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2014-2015 HONORS Chemistry Midterm Review This review sheet is a list of topics and sample practice problems only. The practice problems are good representation of what to expect on the midterm, but it is not enough to just study from the review. You need to look over your notes, old review sheets, tests and quizzes, homework, etc. Ask questions!!!! You may check your answers online and I am available Tuesday, Wednesday, and Thursdays for extra help. Chapter 1 & 2: Intro to Chemistry Key Topics: What is chemistry Uncertainty in Measurement –sig figs Physical and chemical properties Physical and chemical changes 1. Determine the number of significant figures in the following values: a. 6.70 _______ c. 15,300 _______ b. 0.03260 _______ d. 4.68 _______ 2. Perform the following calculations and express your answer with the correct number of significant figures: a. 34.0 x 45.62 = _______ b. 45 – 95.24 = _______ Chapter 3: Atomic Structure Key Topics: Models of the atom (Modern atomic theory) Isotopic Notation, Subatomic particles Atomic Orbitals – s, p, d shapes Electron configurations Valence electrons Periodic Law 3. Describe the basic structure of the atom in the modern atomic theory (be able to label protons, neutrons, electrons, and the nucleus) (Ch. 3): 4. 14 6 C protons = _______ neutrons = _______ electrons = _______ 5. Sketch s and p orbitals (Ch 3): 6. Write the electron configuration for Bromine. 7. What element has the following electron configuration: 1s22s22p63s33p64s23d5 Chapter 4: The Periodic Table Key Topics: Organization of the Periodic Table (Periodic Law) Periodic Trends: Electronegativity Recognize properties of main groups 8. State the periodic law (Ch 4): 9. Label the following areas on your periodic table (some may overlap) (Ch 4): o Metals o Nonmetals o Metalloids o Transition metals o Alkali family o Alkaline earth family o Halogen family o Noble gases Chapter 5: Ionic Compounds Key Topics: Octet Rule Naming and writing formulas Properties of ionic versus covalent compounds 10. Compare and contrast ionic and covalent bonds (Ch 5 and 6, essay): Ionic Both Covalent 11. Name the following ionic formulas (Ch 5): a. NH4Cl __________________ __________________ b. CuO __________________ __________________ c. NaF __________________ __________________ d. Mg(NO3)2 __________________ __________________ 12. Write formulas for the following ionic compounds (Ch 5): a. Magnesium Hydroxide _____________ b. Copper(II) Chloride _____________ c. Calcium Hydroxide _____________ d. Sodium Phosphate _____________ Chapter 6: Covalent Compounds Topics: Naming and writing formulas Properties Lewis Dot structures Polar vs. Non-polar covalent bonds VSEPR Be able to… Sketch lewis structures and predict molecular geometries (VSEPR) 11. Name the following covalent compounds (Ch 6): a. CO2 __________________ __________________ b. SiF4 __________________ __________________ c. SnO4 __________________ __________________ d. CCl4 __________________ __________________ 12. Write formulas for the following covalent compounds (Ch 6): a. dinitrogen pentoxide _____________ b. phosphorus trichloride _____________ c. carbon monoxide _____________ d. selenium hexachloride _____________ 13. Write the dipole moment and bond character of each (Ch 6): a. C-H __________________ __________________ b. C-S __________________ __________________ c. Na-Cl __________________ __________________ d. Si-O __________________ __________________ e. Cl-N __________________ __________________ 14. Draw Lewis Structures (Ch 6): CH3Cl 15. OF2 SO3 Identify the shape and bond angle of molecular compounds (Ch 6): Lewis Structure Shape Bond angles NH3 SO2 CCl4 Chapter 7: Organic Chemistry Topics: Organic bonding Hydrocarbons Alkanes, alkenes, alkynes Naming and drawing formulas Functional groups Practical applications 16. Define hydrocarbon: 17. Compare/Contrast Alkanes, Alkenes, Alkynes: Type of Bonds Alkane Alkene Alkyne Name 18. List and describe 3 uses of organic compounds (Ch 7, organic presentations) 19. Drawing and naming organic structures and naming (Ch 7): Recognize how to draw/name structures for alkanes, alkenes, and alcohols. 3-octene Pentane Chapter 8: The Mole Topics: Mole Avogadro’s number Percent composition Empirical formulas Molecular formulas Be able to… Calculate molar mass Convert between grams and moles Convert between number of particles and moles Perform multi-step conversions Calculate percent composition Determine empirical formula Determine molecular formula 20. Determine the molar mass of the following compounds (Ch 8): Al2(SO4)3 KBr Li2O 21. Find the percent composition of each element (Ch 8): %Mg in MgSO4? %H in C2H5O? 22. Mole conversions (Ch 8): # of moles in 2.5g of Aluminum Oxide? # of moles in 15g of Neon? # of atoms in 0.5mol of Gold? # of atoms in 1.5 grams of Zinc (II) Chloride? Chapter 9: Chemical Reactions and Equations Key Topics: Chemical reaction Reactant Product Chemical equation Coefficient Reaction Types Be able to… Write and balance equations Identify types of reactions 23. Balance the equations and classify the reaction type (Ch 9): ___ Fe + ___ O2 ___ Fe2O3 ________________ ___ Fe + ___ H2O ___ Fe3O4 + ___ H2 ________________ ___ Mg + ___ N2 ___ Mg3N2 ________________