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NATIONAL INSTITUTE OF TECHNOLOGY, ARUNACHAL PRADESH, YUPIA, Pin-791112 (Established by MHRD, Govt. of India) Website : www.nitap.in, Fax No: (0360) 2284972 E-Mail: [email protected] / [email protected] Exercises Proposed for teaching in (July – December, 2016 Semester) 1. Name of the Teacher Dr. Ananta Kumar Atta & Dr. N. K. Pramanik 2. Department Basic & Applied Science 3. Course Title Engineering Chemistry 4. Course code CHY-101 5. Course Hands out (in reference to framed & approved syllabus) (maximum 500 words) Dr. A. K. Atta Total estimated number of classes required: 21 Days Day-1 Day-10 Day-11 Subject matter to be covered Properties of Organic molecules. Definition and characterization of Electron affinity, Electro negativity, Inductive effect, Hybridization with Examples. Introduction to Resonance and Hyperconjugation with examples. Solutions of problems related Electro negativity and Electron affinity. Introduction to carbocation, carbanion and free radicals with examples. Properties of Carbocation, carbanion and free radicals. Discussion of carbocation/carbanion/free radicals related problems and solutions. Properties and mechanism of substitution reaction: definition, examples, solvent effect, choice of molecules etc. Rearrangement of carbocations in substitution reaction. Reaction of epoxide. Substitution reaction related Problems and solutions. Introduction to addition reactions, Electrophilic addition of HX and mechanism, Comparison between substitution and elimination reaction with examples. Markovnikov’s rule, Energy diagram for electrophilic addition reaction, Elimination reaction: Introduction, Mechanism, energy diagram. Concepts, classifications and industrial applications. Polymerization processes (addition and condensation polymerization), degree of polymerization, Preparation, structure and use of some common polymers: Copolymerization,stereoregularity of polymer, crystallinity and amorphicity of polymer, plastic, rubber, Conducting and semi-conducting polymers Mass spectrometry: General features, Fragmentation, M+2 peaks with examples. Infrared spectroscopy with examples Day-12 NMR, UV-VIS spectroscopy Day-13 Different statements, mathematical form; internal energy: physical significance, mathematical expression (ideal and real gas), Enthalpy: physical significance, Day-2 Day-3 Day-4 Day-5 Day-6 Day-7 Day-8 Day-9 NATIONAL INSTITUTE OF TECHNOLOGY, ARUNACHAL PRADESH, YUPIA, Pin-791112 (Established by MHRD, Govt. of India) Website : www.nitap.in, Fax No: (0360) 2284972 E-Mail: [email protected] / [email protected] mathematical expression Day-14 Day-15 Day-16 Day-17 Day-18 Day-19 Day 20 Day 21 Concept of Thermodynamic System: diathermal wall, adiabatic wall, isolated system, closed system, Open system, extensive property, intensive propertyIntroduction to first law of thermodynamics Cp and Cv: definition and relation, Adiabatic changes; reversible and irreversible processes; application of first law of thermodynamics to chemical processes: exothermic, endothermic processes Law of Lovoisier and Laplace, Hess's law of constant heat summation, Kirchoff's law, Second law thermodynamics; Joule Thomson and throttling processes; inversion temperature; evaluation of entropy: characteristics and expression Entropy change in irreversible process, entropy change for irreversible isothermal expression of an ideal gas, Entropy change of a mixture of gases. Gibbs Helmholtz equation. Condition of spontaneity and equilibrium Work function and free energy: physical significance, mathematical expression for ideal and real gases obeying Vander Waals' equation Solid, liquid and gaseous fuels; compositions of coal, Coal analysis, Proximate and ultimate analysis. Gasoline, octane number, aviation fuel, diesel, cetane number, Natural gas, water gas, Coal gas, bio gas. Bio-diesel Dr. N. K. Pramanik Total estimated number of classes required: 21 Days Day-1 Subject matter to be covered Reaction rate laws: order; molecularity of reaction with examples. Day-2 Day-5 Day-6 Zero, first order kinetics with examples, derivation of rate constant and half life period. Second order chemical kinetics with rate constant and half life period. Relationship between rate constant and half time and derivation of mathematical expression. Discussion on problems in chemical kinetics and their solutions. Derivation of Arrhenius equation, significance and applications. Day-7 Day-8 Transition state theory, significance and applications. Discussion of problems on Arrhenius equation. Day-9 Derivation of Collison theory, modification and applications. Day-10 Day-11 Homogeneous catalysis and heterogeneous catalysis with examples and mechanism. Introduction to electrochemistry, concept of conductance of electrolytic solutions. Day-12 molar conductance, specific conductance, equivalent conductance and ion Day-3 Day-4 NATIONAL INSTITUTE OF TECHNOLOGY, ARUNACHAL PRADESH, YUPIA, Pin-791112 (Established by MHRD, Govt. of India) Website : www.nitap.in, Fax No: (0360) 2284972 E-Mail: [email protected] / [email protected] conductance etc. Day-13 Discussion on problems in electrochemistry. Day-14 Transport numbers of ions, Cationic and anionic transport numbers and their relationship. Problems in electrochemistry regarding conductivity and transport number Day-15 Day-16 Day-18 Day 19 Conductometric titrations alongwith curve: SA vs SB & SA vs WB; Precipitation titration KCl vs AgNO3 etc. Effect of temperature and concentration on conductance, mobility and transport number of ions, Kohlrausch’s law and applications. Discussion on problems on Kohlrausch’s law. Cell EMF, reduction and oxidation potential and thermodynamic significance. Day20 Hydrogen electrode and its significance Day 21 Calomel and Quinhydrone electrodes and their applications. Day-17 6. Books/Literature to be followed: (a) Books (Min. 2 texts + 3 references) (i) Title Organic Chemistry Author I. L. Finar Publisher Pearson Edition Sixth Edition (ii) Title Author Publisher Edition Organic chemistry J. G. Smith Tata McGraw Hill Second Edition (iii) Title Author Publisher Edition Organic Chemistry M. Boyd Pearson Seventh Edition (iv) Title Author Publisher Edition Physical Chemistry P. C. Rakshit Sarat Seventh Edition (v) Title Author Physical Chemistry S. Pahari NATIONAL INSTITUTE OF TECHNOLOGY, ARUNACHAL PRADESH, YUPIA, Pin-791112 (Established by MHRD, Govt. of India) Website : www.nitap.in, Fax No: (0360) 2284972 E-Mail: [email protected] / [email protected] (vi) (vii) Publisher Edition Title Author Publisher Edition Central Fourth Edition Title Author Publisher Edition Physical chemistry C. R. Metz Tata McGraw Hill Second Edition Physical Chemistry P. Atkins Oxford Eighth Edition (viii) Title Author Publisher Edition Inorganic Chemistry J. D. Lee Wiley Fifth Edition (ix) Principle of polymer chemistry P. L. Flory Asian Books Pvt. Ltd. First Edition Title Author Publisher Edition (x) (b) Title Introduction of polymer chemistry Author G. S. Misra Publisher New age Edition First Edition Magazines/Journals (Minimum 5) (i) Journal of Organic Chemistry (ii) Tetrahedron Letter (iii) Journal of Chemical Thermodynamics (iv) The Journal of Physical Chemistry A (v) Chemistry Today 7. Mode of Teaching: J.C Bose/S. N. Bose (please tick): S. N. Bose 8. If the course is of practices, list the experiments to be offered. (i) Determination of the Concentration of a NaOH Solution (ii) Determination of the Concentration of a HCl Solution (iii) Standardization of KMnO4 Solution by Mohr’s Salt. NATIONAL INSTITUTE OF TECHNOLOGY, ARUNACHAL PRADESH, YUPIA, Pin-791112 (Established by MHRD, Govt. of India) Website : www.nitap.in, Fax No: (0360) 2284972 E-Mail: [email protected] / [email protected] (iv) Determination of the Total, Temporary and Permanent Hardness of Water in ppm Equivalent of CaCO3 Hardness. (v) Determination of the pH Value of Solution by Indicator pH Meter and pH Paper. (vi) Determination of Strength of Given HCl Solution Conductometrically (vii) Estimation of the Available Chlorine in Bleaching Powder. (viii) Synthesis of di-acetone glucose from D-glucose Are the manuals ready for the experiments to be conducted? Yes/No (please tick): YES If “No”, the reasons there of and fixing responsibility __________________________________________ Remarks/ Endorsement by the HoD With his /her signature with date Name of the Teacher: Dr. A. K. Atta and Dr. N. K. Pramanik Designation: Assistant Professor Signature with Date: