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Sedimentary Rocks Deposited on or Near Surface of Earth by Mechanical or Chemical Processes Sedimentology is study of sediments. The Oxford English Dictionary defines sediments as "that material which settles to the base of a liquid." Liquids, in this case may be: water - riverbed or beach deposition air - sand dunes, aeolian dust gas - volcanic ash flows 1 Sedimentary Cycle 2 What Rocks Tell Us Rock Type Igneous Sedimentary How Classified Composition Texture Chemical Composition Grain Size Composition Metamorphic Mineral Makeup Texture What it Tells Us Tectonic Setting Cooling History Surface Environment Energy of Environment Original Rock Type Temperature, Pressure Degree of Change 3 Sedimentary Rocks are the Principal Repository for Information About the Earth’s Past Environment EARTH HISTORY! 4 Environmental Clues in Sedimentary Rocks • Grain Size - Power of transport medium • Grading - Due to sudden events followed by waning energetics • Rounding } Transport, Reworking • Sorting • Cross-bedding Wind, wave or current action 5 Environmental Clues in Sedimentary Rocks • Fossils (some examples) – Salt Water - Corals, Echinoderms – Fresh Water - Insects, Amphibians – Terrestrial - Leaves, Land Animals • Color And Chemistry – Red Beds - Often Terrestrial (oxidized iron) – Black Shale - Oxygen Poor, Often Deep Water – Evaporites – Arid Climates 6 Two features characterize sediments and sedimentary rocks: a detrital fabric and the presence of layers, or bedding Sedimentary Fabric Settling produces a detrital fabric i.e. a fabric with point contacts between grains, rather than a fabric of interlocking grains found in igneous or metamorphic rocks. 7 Bedding or Stratification • Almost always present in sedimentary rocks • Originally horizontal • Tilting by Earth forces later • Variations in conditions of deposition • Size of beds (Thickness) – Usually 1-100 cm – Can range from microscopic to 50m 8 Graded Bedding Often largest particles settle first, followed by successively smaller ones so that the particles are sorted more or less according to size. Normal grading - the coarsest material on bottom, getting finer grained towards the top This suggests an initial energetic event, followed by waning energy (e.g. a flood, turbidity currents) 9 Bedding • Bedding is a series of visible layers within the rock. It is primarily due to episodic nature of sedimentation where very fine particles are laid down slowly between times of more rapid deposition. • Bedding planes are assumed to be originally horizontal or nearly horizontal for water-laid sediments. • For aeolian (wind-laid or sub-aerial) more commonly show cross-bedding, because the sand can support steeper dune surfaces in air than in 10 water. Modern ripples in loose sediment ancient ripples preserved in sandstone Sedimentary Structures • Often, evidence of the nature of the sedimentary surface are preserved in sedimentary rocks 11 Mud cracks on the bottom of a modern puddle. Mud-cracks form because clay minerals may shrink by up to 15% in volume on drying out. Mud-cracks can be preserved and indicate a depositional environment that is near shore and periodically exposed to air. Mud cracks in Cambrian rocks in southwestern Virginia. Even the curls of the flaking mud are preserved. 12 Sorting • Sorting - is the measure of range of particle size of sediments. A sediment having a wide range of particle size is said to be poorly sorted and if the range is small, the sediment is said to be well sorted. 13 14 Settling is the key process, and is dependent on : size of grain (d) density of grain (rg) fluid velocity and turbulence fluid density (rf) and viscosity (m) Settling Velocity r g r f g 2 d 18m (Stokes Settling Law) 15 Sedimentary Rocks Clastic Rocks • Made of fragmentary material • Deposited by – Water (most common) – Wind – Glacial action – Gravity Biochemical Sedimentary Rocks • Evaporation • Precipitation • Biogenic sediments 16 Clastic Rocks • Clastic sediments are those derived from the weathering, transportation and deposition of older rocks. The term "clastic" comes from the Greek klastos (= broken), indicating the broken nature of the sediment. (An individual particle is a clast) • also known (somewhat confusingly) as detrital sediment, or detritus, which is Latin for "worn down" • As erosion occurs predominantly on the land, they are also termed terrigenous sediments (terra 17 = Earth) Clastic Rocks are classified by: • Grain Size (Sand vs. Gravel vs. Silt, etc.) • Grain Composition (Quartz vs. Feldspar, etc.) • Texture (rounded grains, sorting, etc.) 18 Sediment Sizes and Clastic Rock Types Rock Type Sediment Grain Size Shale Clay less than 0.004 mm Siltstone Silt .004 - 0.064 mm Sandstone Sand .064 - 2 mm Conglomerate* Pebbles 2mm - 64 mm Conglomerate* Cobbles 64 mm - 256 mm Conglomerate* Boulders > 256 mm Sedimentary rocks made of silt- and clay-sized particles are collectively called mudrocks, and are the most abundant sedimentary rocks. * rocks with rounded clasts are conglomerates. Those with angular clasts are breccias Conglomerate / Breccia (less commonly Rudite / Rudaceous Rocks) Lithified gravel (grains over 2 mm) with rounded grains are called conglomerates. The name can be modified by the size of the predominant particles. Thus we can have a boulder conglomerate, cobble conglomerate, pebble conglomerate or granule conglomerate. Conglomerate Breccia 20 Sandstone (less commonly Arenite / Arenaceous Rocks) Lithified sand (grains between 2 mm and 1/16th mm) is called sandstone, or, less commonly, arenite. The name may be modified by the grain size (eg. very coarse sandstone through to very fine sandstone) or grain composition. 21 A sandstone composed of a significant amount (> 25%) of feldspar is called an arkose (or arkosic sandstone). If feldspar is present in significant quantities, but less than 25%, it may be termed a feldspathic sandstone. 22 A sandstone composed of mainly rock fragments is called a lithic sandstone (or a litharenite). A poorly sorted lithic sandstone with angular to sub-angular grains with a fine, muddy or clay matrix is called a greywacke. 23 Mudstone (Argillaceous Rocks) Mudstones are fine grained clastic rocks, which may be divided into siltstone and claystone. Although mudstones are too fine to easily determine their mineralogy, they are most commonly composed of quartz and clay. If there is a significant proportion of quartz, the rock will be gritty, whereas if it is nearly all clay it will feel slimy. The best way of determining ‘grittiness’ is to scrape the rock on the underside of your teeth! A gritty texture defines a siltstone, whereas a slimy texture is a claystone. The abundance of clay minerals (micas) means that the rock may have a tendency to break along planes that are parallel to bedding, due to the original orientation of the clays when they settled. This property is called fissility. Fissile mudstones are 24 termed shales. SHALES 25 Clastic Sediment Composition What the grains are composed of. Generally this involves determining the amount of quartz grains, feldspar grains Chemical Sediments and rock fragments. mineral aggregates precipitated out of natural bodies of water such as lakes, lagoons and oceans. The components were transported in solution and then chemically precipitated out of solution. Biogenic Sediments sediment composed mainly of fossil remains Residual Sediments products remaining after intensive chemical breakdown of rock exposed to attack by natural agents such as oxygen, water and organic and inorganic acids. Pyroclastic Sediments result from violent volcanic eruptions - typically produces a mixture of angular fragments of mineral grains, volcanic glass fragments, and volcanic rock fragments. When deposited by primary volcanic processes = “pyroclastic.” If reworked by wind or water it can best be called a “volcaniclastic sediment.” Because quartz (SiO2) is abundant and relatively resistant to chemical weathering it makes up the bulk of sand-sized particles. Fine particles (silt and clay) are carried to regions where the water is still (off-shore environments). Clay minerals that are the weathering products of feldspars and ferro-magnesian minerals form the bulk of these particles. Coarse products (boulders and cobbles) require fast moving water (mountain streams) to be moved at all, and so are not transported very far from their sources. These particles may be unweathered and retain their source mineralogy and chemistry. Intermediate-sized particles (sand) are transported by rivers and wind and deposited on river bottoms, at coasts or in deserts. 27 Sediment Maturity • Stability of Minerals (e.g. - feldspar, micas unstable; quartz is very stable) • Rock Fragments (most rock fragments not as durable as individual grains) • Rounding or Angularity (well rounded grains have been through a lot of abrasion, angular ones are “fresher”) • Sorting (well sorted deposits have had processes acting on them longer than poorly sorted ones) Removal of unstable ingredients suggests Mechanical Working 28 Shape - there are two main things to look at here: the grains’ roundness and sphericity Sphericity Roundness 29 Diagenesis (making a rock from loose sediment) After sediments are deposited, they are commonly compacted by the weight of overlying sediments. Compaction Cementing • Quartz • Calcite • Iron Oxide • Clay • Glauconite • Feldspar Alteration • Limestone - Dolomite • Plagioclase – Albite Recrystallization • Limestone 30 After sediments are deposited, they are commonly compacted by the weight of overlying sediments. They may be lithified (solidified) by the deposit of a cement or secondary mineral that fills the pores. They may also be lithified by recrystallization of the primary minerals. 31 32 Circulating pore water contains dissolved minerals that may precipitate out of solution, producing a cement. Calcium carbonate is a common cement. Silica is not quite as common, but forms an extremely tough rock when it forms the cement. Circulating pore water may also dissolve minerals from the rock. Such dissolution is particularly common in carbonate rocks and may lead to an increase in pore space. Replacement involves the essentially simultaneous dissolution of existing minerals and the precipitation of a new mineral. Occasionally, delicate carbonate skeletons can be pseudomorphed by 33 microcrystalline quartz crystals. Chemical Sediments Evaporites -Water Soluble • Halite • Gypsum • Calcite Precipitates Example: Ca(sol'n) + SO4 (Sol'n) = CaSO4 • Gypsum • Limestone • Iron Formations Alteration After Deposition • Dolomite Biogenic Sediments • Limestone - Shells, Reefs, Etc. Organic Remains • Coal • Petroleum 34 Biogenic Rocks: Limestone is the rock formed by calcite. Calcite (CaCO3) is very near saturation in sea water and so is used as shells material by marine organisms. Most calcite rocks of Phanerozoic age (the last 600 million years) are of biological origin. Dolostones (formed of dolomite (CaMg(CO3)2) may also be formed in this way. 35 Limestone 36 Fossils often form a major component of limestones but not always. Limestones are composed chiefly of calcium carbonate (CaCO3). Calcium carbonate reacts with acids (e.g. - HCl) according to the equation: CaCO3 + 2HCl => CaCl2 + H2O + CO2 (gas) and an audible and visible "fizzing" occurs as the CO2 is released. 37 Limestone is also relatively easy to dissolve compared to other lithologies. When buried, dissolution can be initiated due to pressure. (more soluble under high P) Dissolution occurs along planes that have a jagged appearance to them. Those planes are called stylolites and are frequently black due to the accumulation of insoluble material such as clays and organic detritus. 38 Stylolites 39 Some special kinds of limestones • Chalk - a limestone composed of the shells of tiny, planktonic one-celled organisms. • Coquina - a limestone composed exclusively of large shell fragments. 40 Oolites are small spherical concretions, commonly formed by calcite that was deposited around a sand grain, shell fragment, or some other foreign particle in shallow, wave-agitated water. Oolites form where gentle or periodic wave action in warm marine waters allow carbonate precipitation on all sides of a grain of sand or shell fragment. Large Oolites are called Pisolites or Peastone. 41 Evaporites • Dissolved material (Ca, Na, K, CO3, SO4, Cl) is carried farthest and deposited where the ocean, sea, or lake is evaporated off. • Such rocks are called evaporites. As sea water is evaporated, the sequence of minerals formed is ( ( ( ( 1) calcite (CaCO3) 2) gypsum (CaSO4.2H2O) 3) halite (NaCl) and 4) sylvite (KCl) halite 42 Evaporite Formation 43 Some Weird Chemical Rocks: Lake waters may have different chemistries, depending on the source rocks in the catchment area for the waters. Salts that may precipitate from lake waters include: sodium carbonate (Na2CO3), (for example, lakes in the East Africa Rift Zone) sodium sulfate (Na2SO4) and borax (Na2B4O7.10H2O), which have important commercial applications. Phosphorous Deposits The calcium phosphate, apatite (Ca5(PO4)3(OH,F), can also precipitate from seawater if deep ocean waters, enriched in phosphorous by the decay of marine animals, are brought to the surface by upwelling currents and reach saturation in a shallow basin. Such deposits may be economically valuable sources of 44 phosphorous, which is used as a fertilizer. Chert When silica is precipitated, it forms chert. Chert may form extensive, continuous bands or as nodules in carbonate rocks (flint). (Many banded cherts have formed from the deposition of silica organisms, so are classified as biogenic rocks rather than chemical.) 45 Banded Iron Formations In the past, Fe2+ has formed precipitates in remarkably continuous bands or laminations, known as banded iron formations (BIF). These formed when the atmosphere had very much less oxygen in it than it does today, allowing the dissolution and transportation of Fe2+. Later oxidization of the iron transformed it to Fe3+ which has a much lower degree of solubility and so precipitated out of solution. 46 Banded Iron Formation 47 Coal • A biogenic sedimentary rock composed essentially of lithified plant debris • Delta, continental environments • Carbonized Woody Material • Often fossilized trees, leaves present 48 Coal Seams, Utah 49 Plant Fragments Are Often Visible in Coal 50 Coal forms from the accumulated remains of plants that have not decayed. As the plant material is buried and put under increasing heat and pressure the non-carbon elements are driven off to produce a sequence of substances increasingly concentrated in carbon. Need: Plant rich environments with little oxygen in the water (swamps, bogs --> peat --> coal) (peat --> lignite --> bituminous coal --> anthracite) 51 Thick coals require very thick peats, for which there are three requirements: • Steady, high groundwater levels. Water cover suppresses oxidation and alteration of plant debris. The water level needs to be maintained at the ground surface as subsidence is balanced by peat accumulation. Rising waters flood peatland, forming a lake, whereas falling water levels allow the drying of peat and erosion. • No sediment influx. An input of terrigenous sediment will lead to the formation of shale, rather than coal. • Tectonic stability. A gentle subsidence is required to allow the slow, uninterrupted accumulation of plant debris. Tropical settings are favored, but not required, for peat formation due to the more luxuriant growth of plants and the lower rate of 52 decay. Fossil Fuels 53 Petroleum A hydrocarbon molecule What organisms make these? Answer: None 54 Petroleum • Lots of organisms make these, however • Fatty Acids • Probable source: Marine plankton 55 Petroleum Traps 56 Facies Changes 57 Sedimentary Environments The fundamental property of any sedimentary rock is that grains have to be transported from a source and deposited somewhere. One reason for studying sedimentary rocks is to try to understand the conditions of the sedimentary basin in which the sediments were deposited. There are a relatively limited number of basic types of sedimentary environments. Each depositional environment has its own distinctive sets of physical, chemical and biological characteristics, that result in distinctive lithologies. The characteristics of any particular environment is known as the facies. Adjacent facies can merge into each other gradually or abruptly. By determining the facies of ancient rocks, we can reconstruct the sedimentary environments that were operating at that time. 58 Let’s visit each of the environments and see at least some of the types of deposits found there... 59 Important concept: Migrating Facies Sedimentary environments change over time with changing conditions. At the shoreline, for example, there may be a river facies, beach facies and shallow marine facies. At any one time, sediments are deposited in these facies in a sub-horizontal manner. 60 If conditions were to change such as a rise in sea level, the facies would migrate laterally. Stream sediments would now be deposited further inland, beach sediments would be deposited over the older stream sediments and shallow marine sediments would be deposited on top of the older beach sediments. This is known as a marine transgression. 61 With continued sea level rise (or the sinking of the land), the facies migrate further towards the land. The end result may be a layer of river sediment overlain by beach sediment that, in turn, is overlain by shallow marine sediments. The diagrams shown here are vertically exaggerated. In reality, the three facies form almost horizontal strata. However the layers were not deposited in that order (stream, beach, marine), rather each layer represents the change in the position of the facies over time - the layers were built horizontally, rather than vertically. Time lines A vertical succession of sedimentary strata therefore represents facies that occurred in laterally adjacent environments, provided that no erosion events have occurred between the strata (Walther's Law Johannes Walthers, 1894). 62 Terrestrial Sedimentary Environments: Stream sediments (fluvial, alluvial sediments) Streams are the principal means of transporting sediment across land,and stream deposits can be seen nearly everywhere. A wide variety of depositional environments gives a wide range of sediments in terms of composition, grain size, sorting, rounding etc. In general, where streams are close to their headwaters, they carry coarse, angular, poorly sorted deposits. These regions are high energy regimes, however, where erosion is dominant, rather than deposition, so the deposits are rarely preserved. Where mountain streams emerge onto relatively flat plains, the sediment is deposited in an alluvial fan. 63 Alluvial Sediments deposited by rivers deposited on channel bottoms, on floodplain, and on levees Meandering Streams: As river turns a bend, water velocity is greatest on the outside of the curve, and lowest on the inside therefore erosion is greatest on the outside, and deposition is greatest on the inside 64 Point Bar Cut Bank Slowest velocities Fastest velocities Channel migration THALWEG 65 Meandering Stream Cross-Section Deposition Silt and clay Erosion muds sand gravel sands Gravels, rip-up clasts Channel bottom deposits are the coarsest, topped by sands, silts and clays (finer sediments) Overall fining upwards sequence 66 Some features commonly found in channels Ripples 67 Cross-bedding 68 Fining upwards sequence 69 Oxbow Cut-offs • fill with fine grained sediments (clays and organic sediments) • isolated “clay lenses” in sands and silts 70 Flood Stage During floods - as flooding waters emerge from the channel, they slow down and deposit silts and sands. Do this enough years and you build up... --> LEVEES (sands and silts, getting finer as you move away from the channel) 71 Eventually, the river surface may be above the surrounding floodplain (especially during floods) (but possibly even during nonflood times!) The river may escape through the levee temporarily in what is known as a Crevasse Splay, depositing sand and silt on the neighboring floodplain. Less commonly, the levee will be permanently breached, and the river will abandon its old path and follow a new course 72 AVULSION Crevasse Splay Avulsion - abandoning the old channel and following a new course. (e.g. - the Atchafalaya River, Louisiana) 73 FLOODPLAINS: deposition of suspended mud during floods with later desiccation, soil formation and plant growth. a. sediment is thick beds of mud, especially clays b.laminated to homogeneous mudstones with rootlets, soils c. sheet units 74 clay Silt and clay sand gravel x-section, looking “upstream” map view sand Overall pattern: Silt and clay Coarse channel and levee deposits (which each individually fine upwards) isolated in fine grained floodplain deposits 75 Braided streams • A series of anastomosing channels • Bifurcating and rejoining around mid-channel bars • These bars are typically coarse-grained deposits, and variously eroded and deposited in a complex pattern • Braided streams form in environments with high slopes and abundant coarse-grained sediment supply. • Therefore, generally coarse-grained and very permeable 76 77 Lake sediments (lacustrine) Lakes are low energy environments, where the gradient and water velocity is very low. Deltaic sediments are deposited at the inflow, passing into well sorted, finer, laminated layers. Yearly cycles may produce varves of alternating finer and coarser material. 78 Varved clays Rhythmic deposition of clays and silts/sands, especially in glacial lakes Annual summer melting of glaciers releases coarser material During winter glaciers refreeze, and only fine-grained material (still settling out) is deposited 79 Glacial sediments: Debris eroded by a glacier is released by the melting at the snout or base of the glacier. Grain sizes vary from boulders to clay and are characteristically unsorted, non-stratified and angular. The unlithified sediment is known as till, and the resulting rock is known as tillite. 80 Aeolian sediments Wind blown sediments are generally sand to silt sized. Sand may form into dunes that are well sorted with bedding inclined downwind. Aeolian silt (“loess”) is a common sediment, but is virtually unknown as a sedimentary rock, presumably because it is so easily eroded. 81 (Namibian coast satellite photo) 82 Continental Shelf Environments: Estuarine Environment •Much of the load transported by a large river may be trapped in the low energy environment of an estuary. • Muds settle out as clays flocculate when saline waters are encountered. Clay minerals have a surface negative charge and tend to stay in suspension in fresh water as like charges repel. When saline water is encountered, the cations are attracted to the clay surfaces, neutralizing them. Adjacent particles can then approach each other and aggregate. • If the sedimentation rate is high and the land is slowly subsiding, thick bodies of estuarine form. Estuarine environments have increased from 18,000 years ago, sediment can due to the flooding of river systems by rising sea level since the last glacial maximum. 83 Deltaic Environment Marine deltas are built where large river systems deposit their load on entering the sea. The coarsest sediments are deposited near the river mouth and finer ones are carried further out. The size and shape of the delta depends on the interplay of sediment supply by the river and removal by waves and longshore drift. Yukon Delta 84 Deltas: When running water enters a body of still water, its momentum is checked, velocity drops, and sediment is allowed to be deposited The coarsest-grained material drops out first, finest drops out last (and therefore travels the furthest from the shore) Topset beds Sands and gravels Foreset beds Sands and silts Bottomset beds Silts and clays As the delta builds out into the standing body of water, the sediment coarsens upwards 85 Deltas often grade upwards into stream deposits (either meandering or braided - see those descriptions) as the river and deltas grow out into the standing water body Ganges Delta Nile Delta 86 87 Beach Environment: Beach sediments are typically well sorted and rounded due to the winnowing effects of wave action and the constant abrasion as the particles are washed back and forth. Sandy quartz beaches are the most common, but beaches many times consist of the coarsest sized particles available, so cobble beaches also occur. 88 89 Coastal areas are particularly dynamic environments Waves affect only depths less than 1/2 their wavelength, so shallow water is more energetic (and will have coarser grained deposits associated with it) Currently, the oceans are undergoing sea level rise, though recently (12,000 ybp) sea level was much lower (-100m) Sands (from beaches, barrier islands, etc.) interfinger with clays and silts (from lagoons, off-shore areas) to form complex stratigraphy Barrier Island sands Offshore muds Lagoon muds 90 Offshore Environments (continental shelf): Most coarse marine sediment is deposited within 5 to 6 km of the land. Shelf sediments are distributed over the entire shelf, however, as sea level as a result of changing sea levels in the past. Up to 70% of the sediment cover on continental shelves is probably a relict of past conditions. The great bulk of the Earth's sedimentary strata is formed from continental shelf sediment, as only about 10% of the sediment reaching the continental shelves remain in suspension long enough to arrive at the deep sea. The shelves effectively conserve continental crust which is recycled with active tectonic conditions are generated. 91 92 Carbonate shelf Carbonate sediments are largely of biogenic origin where terrestrial input is minimal and sea temperatures are warm enough to promote abundant carbonate secreting organisms. Carbonate shelves can accumulate thick deposits of fine, massive carbonates. Coarser sediments are found near coral reefs in areas of higher turbulence and strong currents. Carbonate platforms are relatively rare today, but were much more abundant in the past, where higher sea levels inundated large tracts of continental land masses. Bahamas 93 Spectacular coral reefs and atolls occur in the oceans growing in 4,000-5,000 m of water, yet coral growth is clearly limited (by light) to less than 30m of water. Coral growth must be fast enough to keep pace with the gradual submergence of the reef due to plate tectonic movements and changes in sea level. 94 Marine evaporite basins : Saline waters occupying restricted basins in warm climates will evaporate, leading to the saturation of salts and the formation of evaporitic mineral deposits. A modern example of such a restricted basins is the Mediterranean Sea. Warm surface waters from the Atlantic flow east and evaporate, increasing their density. The saline waters sink and salts crystallize on the bottom, forming evaporite deposits. Evaporites underlying the Mediterranean basin are 2 to 3 km thick. If the Mediterranean became landlocked, it would precipitate a salt layer about 70 m thick over the 1000 years it would take to evaporate. These relative thicknesses indicate the importance of a continuous inflow and evaporation over long periods of time to accumulate significant deposits. Evaporation ocean Barrier to circulation High salinity 95 Continental Rise Environments: Turbidites Gravity driven turbidity currents consisting of dilute mixtures of sediment and water flow down the continental slope. With mixing, the mass expands, becomes more turbulent and erodes the material at its base. Velocities of over 90 km/h have been recorded, and flows can spread almost 1000 km from their source. 96 Graded bedding Sole marks (rock flipped upside down - looking at bottom 97 Deep Ocean (Abyssal) Environments: Deep-sea oozes: In temperate oceans less than ~4 km deep, calcareous ooze forms as carbonate secreting organisms die and settle to the bottom. Cooler, deeper waters can dissolve more carbon dioxide, so carbonates particles are dissolved in deeper waters. Other parts of the ocean are mantled with siliceous ooze formed from siliceous organisms. Siliceous ooze is most notable in the equatorial Pacific and Indian Oceans and around the Antarctic, where upwelling deep ocean water rich in nutrients leads to high biological activity. Siliceous oozes are one theorized way for cherts to form. 98 99 Manganese Nodules: Concretions with elevated concentrations of Mn, Fe, Ni, Cu, Co Redox reactions: • Reducing conditions in sediments mobilize Fe, Mn, etc; • Oxidizing conditions in ocean waters precipitate Fe, Mn, etc. oxides as nodules Their growth is very slow (mm per million years) - therefore, they require a SLOW sedimentation rate in order not to be buried by sediments. 100 - Far from continents!