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Chemistry Unit 2, Week 1 Packet Atomic Structure and Theory Tuesday, October 1st – Friday, October 4th MA Framework Standard Check when met 2.1 Recognize discoveries from Dalton (atomic theory), Thomson (the electron), Rutherford (the nucleus), and Bohr (planetary model of atom), and understand how each discovery leads to modern theory. 2.2 Describe Rutherford’s “gold foil” experiment that led to the discovery of the nuclear atom. Identify the major components (protons, neutrons, and electrons) of the nuclear atom and explain how they interact. 2.3 Interpret and apply the laws of conservation of mass, constant composition (definite proportions), and multiple proportions. Weekly Homework Schedule Tuesday 10/1 Early Models of the Atom Worksheet Questions Page 4 Wednesday 10/2 Electrons Worksheet Questions Page 8 Thursday 10/3 Section 1 Review Questions, Study for Quiz Page 11 Friday 10/4 Complete Atomic Theory Graphic Organizer Page 13 Reminder: Atomic Theory Quiz on Friday, October 4th Atomic Theory Introduction: John Dalton’s Contributions What is a model? Why do we use them in science? Where did our model get us to today? Atoms are made of __________________, ____________________, and _____________________. Subatomic Particle Charge Mass Location Proton Neutron Electron How did the model begin? John Dalton’s Atomic Theory of Matter/Solid Sphere Model What he said Law/Example; Still true today? 1. Each element is composed of small particles called ________________. They cannot be broken up into smaller particles. 2. All atoms of an element are identical in mass and other properties; all atoms of different elements are _________________. 3. Atoms cannot be ________________ or Law of Conservation of Mass __________________ in chemical reactions. Before = after. 4. Compounds form when atoms of more Law of Constant Composition than one element combine. Specific compounds always have the ___________ # of atoms and form in whole number ratios. Law of Multiple Proportions Practice MCAS Questions based on Dalton’s Laws Law of Conservation of Mass 1. A balanced equation is shown here: C6H12O6(l) 2C2H5OH(l) + 2CO2(g) Which of the following statements correctly compares the mass of the reactant with the mass of the products in this equation? A. The mass of the reactant is half the mass of the products. B. The mass of the reactant is twice the mass of the products. C. The mass of the reactant is one-fourth the mass of the products. D. The mass of the reactant is the same as the mass of the products. 2. The equation below shows the chemical reaction that occurs in a car battery. How much sulfuric acid (H2SO4) is consumed in the reaction? A. 0.78 kg B. 0.95 kg C. 2.15 kg D. 3.10 kg Law of Constant Composition 3. A 1.00 kg sample of water (H2O) contains 0.11 kg of hydrogen (H) and 0.89 kg of oxygen (O). According to the law of constant composition, how much hydrogen and oxygen would a 1.5 kg sample of water contain? A. 0.11 kg H and 0.89 kg O B. 0.17 kg H and 1.34 kg O C. 0.22 kg H and 1.78 kg O D. 1.34 kg H and 0.17 kg O Law of Multiple Proportions 4. Which of the following statements applies the law of multiple proportions to the relationship between carbon monoxide (CO) and carbon dioxide (CO2)? A. The mass of a mole of CO is exactly half that of a mole of CO2. B. There will always be half as much CO as CO2 in a sample of gas. C. The proportion of oxygen atoms in CO molecules is the same as it is in CO2 molecules. D. The mass of oxygen in CO compared to that in CO2 can be expressed as a whole number ratio. Name CHAPTER 4 Class Date Atoms 1 The Development of Atomic Theory SECTION KEY IDEAS As you read this section, keep these questions in mind: • What scientists helped to develop atomic theory? • What part of atoms did Thomson discover? • What part of atoms did Rutherford discover? Who Proposed the First Atomic Theory? You may know what atoms are: they are the tiny particles that make up all matter. Today, we know a great deal about the structure and behavior of atoms. However, scientists have not always known about atoms. ORIGINS OF ATOMIC THEORY The things we know about atoms today were discovered by many scientists over a long period of time. In fact, the first person to hypothesize that atoms exist was Democritus. Democritus was a Greek philosopher who lived in the fourth century BCE. He suggested that everything in the universe was made of tiny, indivisible units. He called these units atoms. The word atom comes from the Greek word atomos. Atomos means “unable to be cut or divided.” Scientists Who Helped Develop Atomic Theory Scientist Contribution Democritus first proposed that the universe is made up of tiny, indivisible units called atoms Democritus made many observations of how matter changes. He thought that the movements of atoms caused the changes he observed. However, Democritus did not have any evidence to show that his theory was correct. Although some people agreed with Democritus’s theory, others thought that different theories were correct. As the science of chemistry was developing in the 1700s, scientists began to focus on making careful measurements in experiments. Therefore, scientists began to collect more accurate and precise data about matter. Just as scientists do today, scientists in the past used data to decide which theories were most correct. READING TOOLBOX Compare After you read this section, write a paragraph or two comparing Dalton’s, Thomson’s, and Rutherford’s models of the atom. READING CHECK 1. Identify Where does the word atom come from? READING CHECK 2. Explain What do you think is the reason that not everyone agreed with Democritus’s theory? Copyright © by Holt, Rinehart and Winston. All rights reserved. Interactive Reader 67 Atoms Name SECTION 1 Class Date The Development of Atomic Theory continued How Did Dalton Contribute to Atomic Theory? READING CHECK 3. Describe How was Dalton’s theory different from Democritus’s? 8g^i^XVa I]^c`^c\ 4. Apply Concepts Carbon makes up 27% of the mass of carbon dioxide. How many grams of carbon are there in 88 g of carbon dioxide? In 1808, an English schoolteacher named John Dalton proposed a different atomic theory. Like Democritus, Dalton proposed that atoms could not be divided into smaller parts. However, unlike Democritus, Dalton performed scientific experiments to find data to support his theory. Dalton’s experiments showed that atoms of different elements could combine in certain ways to form compounds. This is known as the “law of definite proportions.” The law of definite proportions states that a chemical compound always contains the same proportion of a particular element. For example, in any sample of water, hydrogen will make up 11% of the mass of the sample. In other words, in 100 g of water, there will be 11 g of hydrogen and 89 g of oxygen. 8BUFS$PNQPTJUJPOCZ.BTT )ZESPHFO )ZESPHFOBUPN 0YZHFO 0YZHFOBUPN For any sample of water, 11% of its mass is hydrogen and 89% is oxygen. This suggests that hydrogen and oxygen atoms combine in specific ratios to form water molecules. READING CHECK 5. Explain Why did scientists have to develop new atomic theories that were different from Dalton’s theory? Some parts of Dalton’s atomic theory are still accepted by scientists today. In fact, Dalton’s explanation of how atoms combine to form substances is considered the foundation of modern atomic theory. However, as scientists continued to carry out experiments, they made new observations that did not fit Dalton’s theory. New theories were developed that better explained the new observations. Scientists Who Helped Develop Atomic Theory Scientist Contribution Democritus first proposed that the universe is made up of tiny, indivisible units called atoms John Dalton carried out scientific experiments that showed that atoms exist Copyright © by Holt, Rinehart and Winston. All rights reserved. Interactive Reader 68 Atoms Bonus/Extension Sample Data for Dalton’s Experiments Experiment 1. 30 g of carbon are burned in the open Experiment 2. 30 g of carbon are burned in a closed air where there is plenty of oxygen. 110 g of carbon container under conditions of low oxygen. 70 g of oxide forms. carbon oxide forms. How much oxygen did the carbon combine with in experiment 1? ___________________________ How much oxygen did the carbon combine with in experiment 2? ___________________________ 1. What is the ratio of the masses of carbon to oxygen in both experiments? 2. Is the ratio of masses an integer (whole #) or a number containing decimals (rational #)? 3. How might this data be explained according to Dalton? Name SECTION 1 Class Date The Development of Atomic Theory continued How Did Thomson Contribute to Atomic Theory? In 1897, a British scientist named J. J. Thomson was working with cathode rays, mysterious rays in vacuum tubes. His experiments helped scientists better understand the structure of atoms. In his experiments, Thomson used a vacuum tube that contained two electrodes. One electrode, called the cathode, was negatively charged. The other, called the anode, was positively charged. When electricity was sent through the tube, a glowing beam appeared inside the tube. Other scientists had shown that this beam came from the cathode. However, they had not been able to determine what the beam was made of. When Thomson placed a magnet near the tube, the beam was deflected, or bent, as shown in the figure below. Only streams of charged particles can be bent by a magnet. Light rays cannot. Therefore, Thomson’s experiment suggested that cathode rays were actually streams of tiny, charged particles. READING CHECK 6. Identify Which electrode in Thomson’s vacuum tube was positively charged? The beam is straight when no magnet is present. The cathode has a negative charge. The air was removed from the tube by a vacuum pump. The anode has a positive charge. EHHDBG@<EHL>K 7. Explain Why did the deflection of the beam by a magnet suggest that the cathode ray contained charged particles? The beam is deflected by the magnet. Electric charges behave in this way. So, the deflection suggests that the beam is made of charges. Based on the direction the beam bent, Thomson determined that the particles in the beam were negatively charged. His experiments also showed that, no matter what substance the cathode was made of, the beam was always the same. Based on his results, Thomson concluded that the particles in the beam came from atoms. He also concluded that the particles were the same in atoms of different elements. This is how Thomson discovered electrons, the negatively charged particles inside an atom. Copyright © by Holt, Rinehart and Winston. All rights reserved. Interactive Reader 69 Atoms Thomson Discovers the Electron and Proposes the Plum Pudding Model Scientist JJ Thomson Robert Milikan Experiment/Notes Cathode Ray Tube Experiment Oil Drop Experiment Name _______________________________________________________ Table Texting Question: My Response: Reply 1: Reply 2: Reply 3: EXPECTATIONS: - Only share comments related to the question posed. - Respectfully agree, disagree or ask a follow up question in your reply - Be scholarly in your response. Use background knowledge and/or text clues to support your ideas. Bonus/Extension: Draw and explain the plum pudding model below. Propose an experiment that would support or disprove Thompson’s model of a “pudding” of positive charge. Rutherford Discovers a Positive Nucleus and the Nuclear Atomic Model Video and Reading Notes Name: Date: Rutherford’s Gold Foil Experiment Background Info: In Rutherford’s experiment, he used radioactive alpha particles. He directed these at a thin sheet of gold foil, shown in the diagram to the right. He wanted to see if the particles would go through the foil, or bounce back. Before this experiment, scientists had two different possible ideas of how atoms could be structured: Plum Pudding Model: In this model, the atom has negative particles (electrons) spread out evenly through a positive sphere. If this is how an atom is structured, all of the alpha particles should go straight through since there is nothing solid to stop them. Nuclear Model: In this model, the negative electrons are on the outside, and there is a small dense positive nucleus in the middle. If this is how an atom is structured, alpha particles that enter the atom in the electron areas will go straight through, which particles that hit the nucleus will be bounced back. Results: Rutherford’s experiment found that almost all of the alpha particles went straight through the foil. A few bounced back and were deflected. Question: Which model did Rutherford’s results support? Explain your answer. Claim: Write a sentence that answers the question. Evidence: Most of the particles _________ __________________________ __________________________ Some of the particles ________ __________________________ __________________________ Analysis: Explain what each piece of evidence means about the structure of the atom. Name Class Date Section 1 Review SECTION VOCABULARY electron a subatomic particle that has a negative charge nucleus in physical science, an atom’s central region, which is made up of protons and neutrons 1. Describe What did Rutherford’s gold-foil experiment suggest about the structure of an atom? 2. Define State the law of definite proportions in your own words. 3. Compare How was Dalton’s atomic theory similar to Democritus’s atomic theory? 4. Compare How was Thomson’s atomic theory different from Rutherford’s atomic theory? 5. Describe What did Thomson conclude about the particles in cathode rays? 6. Apply Concepts Nitrogen makes up 82% of the mass of ammonia. How many grams of nitrogen are there in 200 g of ammonia? 7. Calculate The compound ammonia contains nitrogen and hydrogen atoms. How many grams of hydrogen are there in 150 g of ammonia? (Hint: What percentage of the mass of ammonia is hydrogen?) Copyright © by Holt, Rinehart and Winston. All rights reserved. Interactive Reader 72 Atoms Bohr Proposes the Solar System Model What did Bohr find? What did Bohr propose? Models of the Atom Review Scientist #1: Thompson It is possible to remove a negatively charged particle from an atom using electrical forces. Does this evidence better support the solid sphere model, or the plum pudding model? Explain your reasoning: Scientist #2: Rutherford Does this evidence better support the nuclear model or If a tiny particle is shot into the middle of the plum pudding model? Explain your reasoning: an atom, it hits something dense in the center and bounces back in the direction from which it came. If a tiny particle is shot into the edges of the atom, it goes through. Most of the particles shot at an atom will go through. Scientist #3: Bohr The farther from the center of an atom the negatively charged particles are, the easier they are to remove. Does this evidence better support the solar system model or the nuclear? Explain your reasoning: 1. Which scientist first showed that atoms are not just a solid sphere that can’t be divided? 2. What subatomic particle did JJ Thompson identify? 3. Which scientist figured out that atoms have a nucleus? 4. Which scientist showed that electrons are located at different distances from the nucleus? Atomic Theory Graphic Organizer: How Did Models Get Us To Where We Are Today? Scientist Name 1803 1897 1911 1913 Model Name, Key Points of Model Solid Sphere Model Plum Pudding Model Nuclear Model Solar System Model