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21. What is the basis of the VSEPR theory? 22. Electron pairs repel each other in a molecule. Most stability with largest bond angles. What happens to the bond angles as: a. The number of lone pairs increase? The bond angles decrease b. The number of bonds increase? 23. What two factors determine whether or not a molecule is polar? 24. Bond polarity and molecular shape (lone pairs = asymmetric = more polar) In water, two hydrogen atoms are bonded to one oxygen atom. Why isn’t water a linear molecule? 25. The bond angles decrease Water is not linear because the oxygen atom has 2 lone pairs. Label the following bonds as being nonpolar covalent, polar covalent or ionic, based on electronegativity difference: 3.0 – 1.0 = 2.0 c. P-Br Ionic b. N-O 3.5 – 3.0 = 0.5 d. F-F Polar Covalent What is the meaning of the phrase “Like Dissolves Like.” a. Ca-Cl 26. 2.8 – 2.1 = 0.7 Polar Covalent 4.0 – 4.0 = 0 Nonpolar Covalent Compounds will dissolve if the solvent has the same polarity. Polar dissolves polar, but not nonpolar. Predict the molecular geometry and indicate the polarity for the compounds in the table. Formula Lewis Structure Shape Molecule Polarity 27. SiO2 Linear Nonpolar 28. NF3 Trigonal Pyramidal Polar