaterials: Synthesis, Properties &
Applications (2nd edition). Singapore: World Scientific Publishing Co. Pte Ltd, 2010. –
520 p.
5. Vogtle F., Richardt C., Werner N. Dendrimer chemistry. Wiley-WCh Verlag, 2009. –
350p.
6. Лебедев Н.Н. Химия и технология основного органического и нефтехимического
синтеза. М.: Химия, 1975.
7. Балоян Б.М., Колмаков А.Г., Алымов М.И., Кротов А.М. Наноматериалы.
Классификация, особенности свойств, применение и технологии получения.
Москва, 2007. – 125с.
8. Гусев А.И. Наноматериалы, наноструктуры, нанотехнологии. – М.: Физматлит,
2005. – 416с.
9. Cергеев Г.Б. Нанохимия. М.: МГУ, 2003. – 288с.
10. Тимохин Б.В., Дмитриченко М.Ю. Основы комбинаторного синтеза: теоретическое
пособие. – Иркутск: Иркут. ун-т, 2003. – 40с.
11. Федорова О.А. Супрамолекулярная химия: учеб. пособие.– М.: РХТУ им. Д.И.
Менделеева, 2010. – 204 с.
1.
2.
3.
4.
5.
6.
Кобояси Н. Введение в нанотехнологию. М.: 2008.
Успехи химии. 1998-2010 гг.
Журнал органической химии. 2000-2010 гг.
Журнал Россииского общества им. Д.И. Менделеева. 1999-2008 гг.
Нефтехимия. 1998-2010 гг.
Толстиков А.Г., Толстиков Г.А. и др. Современные проблемы асимметрического
синтеза. Екатеринбург. 2008. 207 с.
ACADEMIC POLICY OF COURSE
All types of works need to be done in time. Master students, who have not done task or
have got less than 50% of balls can fulfill task according to additional schedule. Master students,
who missed laboratory lessons due to good reason, need to fulfill these lessons after admission of
teacher in an extra time in the presence of laboratory assistant. Master students, who did not
carry out all types work, are not allowed to exam. Master students activity and lessons
attendance are evaluated.
Tolerance and respecting of other person’s opinion are requested. Correct formulation of
objections is also needed. Plagiarism and other forms of dishonest activity are unacceptable.
Writing off during pass the SWM and exam, copying of tasks by other persons, passing an exam
instead of other master students are inadmissible. Master student, convicted of falsification of
any information, unauthorized access to the Internet, using cribs will be evaluated "F".
Consultations on SWM, exam and other questions will be given by teacher during his working
time.
Evaluation by
alphabetic system
А
АВ+
В
ВС+
С
СD+
DF
I
P
Digital
ball equivalent
4,0
3,67
3,33
3,0
2,67
2,33
2,0
1,67
1,33
1,0
0
-
Percentage
95-100
90-94
85-89
80-84
75-79
70-74
65-69
60-64
55-59
50-54
0-49
0-60
65-100
Evaluation by traditional
system
Excellent
Good
Satisfactory
Unsatisfactory
Incomplete
Pass
NP
-
W
AW
AU
АT.
-
Not AT
R
-
0-29
0-64
30-60
50-100
0-29
0-49
-
No Pass
Withdrawal
Academic Withdrawal
Audit
Attested
Not attested
Retake
Syllabus is approved at the meeting of department of chemistry and technology of organic
substances, natural compounds and polymers, protocol № 1, August 28, 2014.
Chair of department of chemistry
and technology of organic matters,
natural compounds and polymers
G.A. Mun
Lecturer
N.N. Chopabayeva