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“Our civilization runs by burning the remains of humble creatures who inhabited the Earth hundreds of millions of years before the first humans…” - Carl Sagan 1 Catalytic converter • Cerium • Lanthanum Battery • Lanthanum • Cerium LCD screen • Europium • Yttrium • Cerium Electric motors and generator • Dysprosium • Neodymium • Praseodymium • Terbium Fig. 14-2, p. 350 Dynamic processes within the earth and on its surface produce the mineral resources on which we depend Mineral resources are nonrenewable Produced and renewed over millions of years mostly by the earth’s rock cycle During the carboniferous period, lasting from about 350- 300 million years ago, much of the Earth was ideal for plant growth. The overall climate was warm. Glaciers retreated. Much of the land mass was near the equator. 5 The dominant plants during this time were fern-like trees. The trees evolved a new carbon-based chemical compound called lignin. This formed the basis of their bark. No bacteria , fungus, or insect had yet evolved the ability to decompose lignin. The forests, with few limiting factors, grew massive and numerous. Plants of the Carboniferous Age. Meyers Konversationslexikon, 1885-1890. 6 The surplus of photosynthesis drove oxygen levels up, reaching concentrations in the atmosphere near 35%. Arthropods, which breathe through their exoskeletons, were no longer size-restricted by available oxygen. Model of a Meganisoptera, a giant dragonfly. 7 A short, intense ice age eventually led to the demise of these forests. Nearly 50 million years of accumulated plant matter (lignin) became buried under swamps. As the plant material was exposed to greater amounts of pressure and heat, it became coal. 8 Increasing heat and carbon content Increasing moisture content Lignite Peat (brown coal) (not a coal) Anthracite (hard coal) Bituminous (soft coal) Heat Heat Heat Pressure Pressure Pressure Partially decayed plant matter in swamps and bogs; low heat content Low heat content; low sulfur content; limited supplies in most areas Extensively used as a fuel because of its high heat content and large supplies; normally has a high sulfur content Highly desirable fuel because of its high heat content and low sulfur content; supplies are limited in most areas Stepped Art Fig. 15-11, p. 383 Today, the countries with the greatest coal deposits line up with the locations of largest carboniferous swamps – North America, Northern Europe, and Asia. 10 TRADE-OFFS Coal Advantages Ample supplies (225– 900 years) High net energy yield Low cost Well-developed technology Air pollution can be reduced with improved technology Disadvantages Severe land disturbance, air pollution, and water pollution Severe threat to human health when burned Environmental costs not included in market price Large government subsidies High CO2 emissions when produced and burned Radioactive particle and toxic mercury emissions Fig. 15-15, p. 385 Coal was first widely used in China. Europeans were astonished at its ability to produce heat, as written by Marco Polo: “Throughout the whole province of Cathay are a kind of black stones cut from the mountains in veins, which burn like logs. They maintain the fire better than wood. If you put them on in the evening they will preserve it the whole night, and it will be found burning in the morning.” 12 The demand for coal increased tremendously during the industrial revolution of the late 19th century as the steam engine was developed. Today, it is almost exclusively used for electricity generation. Midwest Generation Power Plant, Waukegan, Illinois. 13 Today, the largest coal-fired power plant in the world is the Taichung Power Plant, located in Taiwan. The plant uses a total of nearly 15 million tons of coal per year. One open hopper train car holds 100-125 tons of coal. A coal train will have 100-125 cars. Taichung uses over 1,100 train loads of coal per year, just over 3 per day. 14 Shallow deposits of coal can be removed by surface mining. This process requires the removal of all vegetation and topsoil before the deposit can be accessed. Open-pit mining is where large holes are dug into the earth and the minerals removed. Ffos-y-fran Land Reclamation Scheme, Wales, U.K. 17 Strip mining actually carves away horizontal beds of coal deposit close to the surface. Mountaintop removal is a method that uses machines and explosives to expose seams of coal underneath entire mountain tops. 19 The cumulative effects of mountaintop removal can be seen from satellite, as shown in this NASA Earth Observatory slideshow of the Hobet Mine in West Virginia. 21 Subsurface, or underground mining, removes coal through deep tunnels and shafts. Most of the removal is done by machine and conveyor belt. The mining machines generate high amounts of explosive coal dust. 23 Coal dust can build up in the lungs over long periods of time, causing Black Lung disease. Normal lung tissue. Mild case of Black Lung disease. Severe case of Black Lung disease. 24 Once the coal is extracted, its potential energy converted to electricity in a power plant. The coal is pulverized into a powder, then blown into the boiler. The heat from the boiler converts water into steam. Pressure from the steam causes a giant set of turbine blades to spin. The shaft of the turbine is connected to a generator, where magnets spin within wire coils to generate electricity. 25 Coal is about 90% carbon, 4% hydrogen, and 3% oxygen, and about 1% sulfur. This is similar to the chemical composition of plants. When coal is burned for fuel, it combines with oxygen in air to form several air pollutants, including: Carbon dioxide, CO2 Sulfur dioxide, SO2 Nitrogen oxides, NOx Fine black particles of carbon (soot) Pleasant Prairie Power Plant, Wisconsin. Source: www.kevinpalmer.com 26 Burning coal also produces a great deal of leftover ash. The ash contains toxins and heavy metals including arsenic, cadmium, chromium, lead, mercury, and radioactive radium. The ash is usually mixed with water, to minimize dust, then pumped into a temporary storage pond. Eventually, 70-80% of this ash is disposed of in landfills. The rest is used in concrete, asphalt, and other applications. Power plant and coal ash ponds, Asheville, North Carolina. 27 Conversion of solid coal to Synthetic natural gas (SNG) by coal gasification Methanol or synthetic gasoline by coal liquefaction Are there benefits to using these synthetic fuels? TRADE-OFFS Synthetic fuels Advantages Disadvantages Large potential supply Low to moderate net energy yield Higher cost than coal Vehicle fuel Requires mining 50% more coal Environmental costs not included in market price Moderate cost High environmental impact Large government subsidies Lower air pollution than coal when burned High water use Higher CO2 emissions than coal Fig. 15-16, p. 386 Like coal, most of the oil on Earth was formed millions of years ago. Certain warm shallow seas, such as the Gulf of Mexico and Tethys Sea, were so ideal for life that organic material was formed faster than it could decompose. Large masses of organic material became buried at the sea bottom, were heated and pressurized, forming oil. 30 The present day distribution of oil lines up with these ancient shallow seas. Majority of oil reserves are in Middle Eastern countries. 31 32 In elemental composition, oil is similar to coal. Mostly carbon, but also hydrogen, nitrogen, oxygen and sulfur. As a liquid, oil can be distilled (separated) into other fuels such as gasoline, kerosene, and diesel fuel. 33 As a liquid, oil can be pumped directly out of the ground. This eliminates the need for mining. A long drill is used to bore deep into the Earth to reach the deposit. The hole is lined with a steel pipe and cement. The top is outfitted with collection pipes and valves. 34 The ease of transporting oil has enabled drilling at very remote locations. At its peak, Alaska accounted for about 25% of the U.S. oil production. It is transported to the southern ports of the state through the Alaska Oil Pipeline. 35 As a liquid, oil can also escape more easily, forming an oil spill. Oil spills are devastating to marine life. Penetrates through the fur and feathers of animals, reducing their ability to fly, float, and insulate themselves. Benthic organisms, living at the bottom of the sea, can be suffocated. Entire populations of krill and plankton can be wiped out. Exxon Valdez oil spill, 1987. 36 Of the fossil fuels, oil has been the most quickly depleted. Peak oil is defined as the point at which known all known oil reserves have been tapped and production will begin declining in the following years. The United States reached its peak production in the 1970s. The estimated date of worldwide peak oil is unknown. Natural gas is actually a mixtures of gases. 50-90% methane. Smaller amounts of propane and butane. As a gas, it is the most difficult fossil fuel to transport. A supply of natural gas exists above most oil wells, however, if no pipelines are nearby, it will often simply be burned off. 38 TRADE-OFFS Conventional Natural Gas Advantages Disadvantages Ample supplies High net energy yield Low cost Less air pollution than other fossil fuels Lower CO2 emissions than other fossil fuels Easily transported by pipeline Low land use Good fuel for fuel cells, gas turbines, and motor vehicles Nonrenewable resource Releases CO2 when burned Gas turbine Government subsidies Environmental costs not included in market price Methane (a greenhouse gas) can leak from pipelines Difficult to transfer from one country to another Can be shipped across ocean only as highly explosive LNG Fig. 15-10, p. 382 One of the biggest advantages in natural gas is the relatively small amount of pollution produced by burning it. The only two waste products are carbon dioxide and water vapor. 40 Hydraulic fracturing, or “fracking”, is a controversial technique used to extract natural gas from rock formations (such as shale) that are not very permeable. 41 Fracturing has become an increasingly popular tool for extracting natural gas, especially with the discovery of the methane-rich Marcellus Shale. 42 First, a mixture of water and other chemicals is pumped into a narrow hole drilled into the rock formation. The pressure created from this fluid causes the rock formation to crack. Sand is injected afterwards to fill the cracks, because it is more permeable and allows the methane to seep out. 43 There are two big issues that make hydraulic fracturing controversial. Millions of gallons of water are needed to “frack” the well. The water that returns back to the surface, called flowback water, is contaminated with minerals, fracturing fluid chemicals, and natural gas itself. Water trucking containers, Dimock, Pennsylvania. 44 The disposal of flowback water has been a major source of contamination. Due to an exemption given to gas drillers in a 2006 law, they do not have to disclose the full list of chemicals injected into a well. These chemicals include carcinogens and endocrine disruptors. Water collected from a well in rural Bradford County, Pennsylvania. 45 Fossil Fuels currently provide about 85% of all commercial energy in the world. Other renewable sources (wind, solar, hydroelectric) make up 7% of commercial power. Nuclear power makes up 8% of commercial power. 46 The richest 20 countries consume nearly 80% of natural gas, 65% of oil, and 50% of coal production annually. On average, each person in the U.S. and Canada uses more than 300 GJ of energy annually. In the poorest countries of the world, each person generally consumes less than one GJ annually. 47 The environmental and human costs of extracting fossil fuels ultimately lies with those who use them the most. 48 Sludge Pharmaceutical plant Local farmers Sludge Greenhouses Waste heat Waste heat Waste heat Fish farming Waste heat Oil refinery Surplus natural Electric power plant gas Surplus sulfur Surplus natural gas Waste calcium sulfate Fly ash Waste Cement manufacturer heat Sulfuric acid producer Wallboard factory Area homes Fig. 14-25, p. 367