Download Organic Chemistry B

Organic Chemistry B
Credit code：13110252
Credits：5
Hours：75 （teaching hours: 75）
Preceded courses：Inorganic Chemistry，Inorganic Chemistry Experimentation
Major：Chemical Engineering and Technology
Course material：Organic Chemistry
By Xu Shouchang, high education press, 1991
School：School of Chemistry and Chemical Engineering
1. Course features and objectives：
Organic Chemistry is a major basis course for chemical engineering and
technology in colleges and universities. The course is intended to improve students’
ability of basic thought and methods, elementary knowledge and basic skill of organic
chemistry, and master structure, property, separation and identification of organic
compounds, essential condition and reaction mechanism of important reaction, and so
on. The course emphasizes to combine theory with practice, enhance students’ ability
of problem analysis and problem-solving. The primary mission is to foster higher
quality professional.
2. Course elements and requirements
Ch1 Structures and Properties of Organic Compounds
Master the structures of organic compounds and basic components of the
covalent bond theories.
Master the meanings of Brфnsted-Lowry acid-bases, Lewis acid-bases, conjugate
acid-base.
Master the meanings and names of common functional groups.
Ch2 Alkanes
Master
physicochemical
properties,
nomenclature,
configuration
and
conformation isomers of alkanes.
Understand the meachnism of alkanes halosubstituted reaction and free radical
reaction.
Ch3 Alkenes
Master systematic nomenclature, several important reactions and preparation
methods of alkenes.
Master the basic meanings of the following concepts: sp2 hybridisation, π bond,
cis-trans isomer, Z/E configuration, sequene rule, electrophilic addition, catalytic
hydrogenation, Markovnikov's rule,
hyperoxide effect, ozonation reactions,
polymerization reaction, α-H activity.
Ch4 Alkynes, Dialkadienes, Infrared Spectroscopy
Master the nomenclature of alkynes and dialkadienes, and alkynes’ chemical
properties and use.
Master conjugated dienes structural features and chemical properties.
Understand the characteristic of sp hybridization and infrared spectroscopy.ve
Ch5 Alicyclic Hydrocarbons
Master nomenclature and chemical properties of alicyclic hydrocarbons, and the
conformations of cyclohexane.
Ch6 Monocyclic Aromatic Hydrocarbons
Master nomenclature and chemical properties of benzene and its homologs.
Understand the structural feature of benzene and the mechanism of electrophlic
substitution.
Master the effect of substituents on reactivity and orientation.
Ch7 Polycyclic Aromatic Hydrocarbons and Non-Benzenoid Aromatics
Master chemical properties of naphalene and electrophilic substitution rule on
naphthalene.
Understand biphenyls and its derivatives.
Understand Hückel Rule and common non-benzenoid aromatics.
Ch8 Stereochemistry
Master molecular symmetry, chirality and optical activity.
Understand R/S configuration, stereoisomerism of cyclic compounds and
resolution of enantiomers
Ch9 Halohydrocarbons
Master chemical properties, the relationship between structure and properties,
preparetions of halohydrocarbons.
Understand the mechanism of nucleophilic substitution reactions.
Understand some important halohydrocarbons and special use of organic
compounds containing fluorine.
Ch10 Alcohols and Ethers
Master nomenclature, chemical properties and structural features of alcohols and
ethers.
Master the basic reactions and differentiation of alcohols and ethers.
Master the major preparation methods and applications of alcohols and ethers.
Ch11 Phenols and Quinones
Master chemical properties and preparation methods of phenols. Understand
some important phenols and the properties of quinones.
Ch12 Aldehydes and Ketones, Nuclear Magnetic Resonance Spectroscopy
Master the structural difference between C=O(carbonyl) and C=C and their
difference in addition reaction.
Master chemical properties and preparation of aldehydes and ketones.
Understand mechanism of nucleophilic addition reaction.
Understand the difference of chemical properties between aldehydes and
ketones.
Understand the method to deduce the chemical structure based on the nuclear
magnetic resonance spectroscopy.
Ch13 Carboxylic Acids and Their Derivates
Master nomenclature, chemical properties and structural features of carboxylic
acids and their derivates.
Master the major reactions, identification, preparation and application of
carboxylic acids and their derivates.
Ch14
β- dicarboxyl Compounds
Master Claisen condensation, keto-enol tautomerism.
Master the application of ethyl acetoacetate and diethyl malonate in synthesis.
Understand the major properties of active methylene compounds.
Ch15 Nitro-compounds and Amines
Master preparation and properties of aromatic nitro-compounds.
Master classification, nomenclature, preparation, properties and base of amines.
Master the difference among primary amine, secondary amine and tertiary amine,
some important amines.
Understand quaternary ammonium salt and quaternary ammonium hydroxide,
the preparation and properties of nitrile and iso-nitrile.
Ch16 Diazo Compounds and Azo-compounds
Master the properties and application of diazonium salt. Understand the structure,
properties and dipolar addition of diazomethane. Understand the relationship between
structure and colour of azo-compounds, the colour theory of dyes.
Ch17 Heterocyclic Compounds
Master nomenclature and structures of common heterocyclic compounds.
Master the chemical properties of furan, thiophene, pyrrole and pyridine.
Master the properties and preparation of Furfural.
Understand the properties of quinoline, isoquinoline and alkaloid.
Ch18 Carbothydrates
Master the structures and properties of glucose and frutose.
Understand the structural feature and application of disaccharide and
polysaccharide.
Ch19 Amino Acids, Proteins and Nucleic Acids
Master the structures, nomenclature and properties of important amino acids.
Understand the composition, structures and properties of protein.
Understand the composition and structure of two kinds of nucleic acids.
Ch20 Elemento-Organic Compounds
Master the properties and reparation methods of .the organo-lithium compounds
and organo-alumium compounds.
Understand organo-silicone compounds and organo-phosphorous compounds.
3. Assignment of course periods.
Chapters
Lecture
Experiment
Ch1 Structure and Property of Organic
2
0
Ch2 Alkanes
4
0
Ch3 Alkenes
4
0
Ch4 Alkynes，Dialkadienes, Infrared
6
0
Ch5 Alicyclic Hydrocarbons
2
0
Ch6 Monocyclic Aromatic Hydrocarbons
4
0
Ch7 Polycyclic Aromatic Hydrocarbons and
2
0
Ch8 Stereochemistry
2
0
Ch9 Halohydrocarbons
4
0
Ch10 Alcohols and Ethers
6
0
Ch11 Phenols and Quinones
4
0
6
0
6
0
2
0
Ch15 Nitro-compounds and Amines
6
0
Ch16 Diazo Compounds and Azo-compounds
2
0
Ch17 Heterocyclic Compounds
2
0
Ch18 Carbothydrates
3
0
Ch19 Amino Acids, Proteins and Nucleic Acids
2
0
Ch20 Elemento-Organic Compounds
4
0
Review
2
0
Compounds
Spectroscopy
Non-Benzenoid Aromatics
Ch12
Aldehydes
and
Ketones,
Nuclear
Magnetic Resonance Spectroscopy
Ch13 Carboxylic Acids and Their Derivates
Ch14
β- dicarboxyl Compounds
4. Syllabus description (Experimental content, basic requirements, exercise
requirements and other necessary explanations may be included)
(1) The experimental requirements are contained in the experimental syllabus.
(2) Teaching by multimedia
(3) Appropriate amount of homework is to be assigned ever time after lessons
which mainly contains exercises and questions attached in the textbook.
5. Bibliography
(1) Yun Kuihong , ‘Organic Chemistry’ (1st edition), people’s education press, c1982.
(2) Ren Guizhong, ‘Organic Chemistry Study Guide’ (1st edition), Tianjin university
press, c1991.