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Chapter 6: Starlight and Atoms Properties of Matter • _______ of matter • ______ of matter • How _______ is stored in atoms How do light and matter interact? To study the largest objects in the universe, we must first understand the smallest objects in the universe! What is the structure of matter? • • Electron Cloud Atom Atomic Terminology Atomic Number = # of ______ in nucleus Atomic Mass Number = # of _______ + __________ Nucleus • Molecules: consist of two or more _____ (H2O, CO2 ) Atomic Terminology • Isotope: same # of protons but different # of ________. (4 He, 3He) What are the phases of matter? • Familiar phases: – Solid (ice) – Liquid (water) – Gas (water vapor) • Phases of same material behave differently because of differences in _________ _______ 1 Phase Changes • ________: Breaking of rigid chemical bonds, changing solid into liquid • ____________: Breaking of flexible chemical bonds, changing liquid into gas • ____________: Breaking of molecules into atoms • __________: Stripping of electrons, changing atoms into plasma How is energy stored in atoms? • Electrons in atoms are restricted to particular _______ _____ (electron shells) Energy Level Transitions • An electron can only go from one level to another, not in between ___ ________ A Simple Atom • Only 2 energy levels – Ground (E1) – Excited (E2) • Right now electron is at E1 ________ A Simple Atom • Excitation – Electron ______ a photon and jumps from E1 to E2 – Photon only absorbed if it has energy = (E2-E1) A Simple Atom • Ionization – Electron ______ a photon and leaves! – Only works if electron is in higher energy levels 2 A Simple Atom • De-excitation – Electron _____ a photon of energy (E2-E1) – Electrons like to be in the ground state What are the three basic types of spectra? ________ Spectrum __________ Spectrum __________ Spectrum Spectra of astrophysical objects are usually combinations of these three basic types _________ Spectrum • All wavelengths, no breaks • Rainbows! __________ Spectrum _________ Spectrum • Bright, individual lines • Also called ______-____ spectrum • Electrons are moving to lower energy levels, emitting photons of light Kirchhoff’s Laws I. • Rainbow with dark lines on top • Also called ____-____ spectrum • Atoms in the cloud are absorbing photons, moving to higher energy levels A hot, dense substance will give off ____________ spectrum II. A hot, low-density gas will give off an __________ spectrum III. A cool, low-density gas in front of a continuous-spectrum source will give off an ___________ spectrum 3 Chemical Fingerprints • Each type of atom has a unique set of energy levels Energy levels of Hydrogen • Each transition corresponds to a unique photon energy, frequency, and wavelength Chemical Fingerprints • Each type of atom has a unique spectral fingerprint, due to ________ of ______ _____ Energy Levels of Molecules Spectrum of Molecular Hydrogen (H2) • Spectra of molecules can be very complicated – Lots of energy modes • Molecular transitions are typically in the IR Chemical Fingerprints • Downward transitions produce _______ lines • Upward transitions produce __________ lines Energy Levels of Molecules • Molecules have additional energy levels because they can vibrate and rotate Light and Atoms Lecture Tutorial: page 63 • Work with a partner or two • Read directions and answer all questions carefully. Take time to understand it now! • Come to a consensus answer you all agree on before moving on to the next question. • If you get stuck, ask another group for help. • If you get really stuck, raise your hand and I will come around. 4 What can we learn from light? • • • • Temperature Energy Chemical Composition Speed towards or away from us • Why do different objects give off different forms of light? • They have different ___________! – Temperature depends on the motion of _____ & __________ – Fast motion -> High temp. – Slow motion -> Low temp. All from the spectrum! Temperature, Heat, or Thermal Energy? Kelvin Temperature Scale • Temperature: ________ of thermal energy • Heat: ______ of thermal energy Two objects can be at the same temperature, but have different amounts of heat or thermal energy Temperature and Color • Higher temp = higher E= higher f = shorter λ • What color has shorter wavelength? – _________ – Opposite of faucet handles… 400 nm Temperature and Radiation • Zero Kelvin (written 0 K) is absolute zero (-459.7ºF) – No heat energy • Water freezes at 273 K, boils at 373 K. K = ºC + 273.2 Spectrum: Wavelength vs. Intensity • Visible: • Intensity vs. wavelength plot: 700 nm 5 They show the same information “Dips” in _____ = black lines Temp. and Color: Blackbodies • A blackbody absorbs and re-emits all light that falls on it • Idealized objects – But still a good model for ______ • They don’t actually look black (misnomer) – Color depends on their temperature Dips in ________ Radiation from a Heated Object • Intensity vs. wavelength for three objects of different temperatures. Radiation from a Heated Object • The total ____ under each curve is proportional to the total _______ emitted. – Hotter object emits more total energy than cooler objects. Radiation from a Heated Object • The curves are high in the middle and low at either end. – These objects emit most intensely at middle wavelengths. Radiation from a Heated Object • Wavelength of maximum intensity depends on __________. – The _____ the object, the ________ the wavelength of max. intensity 6 Radiation from a Heated Object Temp. and Color: Blackbodies ______ Object • Temperature determines the _____ of a glowing black body. – The hotter object emits more ____ light than ____, and thus looks ____. – The cooler object emits more ____ than ____, and consequently looks ____. Blackbody Radiation Lecture Tutorial: page 57 • Work with a partner or two • Read directions and answer all questions carefully. Take time to understand it now! • Come to a consensus answer you all agree on before moving on to the next question. • If you get stuck, ask another group for help. • If you get really stuck, raise your hand and I will come around. _______ Object Comparing Spectra • Peak at shorter wavelength = _______ temperature • Higher temperature = _____ in color • Larger _____ ____ under curve = higher total ______ ______ 7 Example: Solar Spectrum 8