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GEOLOGY Geology is … the study of the Earth’s form and composition, and both historical and present changes it continues to experience Divided into 2 broad areas of study 1. Physical Geology a) b) c) d) e) Rocks and minerals Igneous Processes Sedimentary Processes Metamorphic Processes Plate tectonics Earth’s Interior Mountain Building Processes Earthquakes and Fault Systems 2. Historical Geology a) Geologic Time Geologic Time Scale Stratigraphy b) Earth’s Origin c) Prehistoric Life Fossils Paleontology MINERALS Minerals … Are the Building Blocks of Rocks Are Naturally Occurring Are Inorganic Are Solid Have a Definite Chemical Structure Properties of Minerals 1. Crystal Form External expression of a mineral’s internal orderly arrangement of atoms ◦ Minerals are crystalline structures made from a mixture of different elemental compounds. ◦ The shape of a crystal is based on the atomic structure of these elemental building blocks. ◦ Atoms within a mineral are arranged in an ordered geometric pattern called a "motif" which determines its "crystal structure." ◦ A mineral's crystal structure will determine its symmetry, optical properties, cleavage planes, and overall geometric shape. ◦ The mixture of these compounds becomes the blueprint for how the crystal will grow. ◦ A crystal's growth pattern is referred to as its "Crystal Habit." 2. Crystal Structure Introduction ◦ Symmetry: the periodic repetition of structural features 2 types Translational symmetry the periodic repetition of a motif across a length or through an area or volume Point symmetry the periodic repetition of a motif around a point Translational Symmetry Point Symmetry Point Symmetry Operations 4 different point symmetry operations. Reflection ◦ Occurs when a motif on one side of a plane passing through the center of a crystal is the mirror image of a motif which appears on the other side of the plane. The motif is said to be reflected across the mirror plane which divides the crystal. Rotation ◦ Arises when a structural element is rotated a fixed number of degrees about a central point before it is repeated. Inversion ◦ Every line drawn through the center of the crystal will connect two identical features on opposite sides of the crystal. Rotoinversion ◦ a compound symmetry operation which is produced by performing a rotation followed by an inversion. 32 possible combinations of symmetry operations. 32 crystal classes Each crystal class is a member of one of 7 crystal systems ◦ Every crystal of a certain crystal system will share a characteristic symmetry element with the other members of its system. A crystal form is a set of planar faces which are geometrically equivalent and whose spatial positions are related to one another by a specified set of symmetry operations. ◦ A simple crystal may consist of only a single crystal form. A more complicated crystal may be a combination of several different forms. Lattices and Unit Cells A specified motif which is translated linearly and repeated many times will produce a lattice. ◦ Motif – spatial arrangement of atoms A lattice is an array of points which define a repeated spatial entity called a unit cell. The unit cell of a lattice is the smallest unit which can be repeated in 3 dimensions in order to construct the lattice. Corners of the unit cell that serve as points which are repeated to form the lattice array are called lattice points. There are14 different lattices called Bravais lattices 3 - 90o axes All equal Copper, Silver, Sodium Chloride 3 - 90o axes Only 2 equal Tin, Rutile, Spodumene 3 - 90o axes All unequal Gallium, Perovskite 3 – axes One pair not at 90o Gypsum 3 - axes None at 90o Potassium Chromate 3 – axes equally inclined None at 90o All equal Calcite, Arsenic, Bismuth 3 - 120o axes coplanar 4th axis at 90o Zinc, Cadmium, Quartz 3 – fold axes 4 – fold axes 7 Crystal Systems The crystal system is a grouping of crystal structures that are categorized according to the axial system used to describe their atomic "lattice" structure. A crystal's lattice is a three dimensional network of atoms that are arranged in a symmetrical pattern. The seven unique crystal systems, listed in order of decreasing symmetry, are … Each crystal system consists of a set of three crystallographic axes (a, b, and c) in a particular geometrical arrangement. 1. Isometric (Cubic) - halite, magnetite, and garnet The crystallographic axes used in this system are of equal length and are mutually perpendicular, occurring at right angles to one another. Can have 2, 3 or 4 fold axes of symmetry Minerals of this system may demonstrate up to 9 different mirror planes. 2. Hexagonal – quartz, apatite, beryl 3 crystallographic axes which intersect at 120° and a fourth which is perpendicular to the other three. ◦ 4th axis is usually depicted vertically. possess a single 6-fold axis of rotational symmetry up to six 2-fold axes of rotation up to 7 mirror planes 3. Tetragonal - zircon and cassiterite a simple cubic shape that forms a rectangular prism. will have a square base and top, but a height which is taller. 3 mutually perpendicular axes possess a single 4-fold symmetry axis possess up to four 2-fold axes of rotation up to 5 mirror planes 4. Trigonal (rhombohedral) – calcite, dolomite possess a single 3-fold axis of rotation possess up to three 2-fold axes of rotation up to 3 mirror planes. 5. Orthorhombic - olivine and barite 3 mutually perpendicular axes, each of which is of a different length than the others possess three 2-fold rotation axes 3 mirror planes 6. Monoclinic - amphibole, orthoclase 3 unequal axes 2 are inclined toward each other at an oblique angle 3rd axis is perpendicular to the other two 2-fold rotation axis a single mirror plane 7. Triclinic - plagioclase 3 unequal axes all intersect at oblique angles None are perpendicular to the others only a 1-fold symmetry axis = no symmetry No mirror planes 3. Luster The appearance or quality of light reflected from the surface of a mineral Types of Luster ◦ Metallic – pyrite, galena, gold, silver ◦ Nonmetallic Vitreous (glassy) – quartz, topaz, fluorite Silky – serpentine, ulexite, satin spar gypsum Resinous – garnet, sphalerite Earthy – hematite, limonite Examples of Mineral Luster Metallic Vitreous Nonmetallic Silky Resinous Earthy 4. Color Caused by slight impurities in the mineral Unreliable diagnostic property ◦ ◦ A mineral can be a variety of colors Example: Varieties of Quartz 5. Streak The color of a mineral in its powdered form More reliable indication of color Obtained by rubbing the mineral across a piece of hard, unglazed porcelain – streak plate Appearances can be deceiving 6. Hardness A measure of the resistance of a mineral to abrasion or scratching ◦ One of the most useful diagnostic properties Determined by rubbing the mineral to be identified against another substance of known hardness MORS Hardness Scale ◦ Consist of 10 minerals arranged in order from hardest (10) to softest (1) 7. Cleavage The tendency of a mineral to cleave, or break, along planes of weak bonding ◦ When a mineral breaks evenly in more than one direction, cleavage is described by the number of planes exhibited and the angles at which they meet. Types of Cleavage 1. Cleavage Quality a.) perfect – mica, calcite b.) imperfect – beryl c.) poor – garnets a. b. c. d. e. f. g. 2. Crystallographic Type a.) basal – micas b.) prismatic – feldspar c.) cubic – halite, galena d.) octahedral – fluorite e.) rhombohedral – calcite f.) pinacoid – amphibole g.) dodecahedral – sphalerite Cleavage in 1 direction – basal Cleavage in 2 directions at right angles – prismatic Cleavage in 3 directions at right angles – cubic Cleavage in 4 directions – octahedral Cleavage in 3 directions not at right angles – rhombohedral Cleavage in 2 directions not at right angles – pinacoid Cleavage in 6 directions – dodecahedral Basal Prismatic Cubic Octahedral Rhombohedral Pinacoid Dodecahedral 8. Fracture Occurs when a broken mineral has a jagged, uneven appearance Examples ◦ ◦ ◦ ◦ ◦ ◦ Concoidal fracture – broken glass: quartz Subconcoidal fracture – like concoidal but w/o curved surface: andalusite Uneven fracture – uneven surface: anhydrite Jagged fracture – sharp points or edges: copper Splintery fracture – fibrous: Chrysotile serpentine Earth fracture – broken clay-like surface: limonite Conchoidal Subconchoidal Uneven Jagged Splintery Earthy 9. Specific Gravity Compares the weight of a mineral to the weight of an equal volume of water 10. Other mineral properties Taste – halite: salty Magnetic – magnetite: attracted to magnet Texture – talc: soapy feel graphite: greasy feel Optical – calcite: double refraction Odor – sulfur: smells like rotten eggs Effervesces – calcite: reacts to HCl (fizzes) Malleability – copper: can be made into different shapes Magnetic Optical Effervesces Malleability