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Course code FIE5002 Course group C COURSE DESCRIPTION Volume in Course Course valid to ECTS credits valid from 6 2013 05 31 2016 05 31 Course type (compulsory or optional) Course level (study cycle) Semester the course is delivered Study form (face-to-face or distant) Reg. No. Compulsory II level, 1st term Autumn Face-to-face Course title in Lithuanian Paviršiaus elektrochemija Course title in English Surface Electrochemistry Short course annotation in Lithuanian (up to 500 characters) Kursas skirtas supažindinti studentus su elektrocheminiais procesais, vykstančiais medžiagų paviršiuose akcentuojant adsorbciją, katalizę, koroziją ir oksidaciją. Suteikiamas supratimas apie elektroninius procesus, vykstančius medžiagų paviršiuose, kurie keičia jų savybes, cheminę sudėtį ir termodinamiką. Aiškinami procesai, kuriems vykti reikalinga papildoma energija, ir procesai, kurių metu išsiskiria energija. Short course annotation in English (up to 500 characters) The course presents the electrochemical processes on the surfaces making emphasis on adsorption, corrosion and oxidation. The other key topics include the study of the relationship between chemical change and electric energy. Electrochemistry has two parts: electrolysis (or redox reactions that require energy to occur) and galvanic or voltaic cells (or reactions that provide energy when they occur). Prerequisites for entering the course Course aim The aim of the course is to allow the students to gain necessary knowledge in order to understand, analyze and solve problems related to electrochemical processes. Links between study programme outcomes, course outcomes and criteria of learning achievement evaluation Study programme Criteria of learning Course outcomes outcomes achievement evaluation Described applications of 1. Applications of electrochemistry electrochemistry in the 1. To apply physical models in the fields of fuel cells. fields of fuel cells.. for the description, analysis and assessment of various 5. Formulate models for evaluation energy technologies and their Evaluated of environmental of environmental effects of impact on the environment. effects of electrochemical electrochemical processes used in processes used in energy energy technologies. technologies 3. To use advanced system Described applications of 2. Applications of electrochemistry analysis, modelling and electrochemistry in the in the fields of batteries design tools to design and fields of batteries. develop energy technologies and systems 3. Applications of electrochemistry in the fields of electrolytic processes and electrochemical corrosion. 4. To be able to employ advanced experimental techniques for the development and analysis of new materials for energy technologies 4. Use of calculations on electrochemical systems and in experimental methods in electrochemistry Explained applications of electrochemistry in the fields of electrolytic processes and electrochemical corrosion. Models applied on electrochemical systems and in experimental methods in electrochemistry Link between course outcomes and content Course outcomes Content (topics) 1. Applications of electrochemistry in the fields of fuel cells 2. Applications of electrochemistry in the fields of batteries 3. Applications of electrochemistry in the fields of electrolytic processes and electrochemical corrosion Surface structure of metals. Relaxation and reconstruction of surfaces. Surface tension. The Kelvin equation. Gibbs adsorption equation. Molecular adsorption. Energetic of adsorption. Langmuir isotherm. Enthalpy of adsorption. Kinetics of catalytic reactions. The solid-state electrochemical cell. Electrode potential, cell potential. Theories for the structure of the electrochemical double layer and double layer capacitance. Nerst equation. Battery operation. Electrolysis. Fuel cell mod. 4. Use of calculations on Equilibrium constants for ionic reactions. electrochemical systems and in Auger spectroscopy. Photoelectron spectroscopy. experimental methods in Secondary ion mass spectrometry. Temperature programmed electrochemistry. methods. 5. Formulate models for Basic concepts in surface imaging and localized spectroscopy. evaluation of environmental effects of electrochemical processes used in energy technologies Study (teaching and learning) methods Lectures, discussions, problem analysis Methods of learning achievement assessment Testing, control works, problem solutions, presentations Distribution of workload for students (contact and independent work hours) Lectures 45 hours Seminars 5 hours Laboratory work 10 hours Individual students work 85 hours Total: 160 hours Structure of cumulative score and value of its constituent parts Seminars – 33 %, practical work – 17 %, exam – 50%. Recommended reference materials Number of copies in No . Publication year 1 2012 2. 2007 3. 2007 1. 1997 Authors of publication and title Publishing house Basic materials eLiudas Pranevicius Physical manuscript kinetics and chemistry, VDU A.Galdikas. Surface electrochemistry (www.hydrogen.lt/ LEI kursai/surface_electrochemistr y.pdf). L. Pranevičius. Characterization of surfaces: surface chemistry and electrochemistry. LEI (http://www.hydrogen.lt/moky mai/laboratoriniai/ penktas.pdf) Supplementary materials G. Ertl, H. Knözinger, J. Weitkamp. (Eds.) Handbook on Wiley-VCH heterogeneous catalysis. Course programme designed by Prof. Liudvikas Pranevičius, VMU Physics Department University library 30 1 Self-study rooms Other libraries