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Organic Chemistry B Credit code:13110252 Credits:5 Hours:75 (teaching hours: 75) Preceded courses:Inorganic Chemistry,Inorganic Chemistry Experimentation Major:Chemical Engineering and Technology Course material:Organic Chemistry By Xu Shouchang, high education press, 1991 School:School of Chemistry and Chemical Engineering 1. Course features and objectives: Organic Chemistry is a major basis course for chemical engineering and technology in colleges and universities. The course is intended to improve students’ ability of basic thought and methods, elementary knowledge and basic skill of organic chemistry, and master structure, property, separation and identification of organic compounds, essential condition and reaction mechanism of important reaction, and so on. The course emphasizes to combine theory with practice, enhance students’ ability of problem analysis and problem-solving. The primary mission is to foster higher quality professional. 2. Course elements and requirements Ch1 Structures and Properties of Organic Compounds Master the structures of organic compounds and basic components of the covalent bond theories. Master the meanings of Brфnsted-Lowry acid-bases, Lewis acid-bases, conjugate acid-base. Master the meanings and names of common functional groups. Ch2 Alkanes Master physicochemical properties, nomenclature, configuration and conformation isomers of alkanes. Understand the meachnism of alkanes halosubstituted reaction and free radical reaction. Ch3 Alkenes Master systematic nomenclature, several important reactions and preparation methods of alkenes. Master the basic meanings of the following concepts: sp2 hybridisation, π bond, cis-trans isomer, Z/E configuration, sequene rule, electrophilic addition, catalytic hydrogenation, Markovnikov's rule, hyperoxide effect, ozonation reactions, polymerization reaction, α-H activity. Ch4 Alkynes, Dialkadienes, Infrared Spectroscopy Master the nomenclature of alkynes and dialkadienes, and alkynes’ chemical properties and use. Master conjugated dienes structural features and chemical properties. Understand the characteristic of sp hybridization and infrared spectroscopy.ve Ch5 Alicyclic Hydrocarbons Master nomenclature and chemical properties of alicyclic hydrocarbons, and the conformations of cyclohexane. Ch6 Monocyclic Aromatic Hydrocarbons Master nomenclature and chemical properties of benzene and its homologs. Understand the structural feature of benzene and the mechanism of electrophlic substitution. Master the effect of substituents on reactivity and orientation. Ch7 Polycyclic Aromatic Hydrocarbons and Non-Benzenoid Aromatics Master chemical properties of naphalene and electrophilic substitution rule on naphthalene. Understand biphenyls and its derivatives. Understand Hückel Rule and common non-benzenoid aromatics. Ch8 Stereochemistry Master molecular symmetry, chirality and optical activity. Understand R/S configuration, stereoisomerism of cyclic compounds and resolution of enantiomers Ch9 Halohydrocarbons Master chemical properties, the relationship between structure and properties, preparetions of halohydrocarbons. Understand the mechanism of nucleophilic substitution reactions. Understand some important halohydrocarbons and special use of organic compounds containing fluorine. Ch10 Alcohols and Ethers Master nomenclature, chemical properties and structural features of alcohols and ethers. Master the basic reactions and differentiation of alcohols and ethers. Master the major preparation methods and applications of alcohols and ethers. Ch11 Phenols and Quinones Master chemical properties and preparation methods of phenols. Understand some important phenols and the properties of quinones. Ch12 Aldehydes and Ketones, Nuclear Magnetic Resonance Spectroscopy Master the structural difference between C=O(carbonyl) and C=C and their difference in addition reaction. Master chemical properties and preparation of aldehydes and ketones. Understand mechanism of nucleophilic addition reaction. Understand the difference of chemical properties between aldehydes and ketones. Understand the method to deduce the chemical structure based on the nuclear magnetic resonance spectroscopy. Ch13 Carboxylic Acids and Their Derivates Master nomenclature, chemical properties and structural features of carboxylic acids and their derivates. Master the major reactions, identification, preparation and application of carboxylic acids and their derivates. Ch14 β- dicarboxyl Compounds Master Claisen condensation, keto-enol tautomerism. Master the application of ethyl acetoacetate and diethyl malonate in synthesis. Understand the major properties of active methylene compounds. Ch15 Nitro-compounds and Amines Master preparation and properties of aromatic nitro-compounds. Master classification, nomenclature, preparation, properties and base of amines. Master the difference among primary amine, secondary amine and tertiary amine, some important amines. Understand quaternary ammonium salt and quaternary ammonium hydroxide, the preparation and properties of nitrile and iso-nitrile. Ch16 Diazo Compounds and Azo-compounds Master the properties and application of diazonium salt. Understand the structure, properties and dipolar addition of diazomethane. Understand the relationship between structure and colour of azo-compounds, the colour theory of dyes. Ch17 Heterocyclic Compounds Master nomenclature and structures of common heterocyclic compounds. Master the chemical properties of furan, thiophene, pyrrole and pyridine. Master the properties and preparation of Furfural. Understand the properties of quinoline, isoquinoline and alkaloid. Ch18 Carbothydrates Master the structures and properties of glucose and frutose. Understand the structural feature and application of disaccharide and polysaccharide. Ch19 Amino Acids, Proteins and Nucleic Acids Master the structures, nomenclature and properties of important amino acids. Understand the composition, structures and properties of protein. Understand the composition and structure of two kinds of nucleic acids. Ch20 Elemento-Organic Compounds Master the properties and reparation methods of .the organo-lithium compounds and organo-alumium compounds. Understand organo-silicone compounds and organo-phosphorous compounds. 3. Assignment of course periods. Chapters Lecture Experiment Ch1 Structure and Property of Organic 2 0 Ch2 Alkanes 4 0 Ch3 Alkenes 4 0 Ch4 Alkynes,Dialkadienes, Infrared 6 0 Ch5 Alicyclic Hydrocarbons 2 0 Ch6 Monocyclic Aromatic Hydrocarbons 4 0 Ch7 Polycyclic Aromatic Hydrocarbons and 2 0 Ch8 Stereochemistry 2 0 Ch9 Halohydrocarbons 4 0 Ch10 Alcohols and Ethers 6 0 Ch11 Phenols and Quinones 4 0 6 0 6 0 2 0 Ch15 Nitro-compounds and Amines 6 0 Ch16 Diazo Compounds and Azo-compounds 2 0 Ch17 Heterocyclic Compounds 2 0 Ch18 Carbothydrates 3 0 Ch19 Amino Acids, Proteins and Nucleic Acids 2 0 Ch20 Elemento-Organic Compounds 4 0 Review 2 0 Compounds Spectroscopy Non-Benzenoid Aromatics Ch12 Aldehydes and Ketones, Nuclear Magnetic Resonance Spectroscopy Ch13 Carboxylic Acids and Their Derivates Ch14 β- dicarboxyl Compounds 4. Syllabus description (Experimental content, basic requirements, exercise requirements and other necessary explanations may be included) (1) The experimental requirements are contained in the experimental syllabus. (2) Teaching by multimedia (3) Appropriate amount of homework is to be assigned ever time after lessons which mainly contains exercises and questions attached in the textbook. 5. Bibliography (1) Yun Kuihong , ‘Organic Chemistry’ (1st edition), people’s education press, c1982. (2) Ren Guizhong, ‘Organic Chemistry Study Guide’ (1st edition), Tianjin university press, c1991.