Download Components: P2O5 : Phosphorus oxide, powder and pieces Li2O

MSDS Name: KJL130
Manufacturer Name: Kurt J. Lesker Company
Components:
P2O5 :
Li2O :
KJLC Code:
Phosphorus oxide, powder and pieces
Lithium oxide, powder and pieces
EJTLIPO302A2
Kurt J. Lesker Company
Phosphorus oxide, powder and pieces
Manufacturer MSDS Number: P2O5
SECTION 1 : Chemical Product and Company Identification
MSDS Name: Phosphorus oxide, powder and pieces
Manufacturer Name:Kurt J. Lesker Company
Address:
P.O. Box 10
1925 Route 51
Clairton, PA 15025
For emergencies in the US, call CHEMTREC: 800−424−9300
Other Phone: US National Poison Hotline: (800)222−1222
Manufacturer MSDS Creation Date:
06/30/2006
Manufacturer MSDS Revision Date:
06/25/2008
Synonyms:
Phosphorus oxide, phosphoric anhydride, phosphorus pentoxide, phosphoric acid, anhydride, diphosphorus
pentoxide, phosphorus (V) oxide .
Chemical Family: Non−metal oxide
Chemical Formula: P2O5
Molecular Weight: 141.94
DOT HAZARD LABEL
No data.
Product Codes:
P2O5
Chemical Name
SECTION 2 : Hazardous Ingredients/Identity Information
CAS#
% Weight
Phosphorus pentoxide
1314−56−3
0.0 −100.0 %
1
RTECS:
TH3945000
SECTION 3 : Physical And Chemical Characteristics
Physical State/Appearance:
White, fluffy powder and pieces; pungent, sharp, irritating odor. .
Physical State:
[ ] Gas , [ ] Liquid , [ X ] Solid
pH:
No data.
Vapor Pressure:
236 (VS. AIR OR MM HG)
Vapor Density:
NA (VS. AIR = 1)
Boiling Point:
300.00 deg C (572.0 deg F)
Melting Point:
580.00 deg C (1076.0 deg F)
Solubility:
OTHER SOLUBILITY NOTES: to H3PO4
Solubility In Water:
decomposes
Specific Gravity:
2.39 (WATER = 1)
Density:
No data.
Evaporation Point:
NA (VS BUTYL ACETATE=1)
Percent Volatile:
N.A.
FlashPoint:
N.A.
Upper Flammable Explosive Limit:
NA
Lower Flammable Explosive Limit:
NA
SECTION 4 : Fire And Explosion Hazards
Flash Point:
N.A.
Flash Point Method:
NON−FLAMMABLE
Upper Flammable or Explosive Limit: NA
Lower Flammable or Explosive Limit: NA
Extinguishing Media:
Not applicable. Use suitable extinguishing media for surrounding materials and type of fire. .
Fire Fighting Instructions:
Firefighters must wear full face, self−contained breathing apparatus with full protective clothing to prevent contact
with skin and eyes. Fumes from fire are hazardous. Isolate runoff to prevent environmental pollution. .
2
Unusual Fire Hazards:
When heated to decomposition, phosphorus oxide may emit toxic fumes of POx. Absorbs moisture from the air
forming meta, pyro or ortho−phosphoric acid depending on the amount of water absorbed. May react violently with
water to evolve heat and phosphoric acid. May have a hazardous reaction with formic acid, hydrogen fluoride,
inorganic bases, iodides, metals, methyl hydroperoxide, oxidants, 3−propynol and water. .
SECTION 5 : Health Hazards
Phosphorus pentoxide:
Route of Exposure:
Inhalation? Yes , Skin? Yes , Eyes? Yes , Ingestion? Yes , Other: N
Potential Health Effects:
Eye Contact:
SEVERE IRRITANT AND CORROSIVE.
Skin Contact:
SEVERE IRRITANT AND CORROSIVE.
Inhalation:
SEVERE IRRITANT AND CORROSIVE. May cause a sore throat, coughing, shortness of breath, pulmonary edema,
tightness in chest, dizziness and cyanosis.
Ingestion:
May cause severe burns to the mouth, throat, esophagus, stomach and suffocation from swelling of the tongue.
Chronic Eye Contact:a
No chronic health effects recorded.
Chronic Skin Contact:
No chronic health effects recorded.
Chronic Inhalation:
No chronic health effects recorded.
Chronic Ingestion:
No chronic health effects recorded.
Carcinogenicity:
NTP? No , IARC Monographs? No , OSHA Regulated? No
Target Organs:
May affect the skin, eyes and respiratory system. .
Signs/Symptoms:
INHALATION: May cause dizziness, coughing, tightness in chest, difficulty breathing and cyanosis. INGESTION: May
cause severe abdominal and chest pain, vomiting, diarrhea, drop in blood pressure, fever, rigid abdomen and
chemical pneumonitis. SKIN: May cause redness, inflammation, itching and chemical burns. EYE: May cause
redness, inflammation, itching, watering and chemical burns. .
Other Potential Health Effects:
CARCINOGENICITY/OTHER INFORMATION: No data available. PHOSPHORUS OXIDE OTHER TOXICITY DATA:
orl−rat LD50: >1000 mg/kg ihl−rat LC50: 1217 mg/m3/1H ihl−mus LC50: 271 mg/m3/1H ihl−rbt LC50: 1689
mg/m3/1H ihl−gpg LC50: 61 mg/m3/1H .
Aggravation of Pre−Existing Conditions:
Pre−existing respiratory or skin disorders. .
See "Section II" LD 50/LC 50: See "Other Toxicity Data"
SECTION 6 : Emergency And First Aid Procedures
Physical Health Hazard:
HEALTH HAZARDS (ACUTE AND CHRONIC): Phosphorus compounds have variable toxicity. The phosphorus
halides decompose violently with water to from the halide acid and are thus severe irritants. (Sax, Dangerous
Properties of Industrial Properties, eighth edition)
Eye Contact:
Flush eyes with lukewarm water, lifting upper and lower eyelids, for at least 15 minutes. Seek medical attention
immediately.
Skin Contact:
3
Remove contaminated clothing; brush material off skin; wash affected area with mild soap and water; seek medical
attention immediately.
Inhalation:
Remove victim to fresh air; keep warm and quiet; give oxygen if breathing is difficult and seek medical attention
immediately.
Ingestion:
Do not induce vomiting; seek medical attention immediately.
Note to Physicians:
No data available.
SECTION 7 : Reactivity Data
Chemical Stability:
Unstable [ ] Stable [ X ]
Conditions to Avoid:
CONDITIONS TO AVOID − INSTABILITY: None .; CONDITIONS TO AVOID − HAZARDOUS POLYMERIZATION:
None .
Incompatibilities with Other Materials:
Water, moisture, formic acid, hydrogen fluoride, inorganic bases, iodides, metals, methyl hydroperoxide, oxidants and
3−propynol.
Hazardous Polymerization:
Will occur [ ] Will not occur [ X ]
Hazardous Decomposition Products:
Phosphoric acid and oxides of phosphorus. .
SECTION 8 : Precautions For Safe Handling
Spill Cleanup Measures:
Wear appropriate respiratory and protective equipment specified in section VIII−control measures. Isolate spill area
and provide ventilation. Vacuum up spill using a high efficiency particulate absolute (HEPA) air filter and place in a
closed container for proper disposal. Take care not to raise dust. .
Other Precautions:
Phosphorus oxide is deliquescent. Handle and store in an inert gas such as argon. .
HAZARD LABEL INFORMATION:
Store in cool, dry area Store in tightly sealed container Wash thoroughly after handling
Handling:
No data available.
Storage:
No data available.
Hygiene Practices:
WORK/HYGIENIC/MAINTENANCE PRACTICES: Implement engineering and work practice controls to reduce and
maintain concentration of exposure at low levels. Use good housekeeping and sanitation practices. Do not use
tobacco or food in work area. Wash thoroughly before eating and smoking. Do not blow dust off clothing or skin with
compressed air. .
Waste Disposal:
Dispose of in accordance with local, state and federal regulations. .
SECTION 9 : Control Measures
Ventilation System:
LOCAL EXHAUST: To maintain concentration at low exposure levels SPECIAL: Handle in a controlled atmosphere
MECHANICAL (GENERAL): Not recommended OTHER: Handle and store in an inert gas such as argon
Hand Protection Description:
Rubber gloves
Eye/Face Protection:
Safety goggles
4
Protective Clothing/Body Protection:
Protective gear suitable to prevent contamination
Respiratory Protection:
NIOSH − approved dust−mist−vapor respirator
NIOSH approved respirator Impervious gloves Safety goggles Clothes to prevent skin contact
Ingredient Guidelines
Ingredient: Phosphorus pentoxide
Guideline Information:
ACGIH TLV: NE; OSHA PEL: NE; OTHER LIMITS: NE
SECTION 10 : Other Information
Phosphorus pentoxide:
Section 302:
No
Section 304:
No
Section 313 Toxic Release Form:
No
MSDS Revision Date:
06/25/2008
Disclaimer:
Kurt J. Lesker Company (“KJLC”) believes the information contained in this Material Safety Data Sheet is accurate as
of the “Date of Last Revision” specified. The information relates only to typical properties of the product. Do not use
the information for product performance or specification purposes. The information is for use by technically skilled
persons at their own risk. KJLC MAKES NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND, INCLUDING
WITHOUT LIMITATION WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE, WITH RESPECT TO THE
PRODUCT OR THE INFORMATION. The information may not be valid for product use in combination with any other
product or material or in any process. KJLC expressly disclaims any liability arising from any use of the product or any
reliance on the information. Do not treat the information (a) as assurance that use of the product will not infringe
patent or other rights or (b) as a license or grant of patent or other property rights. “KJLC” means KJLC and each of
its subsidiaries.
Abbreviations used
NA=Not Applicable NE: Not Established
ADDENDUM : Other Client Information
, EJTCAP2182A4, EJTLIPO403A+, EJTLIPO302A4, EJTLIPO403A2,
EJTLIPO302A2, EJTZNOPSPL02, EJTZNOPSPL01
Notes:
Copyright© 1996−2009 Actio Corporation. All Rights Reserved.
KJLC Code:
EJTLIPO302A2
Kurt J. Lesker Company
Lithium oxide, powder and pieces
Manufacturer MSDS Number: Li2O
SECTION 1 : Chemical Product and Company Identification
MSDS Name: Lithium oxide, powder and pieces
Notes:
5
Manufacturer Name:Kurt J. Lesker Company
Address:
P.O. Box 10
1925 Route 51
Clairton, PA 15025
For emergencies in the US, call CHEMTREC: 800−424−9300
Other Phone: US National Poison Hotline: (800)222−1222
Manufacturer MSDS Creation Date:
07/6/2006
Manufacturer MSDS Revision Date:
06/25/2008
Synonyms:
Lithium oxide, lithia, lithium monoxide, dilithium monoxide
Chemical Family: Metal oxide
Chemical Formula: Li2O
Molecular Weight: 45.88
DOT HAZARD LABEL
No data.
Product Codes:
Li2O
Chemical Name
SECTION 2 : Hazardous Ingredients/Identity Information
CAS#
% Weight
Lithium oxide
12057−24−8
0.0 −100.0 %
SECTION 3 : Physical And Chemical Characteristics
Physical State/Appearance:
White powder and pieces, no odor
Physical State:
[ ] Gas , [ ] Liquid , [ X ] Solid
pH:
No data.
Vapor Pressure:
No data. (VS. AIR OR MM HG)
Vapor Density:
No data. (VS. AIR = 1)
Boiling Point:
1200.00 deg C (2192.0 deg F)
Melting Point:
1700.00 deg C (3092.0 deg F)
Solubility In Water:
6.67 at 0.0 C (32.0 F)
Specific Gravity:
2.013 at 25.2 C (77.4 F) (WATER = 1)
Density:
No data.
Evaporation Point:
No data. (VS BUTYL ACETATE=1)
Notes:
6
Percent Volatile:
N.A.
FlashPoint:
N.A.
Upper Flammable Explosive Limit:
NA
Lower Flammable Explosive Limit:
NA
SECTION 4 : Fire And Explosion Hazards
Flash Point:
N.A.
Flash Point Method:
No data.
Upper Flammable or Explosive Limit: NA
Lower Flammable or Explosive Limit: NA
Extinguishing Media:
Not applicable. Use suitable extinguishing media for surrounding material and type of fire.
Fire Fighting Instructions:
Firefighters must wear full face, self−contained breathing apparatus with full protective clothing to prevent contact
with skin and eyes. Fumes from fire are hazardous. Isolate runoff to prevent environmental pollution.
Unusual Fire Hazards:
If involved in a fire, lithium oxide may emit toxic fumes. Strong Alkali. Lithium oxide readily absorbs carbon dioxide
and water from the atmosphere. At elevated temperatures it attacks glass, silica and many metals.
SECTION 5 : Health Hazards
Lithium oxide:
Route of Exposure:
Inhalation? Yes , Skin? Yes , Eyes? Yes , Ingestion? Yes , Other: N
Potential Health Effects:
Eye Contact:
SEVERE IRRITANT AND CORROSIVE.
Skin Contact:
SEVERE IRRITANT AND CORROSIVE.
Inhalation:
SEVERE IRRITANT AND CORROSIVE. Causes irritation to the respiratory tract and mucous membranes.
Ingestion:
SEVERE IRRITANT AND CORROSIVE. May cause central nervous system effects, circulatory failure and
cardiovascular collapse.
Chronic Eye Contact:a
May cause blurred vision.
Chronic Skin Contact:
May be an irritant and corrosive.
Chronic Inhalation:
May cause pulmonary edema and lung damage.
Chronic Ingestion:
May cause gastrointestinal irritation, renal disfunction, derangement of neuromuscular activity, diabetes and kidney
damage.
Carcinogenicity:
NTP? No , IARC Monographs? No , OSHA Regulated? No
Notes:
7
Target Organs:
May effect respiratory system, skin and eyes. .
Signs/Symptoms:
INHALATION: May cause a red, dry, burning throat, inflammation and pain throughout the respiratory tract.
INGESTION: May cause burns to the esophagus, nausea, muscular twitches and mental confusion. SKIN: May
cause redness, itching, chemical burns and blistering. EYE: May cause redness, itching, watering, inflammation and
chemical burns.
Other Potential Health Effects:
CARCINOGENICITY/OTHER INFORMATION: No data available.
Aggravation of Pre−Existing Conditions:
Pre−existing respiratory and skin disorders.
See "Section II" LD 50/LC 50: unr−mam LD50: 15 mg/kg
SECTION 6 : Emergency And First Aid Procedures
Physical Health Hazard:
HEALTH HAZARDS (ACUTE AND CHRONIC): To the best of our knowledge the chemical, physical and toxicological
properties of lithium oxide have not been thoroughly investigated and recorded. The toxicity of lithium compounds is a
function of their solubility in water. Lithium ion has central nervous system toxicity. The initial effects of lithium
exposure are tremors of the hands, nausea, micturition, slurred speech, sluggishness, sleepiness, vertigo, thirst, and
increased urine volume. Effects from continued exposure are apathy, anorexia, fatigue, lethargy, muscular weakness,
and changes in ECG. Long−term exposure leads to hypothyroidism, leukocytosis, edema, weight gain,
polydipsia/polyurea (increased water intake leading to increased urinary output), memory impairment, seizures,
kidney damage, shock, hypotension, cardiac arrhythmias, coma, death. (Sax, Dangerous Properties of Industrial
Materials, eighth edition)
Eye Contact:
Flush eyes with lukewarm water, lifting upper and lower eyelids, for at least 15 minutes. Seek medical attention
immediately.
Skin Contact:
Remove contaminated clothing from affected area; brush material off skin; wash affected area with mild soap and
water; seek medical attention immediately.
Inhalation:
Remove victim to fresh air; keep warm and quiet; give oxygen if breathing is difficult and seek medical attention
immediately.
Ingestion:
Do not induce vomiting; seek medical attention immediately.
Note to Physicians:
No data available.
SECTION 7 : Reactivity Data
Chemical Stability:
Unstable [ ] Stable [ X ]
Conditions to Avoid:
CONDITIONS TO AVOID − INSTABILITY: None; CONDITIONS TO AVOID − HAZARDOUS POLYMERIZATION:
None
Incompatibilities with Other Materials:
Water, steam
Hazardous Polymerization:
Will occur [ ] Will not occur [ X ]
Hazardous Decomposition Products:
Lithium hydroxide, oxides of lithium, lithium and hydrogen gas.
SECTION 8 : Precautions For Safe Handling
Spill Cleanup Measures:
Wear appropriate respiratory and protective equipment specified in section VIII−control measures. Isolate spill area
and provide ventilation. Vacuum up spill using a high efficiency particulate absolute (HEPA) air filter and place in a
closed container for proper disposal. Take care not to raise dust.
Other Precautions:
None
Notes:
8
HAZARD LABEL INFORMATION:
Store in cool, dry area Store in tightly sealed container Wash thoroughly after handling
Handling:
Lithium oxide readily absorbs carbon dioxide and water from the atmosphere. Handle and store in a controlled
environment and in an inert gas, such as argon.
Storage:
See above
Hygiene Practices:
WORK/HYGIENIC/MAINTENANCE PRACTICES: Implement engineering and work practice controls to reduce and
maintain concentration of exposure at low levels. Use good housekeeping and sanitation practices. Do not use
tobacco or food in work area. Wash thoroughly before eating and smoking. Do not blow dust off clothing or skin with
compressed air. .
Waste Disposal:
Dispose of in accordance with local, state and federal regulations.
SECTION 9 : Control Measures
Ventilation System:
LOCAL EXHAUST: To maintain concentration at low exposure levels SPECIAL: Handle in a controlled atmosphere
MECHANICAL (GENERAL): Not recommended OTHER: Handle in an inert gas such as argon
Hand Protection Description:
Rubber gloves
Eye/Face Protection:
Safety goggles
Protective Clothing/Body Protection:
Protective gear suitable to prevent contamination
Respiratory Protection:
NIOSH − approved respirator
NIOSH approved respirator Impervious gloves Vented Goggles Clothes to prevent skin contact
Ingredient Guidelines
Ingredient: Lithium oxide
Guideline Information:
ACGIH TLV: NE; OSHA PEL: NE; OTHER LIMITS: NE
SECTION 10 : Other Information
Lithium oxide:
Section 302:
No
Section 304:
No
Section 313 Toxic Release Form:
No
MSDS Revision Date:
06/25/2008
Disclaimer:
Kurt J. Lesker Company (“KJLC”) believes the information contained in this Material Safety Data Sheet is accurate as
of the “Date of Last Revision” specified. The information relates only to typical properties of the product. Do not use
the information for product performance or specification purposes. The information is for use by technically skilled
persons at their own risk. KJLC MAKES NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND, INCLUDING
WITHOUT LIMITATION WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE, WITH RESPECT TO THE
PRODUCT OR THE INFORMATION. The information may not be valid for product use in combination with any other
product or material or in any process. KJLC expressly disclaims any liability arising from any use of the product or any
reliance on the information. Do not treat the information (a) as assurance that use of the product will not infringe
Notes:
9
patent or other rights or (b) as a license or grant of patent or other property rights. “KJLC” means KJLC and each of
its subsidiaries.
Abbreviations used
NA=Not Applicable NE: Not Established
ADDENDUM : Other Client Information
Notes:
, EJTLIPO403A+, EJTLIPO302A4, EJTLIPO403A2, EJTLIPO302A2
Copyright© 1996−2009 Actio Corporation. All Rights Reserved.
Notes:
10