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Balancing Redox Reactions Name _____________________________ Date __________ Balance the following oxidation reduction reactions: 1. MnO4-(aq) + H2S(g) --- S(s) + Mn2+(aq) Determine the oxidation numbers and which element is reduced/oxidized: Element Oxidation Oxidation Number Reaction Number Before After Type Mn H Not applicable here S O Not applicable here 1. Write two half-reaction equations (oxidation; reduction): Oxy Red 2. For each ½ equation, make sure the atoms are balanced on both sides a. For each ½ equation, balance the oxygen (if necessary) by adding H2O molecules to one side b. For each ½ equation, balance hydrogen (if necessary) by adding H+ ions 3. Balance the charge for each ½ equation; electrons on the left for reduction reactions and on the right in oxidation reactions (if you have +2 on one side, then you need +2 on the other) 4. If necessary, multiply the equations by an integer so that the number of electrons is the same in both. 5. Add the half-reactions and cancel the electrons; cancel out any other common terms that appear on both sides. 2. Cr2O72- + Fe2+ ---> Cr3+ + Fe3+ Element Oxidation Oxidation Number Before Number After Cr Fe Not applicable here O Step 1 Step 2. Step 2a. Step 2b. Step 3. Step 4. Step 5. Reaction Type 3. Zn + NO3- ---> Zn2+ + NO2 Element Oxidation Number Before Zn N O Step 1 Step 2. Step 2a. Step 2b. Step 3. Step 4. Step 5. Oxidation Number After Reaction Type 4. BrO- ---> Br- + BrO3- (this is called a “disproportionation” reaction; the same element is both oxidized and reduced) Element Oxidation Oxidation Reaction Type Number Before Number After Br Br O Step 1 Step 2. Step 2a. Step 2b. Step 3. Step 4. Step 5. 5. H2O2 + I- + H+ ---> H2O + I2 Element Oxidation Number Before I H O (careful!) Step 1 Step 2. Step 2a. Step 2b. Step 3. Step 4. Step 5. Oxidation Number After Reaction Type Exercise 2 – converting reaction to Basic solution Use your answers for reactions 1, 2, and 3 to convert to a basic (not acidic) solution. Re-write your answer to reaction 1: a. Now add enough OH- ions to cancel the H+ ions (add OH- to both sides): b. Convert all H+ + OH- => H2O molecules c. Cancel like terms that appear on both sides of the reaction (for example, if there are 3H2O molecules on the left and 1 H2O molecule on the right, you should end up with only 2 H2O molecules on the left): Your answer to Reaction 2: a. b. c. Your answer to Reaction 3: a. b. c.