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Chapter 3: Mass Relations: Stoichiometry: The study of mass relations in chemistry Stoichiometry • All Stoichiometry is based on the Law of Conservation of Mass Section 11-1 3.1 Atomic Masses • Atomic mass unit (AMU) is defined as 1/12th the mass of a carbon – 12 atom. • The weighted average of the masses of the isotopes of an element create the elements atomic mass. – Remember completing weighted avg??? Atomic Mass vs. Molar Mass • A.M.U works for theory, but we can not measure individual atoms • Must create molar mass. • Avagadro’s number, number of atoms of carbon-12 it takes to weigh exactly 12 grams. • 6.02 x 1023 atoms = 1 mole 3.2 Mole Mountain #1 3.3 Percent Composition • Remember the poison worksheet? • What is the % of Carbon in glucose C6H12O6 3.4 Reaction Stoichiometry • How do we know how much we need, how much will be created. • Think of a reaction as a recipe, Reactants → Products Must be a Balanced Equation Mole Mt. # 2 Limiting Reactant • Why do reactions stop? – Eventually we run out of reactants – The reactant we run out of first, stopping the reaction, is the limiting reactant – Any reactant that is left over is the excess reactant If I have 400 tires, 150 engines, 200 steering wheels, and 300 bucket seats (2 per car), how many complete cars could I make? What is the limiting reactant? What is excess reactant? S8(l) + 8Cl2(g) → 4S2Cl4(l) 200.0g S and 100.0g Cl2 Determine which is the limiting reactant Percent Yield • Reactions do not always produce all of what they should. • ____________ yield is how much should be produced based on the limiting reactant • ____________ yield is how much is actually produced in an experiment Percent Yield Percent yield is important in the cost effectiveness of many industrial manufacturing processes. If you are supposed to make 100 pounds of aspirin, and only produce 50 pounds, the company has now lost money.