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Physics 8.04 MIT September 19, 1373 Exercises for Chapter 2 Due: September 26 PUT ON YOUR PAPER THE HOUR AND INSTRUCTOR'S NAME FOR YOUR SECTION 10. Resolving power of an electron microscope A fundamental result of physical optics is that no optical instrument can resolve the structural details of an object that is smaller than the wavelength of the light by which it is being observed. A similar analysis applies to the deBroglie wavelength of electrons in an electron microscope. It is desired to study a virus of diameter 0.02 micron (= 200 8). This is.impossible with an .optical microscope (wavelength about 5000 8) but can be done with an electron microscope. Calculate the voltage through which electrons must be accelerated to give them a deBroglie wavelength 1000 times smaller than the linear dimension of the virus, so as to permit formation of a very good image. f C •'•} 11. The domains of special relativity and of quantum mechanics It is generally accepted that the domain of experience in which non-relativistic mechanics is valid is that in which particles move with speed v such that v/c « 1 in the frame of observation. (That this rule has exceptions is witnessed by the fact that^ magnetic effects are essentially relativistic , but may be produced by electric charges moving at 1 mm/sec in a wire!)' In a similar manner we can set as a criterion for the validity of non-quantum mechanics that the deBroglie wavelength of particles in the system under consideration be much less than some characteristic dimension of the system:A/r « 1 , where X is the deBroglie wavelength and r is some characteristic dimension. Use these criteria to determine which of the following systems are likely to require relativity and/or quantum mechanics for their description. (a) Electron in the atom. Calculate the speed of an electron in the lowest (n = 1) Bohr orbit of hydrogen. What is the ratio of this speed to the speed of light? Are we justified in using a non-relativistic analysis of the hydrogen atom? Carry out a similar analysis for an electron in the inner orbit of mercury (Z = 80). Use the deBroglie relation to calculate X/r for the electron.in the lowest energy state of hydrogen. Does your result verify that we need to use quantum physics to describe the behavior of electrons in atoms? Assume that (b) Proton in the nucleus. 12 one of the protons in a T--V cm ) executes an orbit large nucleus (nuclear radius ££ 10 inside the nucleus with 'kinetic energy 10 MeV. Is special relativity required to describe this motion? (Compare kinetic energy with rest energy.) Calculate A/r for the orbiting proton. Do we need to use quantum physics to describe this nuclear system? Physics 8.04 Exercises Chapter 2 page 2 (exercise 11., continued) (c) Electrons in an accelerator. The Cambridge Electron Accelerator (CEA) on Oxford Street at Harvard University accelerates electrons along an approximately circular path to a terminal kinetic energy of 6 GeV (6 x 10 eV). Does the analysis of the electron orbits require the use of relativistic mechanics? The radius of the orbit is 30 meters. What is the ratio A/r for the electrons at terminal energy? Would you expect that the engineers who designed the magnets whose field holds -the electrons in orbit found it necessary to use quantum physics in their calculations? i 12. The Bohr atom derived from deBroglie's relation Here is another development of Bohr's results for hydrogen, based directly on the deBfoglie relation. If a deBroglie wavelength can be associated with an electron in orbit, then it seems reasonable to suppose that the circumference of an orbit be equal to an integral number of wavelengths. Otherwise (one might argue) the electron would interfere destructively with itself. Leaving to one side the mongrel-like nature of this argument (which employs both words like "orbit 11 and words like "wavelength"), apply it to rederive Bohr's results for hydrogen using the following outline or some other method. (a) Calculate the speed and hence the magnitude of the momentum of an electron in a circular orbit in a hydrogen. (Use the answer to lla.) (b) Use the deBroglie relation to convert momentum to wavelength. (c) Demand that the circumference of the circular orbit be equal to an integral number of deBroglie wavelengths. (d) Solve for the radii of permitted orbits and calculate the permitted energies. Check that they conform to Bohr's results, as verified by experiments. (e) As an alternative method, omit all mention of forces and simply use the deBroglie relation and the condition of integer number of wavelengths in a circumference to show directly that the angular momentum rp.(for the circular case) equals an integer times \\/2ir. This is just the condition that we showed earlier (lecture of 9/17) leads most simply to the Bohr results. (See also text, page 1-25.) . - 13. Single-slit diffraction A sufficiently wide single slit illuminated by light or other wave casts on a distant screen a "geometrical image" of width equal to that of the slit* However, close examination reveals that the edges of this image are fuzzy, and if the slit is made narrow and narrower, the image ultimately becomes wider than the width of the slit. i'-i Physics 8.04 Exercises Chapter 2 page 3 i * (exercise 13, continued) Moreover, if the slit is illuminated with monochromatic light a series of light and dark fringes appear on either side of the central image, as shown below. This phenomenon is called diffraction and results from the wave nature of the disturbance being propagated. A simple analysis accounts for the observed intensity pattern (see, for example, Vibrations and Waves in this series, page 288). Here we develop only one result of that analysis the width of the central image on a distant screen and apply it to diffraction of light (part b below) and diffraction of deBroglie waves (next exercise). The fundamental technique is to divide the slit analytically into sub-slits, treat each sub-slit as a line source in phase with all the others, and add the effects of these sub-slits at a distant point r - A J, « > V i O The left-hand figure shows this subdivision for a propagation direction in which we expect to observe the zero intensity nearest to the central maximum. This direction is such that the sub-slit I 1 just below the center of the opening is a distance X/2 more distant from the screen than the sub-slit 1 just below the top of the opening. If this condition is satisfied, the wave from I 1 will cancel the wave from 1 at the screen. Similarly the wave from 2 1 will cancel the wave from 2, and so forth. As a result, no net propagation takes place in the direction indicated by 9 in the figure. This analysis assumes*that the observing screen is a distance D away much greater than the slit width d (official name: Fraunhofer diffraction). * . (a) Complete the analysis to show that the first zero of. intensity occurs at an angle 9 from the forward direction given by ''' sin = X/d (slit) and that the assumptions in the problem lead to the approximation Physics 8.04 Exercises Chapter 2 page 4 (exercise 13 continued) sin 0 23 0 £J tan 9 so that the central maximum in the diffraction pattern has total width W given by t W £ 2 A D/d (slit) ! . x For a circular aperture the analysis is more complicated but leads to results that differ only slightly in numerical value sin 0 = 1.22 A /d (circular hole) W 2 2.44 A D/d where d is the diameter of the hole. . ' . (b) Pinhole camera design To see, how diffraction effects enter design problems, think about how to obtain the sharpest image with a pinhole camera a camera with a pinhole for a lens. The pinhole images each point on the object as a small circular disk on the film. If the hole is too large, the disk-image will be geometrical and too large. On the other hand, if the hole is too small, diffraction effects will make the disk-image large in this case also. For what pinhole size will, the image have the sharpest features? Assume the pinhole-to-film qistance is 10 centimeters and visible light has wavelength 5000 Angstroms « Define some clearly-stated approximate measure of the disk-image size, for example (geometric image diameter d) plus (diffraction-disk width W) . Minimize your expression to yield a numerical pinhole diameter for greatest image sharpness. Is the result larger or smaller than you expected? Could you fabricate a pinhole of this size, say with a pin? 14. Slit width in an atomic beam apparatus In an atomic beam apparatus, potassium metal (atomic weight 39) is heated to its boiling point (T = 760° C ^ 1000° Kelvin) and streams out of the oven aperture as individual atoms (at average energy 53 kT ££ 1/10 eV, where k is Boltzmann f s constant = -16 1.38 x 10 erg/degree Kelvin and T is degrees Kelvin) into a vacuum chamber. The experimenter wishes to make the beam narrower and masks it down with a slit made of mounted razorblades. The detector is located 50 centimeters downstream from the slit. Is there any danger than the slit will be so narrow that dif f araction effects make the beam significantly wider at the detector than the geometrical image of the slit? Justify your answer with an approximate numerical calculation. Use the results of exercise 13. t.. Physics 8.04 Exercises Chapter 2 page 5 t » ~ 15 . Hydrogen; a Structure in Equilibrium A simple but sophisticated argument (due to Victor Weisskopf) holds that the hydrogen atom has its observed size because this size minimuzes the total energy of the system. The argument rests on the assumption that the lowest energy state corresponds to physical size comparable to a deBroglie wavelength of the electron. Larger size means larger deBroglie wavelength/ hence smaller momentum and kinetic energy. In contrast/ smaller size means lower potential energy/ since the potential well is deepest near the proton. The observed size is a compromise between kinetic and potential energies that minimizes total energy of the system. Develop this argument explicitly/ for example as follows: (a) Write down the classical expression for the total energy of the hydrogen atom with an electron of momentum p in a circular orbit of radius'r. Keep kinetic and potential energies separate. (b) Failure of classical energy minimization Use the force law to obtain the total energy as a function of radius. What radius results if this expression is set to yield a minimum energy? (c) For the lowest energy state, demand that the orbit circumference be one deBroglie wavelength (recall exercise 12). Eliminate wavelength and substitute the result for momentum into the energy relation of part (a) to .yield an expression that is a function of radius. Note how a larger radius decreases the kinetic energy and increases the potential energy, and vice versa. (d) Take the derivative of the energy vs. radius function and find the radius that minimizes total energy,. Show that the resulting radius is the Bohr radius a and that the resulting energy is that calculated by Bohr for the lowest energy state. Comment; This exact result depends on setting the deBroglie wavelength equal to the circumference of the orbit. In fact the argument we are folltfv/ing specifier only an approximate correspondence between system size and deBroglie wavelength. We could have chosen "system size 11 to mean radius or diameter and then derived a size differing from that calculated above by factors of 2 or IT , which is as near to the observed values as one has any right to expect.