Download CHY - 101 - NIT Arunachal Pradesh

NATIONAL INSTITUTE OF TECHNOLOGY, ARUNACHAL PRADESH, YUPIA, Pin-791112
(Established by MHRD, Govt. of India)
Website : www.nitap.in, Fax No: (0360) 2284972
E-Mail: [email protected] / [email protected]
Exercises Proposed for teaching in (July – December, 2016 Semester)
1. Name of the Teacher Dr. Ananta Kumar Atta & Dr. N. K. Pramanik
2. Department
Basic & Applied Science
3. Course Title
Engineering Chemistry
4. Course code
CHY-101
5. Course Hands out (in reference to framed & approved syllabus) (maximum 500 words)
Dr. A. K. Atta
Total estimated number of classes required: 21
Days
Day-1
Day-10
Day-11
Subject matter to be covered
Properties of Organic molecules. Definition and characterization of Electron
affinity, Electro negativity, Inductive effect, Hybridization with Examples.
Introduction to Resonance and Hyperconjugation with examples. Solutions of
problems related Electro negativity and Electron affinity.
Introduction to carbocation, carbanion and free radicals with examples. Properties
of Carbocation, carbanion and free radicals. Discussion of
carbocation/carbanion/free radicals related problems and solutions.
Properties and mechanism of substitution reaction: definition, examples, solvent
effect, choice of molecules etc.
Rearrangement of carbocations in substitution reaction. Reaction of epoxide.
Substitution reaction related Problems and solutions.
Introduction to addition reactions, Electrophilic addition of HX and mechanism,
Comparison between substitution and elimination reaction with examples.
Markovnikov’s rule, Energy diagram for electrophilic addition reaction, Elimination
reaction: Introduction, Mechanism, energy diagram.
Concepts, classifications and industrial applications. Polymerization processes
(addition and condensation polymerization), degree of polymerization,
Preparation, structure and use of some common polymers: Copolymerization,stereoregularity of polymer, crystallinity and amorphicity of polymer, plastic, rubber,
Conducting and semi-conducting polymers
Mass spectrometry: General features, Fragmentation, M+2 peaks with examples.
Infrared spectroscopy with examples
Day-12
NMR, UV-VIS spectroscopy
Day-13
Different statements, mathematical form; internal energy: physical significance,
mathematical expression (ideal and real gas), Enthalpy: physical significance,
Day-2
Day-3
Day-4
Day-5
Day-6
Day-7
Day-8
Day-9
NATIONAL INSTITUTE OF TECHNOLOGY, ARUNACHAL PRADESH, YUPIA, Pin-791112
(Established by MHRD, Govt. of India)
Website : www.nitap.in, Fax No: (0360) 2284972
E-Mail: [email protected] / [email protected]
mathematical expression
Day-14
Day-15
Day-16
Day-17
Day-18
Day-19
Day 20
Day 21
Concept of Thermodynamic System: diathermal wall, adiabatic wall, isolated
system, closed system, Open system, extensive property, intensive
propertyIntroduction to first law of thermodynamics
Cp and Cv: definition and relation, Adiabatic changes; reversible and irreversible
processes; application of first law of thermodynamics to chemical processes:
exothermic, endothermic processes
Law of Lovoisier and Laplace, Hess's law of constant heat summation, Kirchoff's
law, Second law thermodynamics; Joule Thomson and throttling processes;
inversion temperature; evaluation of entropy: characteristics and expression
Entropy change in irreversible process, entropy change for irreversible isothermal
expression of an ideal gas, Entropy change of a mixture of gases.
Gibbs Helmholtz equation.
Condition of spontaneity and equilibrium
Work function and free energy: physical significance, mathematical expression for
ideal and real gases obeying Vander Waals' equation
Solid, liquid and gaseous fuels; compositions of coal, Coal analysis, Proximate and
ultimate analysis.
Gasoline, octane number, aviation fuel, diesel, cetane number, Natural gas, water
gas, Coal gas, bio gas. Bio-diesel
Dr. N. K. Pramanik
Total estimated number of classes required: 21
Days
Day-1
Subject matter to be covered
Reaction rate laws: order; molecularity of reaction with examples.
Day-2
Day-5
Day-6
Zero, first order kinetics with examples, derivation of rate constant and half life
period.
Second order chemical kinetics with rate constant and half life period.
Relationship between rate constant and half time and derivation of mathematical
expression.
Discussion on problems in chemical kinetics and their solutions.
Derivation of Arrhenius equation, significance and applications.
Day-7
Day-8
Transition state theory, significance and applications.
Discussion of problems on Arrhenius equation.
Day-9
Derivation of Collison theory, modification and applications.
Day-10
Day-11
Homogeneous catalysis and heterogeneous catalysis with examples and
mechanism.
Introduction to electrochemistry, concept of conductance of electrolytic solutions.
Day-12
molar conductance, specific conductance, equivalent conductance and ion
Day-3
Day-4
NATIONAL INSTITUTE OF TECHNOLOGY, ARUNACHAL PRADESH, YUPIA, Pin-791112
(Established by MHRD, Govt. of India)
Website : www.nitap.in, Fax No: (0360) 2284972
E-Mail: [email protected] / [email protected]
conductance etc.
Day-13
Discussion on problems in electrochemistry.
Day-14
Transport numbers of ions, Cationic and anionic transport numbers and their
relationship.
Problems in electrochemistry regarding conductivity and transport number
Day-15
Day-16
Day-18
Day 19
Conductometric titrations alongwith curve: SA vs SB & SA vs WB; Precipitation
titration KCl vs AgNO3 etc.
Effect of temperature and concentration on conductance, mobility and transport
number of ions, Kohlrausch’s law and applications.
Discussion on problems on Kohlrausch’s law.
Cell EMF, reduction and oxidation potential and thermodynamic significance.
Day20
Hydrogen electrode and its significance
Day 21
Calomel and Quinhydrone electrodes and their applications.
Day-17
6. Books/Literature to be followed:
(a) Books (Min. 2 texts + 3 references)
(i)
Title
Organic Chemistry
Author
I. L. Finar
Publisher
Pearson
Edition
Sixth Edition
(ii)
Title
Author
Publisher
Edition
Organic chemistry
J. G. Smith
Tata McGraw Hill
Second Edition
(iii)
Title
Author
Publisher
Edition
Organic Chemistry
M. Boyd
Pearson
Seventh Edition
(iv)
Title
Author
Publisher
Edition
Physical Chemistry
P. C. Rakshit
Sarat
Seventh Edition
(v)
Title
Author
Physical Chemistry
S. Pahari
NATIONAL INSTITUTE OF TECHNOLOGY, ARUNACHAL PRADESH, YUPIA, Pin-791112
(Established by MHRD, Govt. of India)
Website : www.nitap.in, Fax No: (0360) 2284972
E-Mail: [email protected] / [email protected]
(vi)
(vii)
Publisher
Edition
Title
Author
Publisher
Edition
Central
Fourth Edition
Title
Author
Publisher
Edition
Physical chemistry
C. R. Metz
Tata McGraw Hill
Second Edition
Physical Chemistry
P. Atkins
Oxford
Eighth Edition
(viii) Title
Author
Publisher
Edition
Inorganic Chemistry
J. D. Lee
Wiley
Fifth Edition
(ix)
Principle of polymer chemistry
P. L. Flory
Asian Books Pvt. Ltd.
First Edition
Title
Author
Publisher
Edition
(x)
(b)
Title
Introduction of polymer chemistry
Author
G. S. Misra
Publisher
New age
Edition
First Edition
Magazines/Journals (Minimum 5)
(i) Journal of Organic Chemistry
(ii) Tetrahedron Letter
(iii) Journal of Chemical Thermodynamics
(iv) The Journal of Physical Chemistry A
(v) Chemistry Today
7. Mode of Teaching: J.C Bose/S. N. Bose (please tick): S. N. Bose
8. If the course is of practices, list the experiments to be offered.
(i) Determination of the Concentration of a NaOH Solution
(ii) Determination of the Concentration of a HCl Solution
(iii) Standardization of KMnO4 Solution by Mohr’s Salt.
NATIONAL INSTITUTE OF TECHNOLOGY, ARUNACHAL PRADESH, YUPIA, Pin-791112
(Established by MHRD, Govt. of India)
Website : www.nitap.in, Fax No: (0360) 2284972
E-Mail: [email protected] / [email protected]
(iv) Determination of the Total, Temporary and Permanent Hardness of Water in ppm
Equivalent of CaCO3 Hardness.
(v) Determination of the pH Value of Solution by Indicator pH Meter and pH Paper.
(vi) Determination of Strength of Given HCl Solution Conductometrically
(vii) Estimation of the Available Chlorine in Bleaching Powder.
(viii) Synthesis of di-acetone glucose from D-glucose
Are the manuals ready for the experiments to be conducted?
Yes/No (please tick): YES
If “No”, the reasons there of and fixing responsibility
__________________________________________
Remarks/ Endorsement by the HoD
With his /her signature with date
Name of the Teacher: Dr. A. K. Atta and
Dr. N. K. Pramanik
Designation: Assistant Professor
Signature with Date: