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Met Pet Part 2 Metamorphism • Changes in a igneous or sedimentary rock that are caused by P, T, fluids or deformation • How do geologists systematically study metamorphic rocks? •The Zone and Facies concepts • Why doe these concepts work? •Because metamorphic rocks are created by reactions that occur under equilibrium conditions, and we can predict what minerals should occur under specific P-T conditions, and vise versa Metamorphic Textures • See handout The Zone Concept • Barrow (ca. 1900) noted significant and systematic mineralogical changes in pelitic rocks • Metamorphic Zones: can subdivide an area into a series of zones that represent changing (normally increasing) metamorphic conditions from one zone to another zone • Each zone are subdivide from one another based on the appearance of a new mineral as metamorphic grade increase, termed the index mineral • can still have minerals from lower grade zones in higher grade zones, change is controlled by first appearance of the index mineral Metamorphic Zones • Isograd = line that separates the zones delineated by the first appearance of the index mineral •Typical sequence: Low grade Chlorite zone Biotite zone Garnet zone Staurolite zone Kyanite zone High grade Sillimanite zone Barrow’s Metamorphic Zones Pros and Cons of Metamorphic Zones • Concept has been applied in many locations world wide, lots of classical and typelocalities • Convenient for field geologists: there are easy mapable boundaries from zone to zone • Has been applied to different rock types, but mostly used for pelitic rocks •Can be hard to related P/T conditions between different rock types • Doesn’t take into account fluid or stress changes The Facies Concept • Eskola (1915), more rigorous method of dealing with metamorphic rocks • In a metamorphic rock, bulk chemistry of rock is same as protolith, and any change in mineralogy is controlled by this original bulk chemistry and are a result of P/T change under equilibrium conditions • As a result, can define a set of mineral assemblages for all bulk chemistries which occur in same P/T range (regardless of protolith) •Metamorphic facies: is a set of repeatedly associated metamorphic mineral assemblages in a specific P/T range Metamorphic Facies: Quick Example • Chemically identical mineral pairs occur under different P-T conditions MgSiO3 + CaAl2Si2O8 = CaMgSi2O6 + Al2SiO5 Enstatite Anorthite Diopside Andalusite Metamorphic Facies Diagram • Facies are defined by a mineral assemblage that occur over a specific P-T range Metamorphic Stability and Equilibrium • If we can find a mineral or set of minerals are in equilibrium and are formed under a narrow range of P/T conditions, we can determine the corresponding P/T conditions of metamorphism •This is because there is a good understand of what reactions take place during metamorphism specific P-T conditions P-T Diagram #1 • Lines represent equilibrium reactions between different minerals, or phases • Can be broken down into simpler diagrams P-T Diagram #2 b a Metamorphic ACF Diagrams Can build metamorphic diagrams using oxide composition of rock/minerals that show co-existing mineral assemblages (Tie Lines) under conditions that the diagram is constructed z If you can determine mineral assemblages in your rocks, you can see what diagram they all plot on,deduce P-T conditions z A=Al2O3+Fe2O3-Na2O-K2O C=CaO-3.3P2O5 F= FeO+MgO+MnO Metamorphic Summary • Changes in a igneous or sedimentary rock that are caused by P, T, fluids or deformation • 5 different types of metamorphism • Rocks can be broadly classified as foliated or unfoliated • Use concepts of metamorphic zones and metamorphic facies to study metamorphic rocks • We can systematically study metamorphic rocks because the changes are based on reactions that take place under equilibrium conditions at specific PT conditions