Survey
* Your assessment is very important for improving the workof artificial intelligence, which forms the content of this project
* Your assessment is very important for improving the workof artificial intelligence, which forms the content of this project
WileyPLUS Assignment 3 Chapters 22, 24 - 27 Due Friday, March 27 at noon Q24.21: Intensity = Power/Area Q25.10: Concave mirror - not covered in course, do not attempt Assignment 4 to follow, due last day of term Monday, March 23, 2009 1 Week of March 23-27 Experiment 5: Spectroscopy Week of March 30 - April 3 Tutorial and Test 4: ch. 27, 28 PHYS 1030 Final Exam Wednesday, April 15 9:00 - 12:00 Frank Kennedy Gold Gym 30 multiple choice questions Formula sheet provided Monday, March 23, 2009 2 Chapter 29: Particles and Waves Wave-particle duality – waves behave as particles and particles as waves Waves as Particles • Blackbody radiation from a heated object, Planck’s constant • Photons and the photoelectric effect (and Planck’s constant) Particles as Waves • The de Broglie wavelength of a moving mass (and Planck’s constant) • Heisenberg Uncertainty Principle (and Planck’s constant) • Omit 29.4 – Compton effect Monday, March 23, 2009 3 Waves and Particles Toward the end of the 19th century, it was thought that just about everything was known about physics and that only a few more decimal places of precision needed to be added to physical constants. But then, a number of puzzling phenomena were discovered... • Electrons can be diffracted –!they behave as waves. • Calculations indicated that a heated object should radiate an infinite amount of electromagnetic radiation (blackbody radiation and the ultraviolet catastrophe). • Light is concentrated in packets of energy that behave as particles (photoelectric effect). Monday, March 23, 2009 4 Particles as waves If electrons behaved as particles, they would form an image of the slits on the screen. Under the right conditions, electrons form an interference pattern on the screen, as if they were waves, passing through both slits. –!when do electrons behave as particles, and when do they behave as waves? Monday, March 23, 2009 5 Wave-particle duality In a Young’s type experiment with electrons instead of light passing through the slits, individual electrons can be seen to have hit the screen – they appear on the screen as particles. As numbers build up, an interference pattern becomes clear – each electron must have travelled as a wave through both slits! And then: if particles behave as waves, can waves also act as particles? ...de Broglie and his wavelength... Monday, March 23, 2009 6 Blackbody Radiation violet red Heated objects emit electromagnetic radiation – “blackbody radiation”. The higher the temperature, the shorter the average wavelength. Calculations of the spectrum of blackbody radiation were wildly inaccurate – intensity became infinite at zero wavelength – the “ultraviolet catastrophe”. Planck (1900): radiation is emitted or absorbed by atomic oscillators in the surface of the heated body. Oscillators vibrating at frequency f can only have energy, E = nhf, n = 1, 2, 3..., and h is Planck’s constant (6.626"10-34 J.s, adjusted to fit the spectrum of blackbody radiation). The radiation is emitted or absorbed as packets of energy, E = hf, whenever an atomic oscillator changes energy state. Monday, March 23, 2009 7 Blackbody Radiation Revolutionary ideas introduced by Planck to solve the problem of the ultraviolet catastrophe (and that Planck didn’t believe at the time): • Quantum Hypothesis: The energy of an atomic oscillator cannot take on any value, but only certain “quantized” values, nhf. • Light is emitted and absorbed in packets. The minimum energy of a packet is hf corresponding to an atomic oscillator changing energy by an amount hf. E em radiation of energy hf 4hf 3hf hf 2hf hf Permitted energies of an oscillator of frequency f Classical physics was incomplete. An object cannot have just any energy, but only certain energies. Light is not emitted as a continuous wave, but as packets of radiation of energy hf. Monday, March 23, 2009 8 Blackbody Radiation The significance of blackbody radiation was realized by Josiah Wedgwood, of pottery fame, grandfather of Charles Darwin: – everything inside the oven in which the pottery was heated glowed with the same colour and intensity, so that individual shapes could not be made out. Realized there was a universal spectrum of light emitted by heated objects. Invented the pyrometer for measuring temperature of heated objects from the colour of light radiated. Found use in steel and other industries, just in time for the industrial revolution... Left a fortune of £500,000. Elected Fellow of the Royal Society, 1783, largely for invention of pyrometer. Monday, March 23, 2009 9 The Photoelectric Effect – Photons Shine light onto a metal surface. If the wavelength of the light is short enough, electrons (“photoelectrons”) are liberated from the metal surface. They are accelerated to the positively charged collector. The current is measured with an ammeter. vacuum + – This was not unexpected, but the details were. By reversing the battery, photoelectrons are slowed down rather than accelerated. Increase the potential until even the most energetic photoelectrons are turned back... Monday, March 23, 2009 I 10 Maximum kinetic energy of the photoelectrons The current is reduced to zero when photoelectrons of the highest energy, KEmax, are stopped and turned back to the metal plate by the applied electric field: Collector Metal plate –V0 – KEmax + KEmax = eV0 (they do not have enough energy to get up the potential energy hill, eV0) battery reversed It is found that KEmax is linearly related to the frequency of the light... Monday, March 23, 2009 11 Maximum kinetic energy of the photoelectrons Slope = Planck’s constant There is a threshold frequency for the photoelectric effect The slope of the line has the same numerical value as Planck’s constant, h = 6.626"10-34 J.s., that was found by fitting the spectrum of blackbody radiation. Surprising, as there was no apparent relation between the photoelectric effect and blackbody radiation. The equation of the straight line (Einstein’s photoelectric equation) KEmax = h f −W0 Monday, March 23, 2009 12 Surprising features (~1900) of photoelectric effect when light is considered as a wave • The maximum kinetic energy of the photoelectrons does not depend on the intensity of the light. – More intensity means more energy falling on the metal, so more kinetic energy for the photoelectrons...? No! • Why is the photoelectron current and not KEmax proportional to the intensity of the light? • Why does the energy of the photoelectrons rise with the frequency of the light? And why is there a threshold frequency, fo? • Why is there no time delay in generating photoelectrons when the light intensity is very weak? If the energy of the light is spread over the wavefront, there should not be enough energy hitting a single atom for the photoelectric effect to occur promptly. Monday, March 23, 2009 13 Einstein’s Photoelectric Equation – Interpretation KEmax = h f −W0 The energy of the light is concentrated in packets – “photons” – each of which has energy: E = hf. A minimum amount of energy is needed to knock an electron out of the surface of the metal. That energy is the “work function”, Wo. The maximum kinetic energy of the electron is the energy of the photon, minus the energy to remove the electron from the metal surface. If the photon has too low a frequency, KEmax < 0 and no photoelectrons are produced. The minimum frequency to release photoelectrons is: f0 = Monday, March 23, 2009 W0 h and then, KEmax = 0 14 Photoelectric Effect Photon: E = hf Electron: KEmax = hf – W0 e e Surface of metal, work function Wo Energy of a photon, E = hf = hc/λ Work function, Wo = minimum energy to remove electron from surface KEmax = h f −W0 Monday, March 23, 2009 15 Photoelectric Effect • The photoelectron current is proportional to the intensity of the light because the intensity is proportional to the number of photons per second. • The maximum kinetic energy of the photoelectrons depends on the energy of each photon, E = hf, and not on the intensity of the light. • Photoelectrons are generated immediately, because the energy of the light is concentrated in photons and it takes just one photon to liberate a photoelectron. Monday, March 23, 2009 16 Blackbody Radiation (Planck) • Energy is “quantized” – can take on only certain values • Light is emitted and absorbed as bundles of energy – photons • Planck’s constant determines the energy of the photons, E = hf Photoelectric Effect (Einstein) Photon: E = hf Electron: KEmax = hf – W0 e e Surface of metal • The energy of the light beam is concentrated in photons of energy hf • A single photon can eject an electron from the surface, but only if the photon has sufficient energy, hf > work function, W0 Monday, March 23, 2009 17 Prob. 29.C6: In the photoelectric effect, suppose that the intensity of the light is increased, while the frequency is kept constant. The frequency is greater than the threshold frequency f0. State whether each of the following will increase, decrease, or remain constant, and explain why. a) The current of photoelectrons. b) The number of electrons emitted per second from the metal surface. c) The maximum kinetic energy an electron can have. Monday, March 23, 2009 I 18 Photons • Photons are “particles” of light. • Photons of frequency f have energy E = hf = hc/!. • Photons travel at the speed of light, v = c, and so: mc2 = E ! 1 − v2/c2 = 0 ! 2 mc From E = " 1 − v2/c2 # That is, photons have zero rest energy and mass. • As E2 = p2c2 + m2c4 and m = 0, then E = pc for photons. photons should carry momentum, ! p = E/c = hf/c = h/! verified by Compton effect (not covered) Monday, March 23, 2009 19 Momentum A solar sail would use the momentum of photons of sunlight to accelerate a space craft away from the sun. How would you get back??? Newton’s 2nd law: force = rate of change of momentum. If the light is reflected back, each photon changes momentum by: !p Δp = 2p = 2E/c −!p The force per unit area of sail is, F = "p/"t = 2P/c, where P is the light power falling on the sail per square metre. (F # 7 $N/m2 at earth). Monday, March 23, 2009 20 Prob. 29.4: The maximum wavelength that an electromagnetic wave can have and still eject electrons from a particular metal surface is 485 nm. What is the work function W0 of this metal? Monday, March 23, 2009 21 Prob. 29.7/42: Radiation of a certain wavelength causes electrons with a maximum kinetic energy of 0.68 eV to be ejected from a metal whose work function is 2.75 eV. What will be the maximum kinetic energy when the same radiation is used to eject electrons from a metal whose work function is 2.17 eV? Monday, March 23, 2009 22 Applications of photoelectric effect Photoelectrons generated by the light • Photographic light meters • CCD arrays to capture the image in digital cameras – + + + Incident light releases electrons in each pixel, the number of electrons is proportional to the light intensity. Electrons are trapped in a pixel by positive electrodes. Reading out the number of trapped electrons in each pixel gives the distribution of light intensity. Red, blue, green filters for colours. Monday, March 23, 2009 23 Blackbody Radiation (Planck) • Energy is “quantized” – can take on only certain values • Light is emitted and absorbed as bundles of energy – photons • Planck’s constant determines the energy of the photons, E = hf Photoelectric Effect (Einstein) Photon: E = hf Electron: KEmax = hf – W0 e e Surface of metal • The energy of the light beam is concentrated in photons of energy hf • A single photon can eject an electron from the surface, but only if the photon has sufficient energy, hf > work function, W0 Monday, March 23, 2009 24