Download 3-D Drawings of Organic Molecules

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VSEPR 3-D Drawings of Organic
Molecules
Models in Chemistry
• Structural models are simplifications, each
having certain advantages and disadvantages
• Together they compliment each other give a
more complete understanding of the
molecular reality
VSEPR -Theory
• Valence Shell Electron Pair Repulsion Theory
• Valence electron pairs repel each other
• They will try to get as far away from each
other as possible!
Carbon
• Carbon has 4 bonds
• equidistantly distributed over the surface of a
sphere (nucleus) will form a tetrahedral
• Angles between single bonds
3D: 109.5o vs 2D: 90o
Different Models of Methane CH4
Stick
VSEPR 3D
Space filling
Quantum
Mechanical
Ball/Stick Model
3D- Drawing guidelines
1. Bonds that lie in the 2D paper plane, draw as
a solid line
(maximize # of these)
2. Bonds protruding from the paper plane are
drawn as a solid wedge
3. Bonds disappearing behind the paper plane
are drawn as dashed
wedge
4. The wide end of the wedge is the outermost
molecule end
Building Models: Example CH3CH2CH3
• Rotate to maximize # of bonds lying in the 2D
paper plane
• The Carbon Skeleton is always portrayed as a
a horizontal zigzag line