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1. COURSE DECRIPTION – GENERAL INFORMATION 1.1. Course teacher Davor Kovačević 1.2. Name of the course Electrochemistry 1.3. Associate teachers 1.4. Study programme (undergraduate, graduate, integrated) Graduate (Mag Chem) elective 1.5. Status of the course 2. COURSE DESCRIPTION 2.1. Course objectives 2.2. Enrolment requirements and required entry competences for the course 2.3. Learning outcomes at the level of the study programme to which the course contributes 1.6. Year and semester of study 1.7. Credit value (ECTS) 1.8. Type of instruction (number of hours L+S+E+e-learning) 1.9. Expected enrolment in the course 1.10. Level of use of e-learning (1, 2, 3 level), percentage of instruction in the course on line (20% maximum) First or second, winter 5 2+0+1 15 1 Application of physical chemistry on macromolecules. Physical chemistry 1 and Physical chemistry 2 Knowing how to apply previously learned physico-chemical rules on macromolecules Students should understand, know how to interprete and apply the following topics in colloid and interface chemistry: Electrolyte solutions: strong electrolyte structural models (Debye&Hückel, Bjerrum, Fuoss); weak electrolytes, polyelectrolytes. 2.4. Expected learning outcomes at the level of the course (4-10 learning outcomes) Galvanic cell: electrical interfacial layer, electromotivity (electromotive force) – definition and measurements; ion-selective electrodes; potentiometry and potentiometric titration. Voltammetric methods: polarography, stationary voltammetry, linear sweep voltammetry, cyclic voltammetry, square vawe voltammetry, stripping voltammetry, electrochemical impedance spectroscopy. Kinetics of electrode reactions: polarization, overpotential; Butler-Volmer model, Tafel plot; electrodes: dropping mercury electrode, rotating electrodes. Applications: electrochemical analysis, fuel cells, corrosion, bioelectrochemistry. Introductory lecture 2.5. Course content broken down in detail by weekly class schedule (syllabus) Electrolyte solutions: strong electrolyte structural models (Debye&Hückel) Electrolyte solutions: strong electrolyte structural models (Bjerrum). Galvanic cell – definitions and measurements. Ion-selective electrodes; potentiometry and potentiometric titration 1 Voltammetric methods: polarography. Voltammetric methods: stationary voltammetry, linear sweep voltammetry, cyclic voltammetry. Voltammetric methods: square wave voltammetry, stripping voltammetry, electrochemical impedance spectroscopy. Kinetics of electrode reactions: polarization, overpotential; Butler-Volmer model, Tafel plot. Electrodes: dropping mercury electrode, stationary electrodes, rotating electrodes. Applications: electrochemical analysis, fuel cells, corrosion, bioelectrochemistry. 2.6. Type of instruction 2.8. Student responsibilities 2.9. Screening of student’s work (specify the proportion of ECTS credits for each activity so that the total number of CTS credits is equal to the credit value of the course)): 2.1. Grading and evaluation of student work over the course of instruction and at a final exam x lectures 2.7. Comments: independent study x seminars and workshops multimedia and the internet x exercises laboratory online in entirety work with the mentor mixed e-learning (other) field work Attending lectures and seminars, writing seminar works, being present for a colloquium Class attendance 1 Research Practical training Report Experimental work (Other--describe) Essay Seminar essay Tests Oral exam 3 (Other—describe) Written exam 1 Project (Other—describe) Passing two colloquia during one semester or written examination and oral examination Number of copies at the library Title A. J. Bard, L. R. Faulkner: Electrochemical Methods, Wiley, New York, 2001. 2.2. Required literature (available at the library and via other media) 2. J. Wang: Analytical Electrochemistry, Wiley, New York, 2000. 3. P. W. Atkins, J. de Paula: Atkins' Physical Chemistry, 7th. ed., Oxford Univ. Press, Oxford, 2002. 4. I. Piljac: Elektroanalitičke metode, RMC, Zagreb, 1995. 2 Availability via other media 5. Vl. Simeon: Equilibria in Electrolyte Solutions, in: N. Kallay (ed.), Interfacial Dynamics, M. Dekker, New York, 2000. 2.12. Optional literature (at the time of the submission of the study programme proposal) 2.13. Methods of monitoring quality that ensure acquisition of exit competences Written examination and oral examination 3