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Chapter 4 Review 1 The four most common elements in living things are A B C D E 2 Which of the following is an organic compound? A B C D E 3 O2 H2O CH4 NaCl H2SO4 As shown in this diagram, a carbon atom can complete its valence shell by forming four covalent bonds. This means that a carbon atom is A B C D E 4 neon, xenon, boron, & sulfur. neon, hydrogen, lithium, & helium. carbon, hydrogen, oxygen, & nitrogen. sodium, hydrogen, potassium, & calcium. chlorine, magnesium, sodium, & phosphorus. divalent. trivalent. hexavalent. decavalent. tetravalent. In addition to carbon atoms, most organic compounds also contain A B C D E oxygen atoms. chlorine atoms. hydrogen atoms. potassium atoms. phosphorus atoms. 8/24/2011 12:49:11 PM Page 1 Chapter 4 Review 5 Look closely at this carbon skeleton. How many additional hydrogen atoms could be attached to the carbon atom labeled "B?" A B C D E 6 Stanley Miller's and Harold Urey's 1953 experiments were significant because they demonstrated that A B C D E 7 0 1 2 3 4 under certain circumstances the theory of vitalism was valid. urea could be synthesized from entirely naturally occurring salts. the behavior of any molecule containing a carbon atom was fundamentally the same. lightning discharges could produce the molecules previously presumed to have originated in volcanic outgassings. a variety of simple organic compounds could be spontaneously synthesized from components in Earth's primitive atmosphere. Urea is a molecule synthesized by organisms and found in urine. Stanley Miller and Harold Urey found urea among the products of their experiment. What conclusion could be drawn from this? A B C D E Urea can only be synthesized by living organisms. Life's molecules may have been synthesized abiotically. Someone must have urinated in their experimental apparatus. There was definitely no urea before living things appeared on Earth. none of the above 8/24/2011 12:49:11 PM Page 2 Chapter 4 Review 8 The gasoline consumed by this chainsaw is a fossil fuel consisting mostly of A B C D E 9 Which of these pairs are geometric isomers? A B C D E 10 thiols. alcohols. amino acids. nucleic acids. hydrocarbons. 1 2 3 4 5 Which of these pairs are structural isomers? A B C D E 1 2 3 4 5 8/24/2011 12:49:11 PM Page 3 Chapter 4 Review 11 Which of these pairs are enantiomers? A B C D E 12 Molecules that differ in the arrangement of their atoms about a double bond are called A B C D E 13 enantiomers. geometric isomers. structural isomers. symmetrical isomers. none of the above These molecules are A B C D E 14 1 2 3 4 5 amino acids. enantiomers. hydrocarbons. geometric isomers. structural isomers. The characteristics of an organic molecule depend not only on its carbon skeleton, but also on groups of atoms with distinctive properties--called _____________--attached to the skeleton. A B C D E isomers ketones aldehydes functional groups structural enantiomers 8/24/2011 12:49:11 PM Page 4 Chapter 4 Review 15 Which of these functional groups is an amino group? A B C D E 16 The functional group labeled "4" is a ________ group. A B C D E 17 1 2 3 4 5 hydroxyl carboxyl carbonyl phosphate sulfhydryl If this group is at the end of a carbon skeleton, the molecule is called an aldehyde; otherwise it is called a ketone. A B C D E 2 3 4 5 6 8/24/2011 12:49:11 PM Page 5 Chapter 4 Review 18 Because it donates hydrogen ions, this group is acidic, and molecules that contain these groups are known as "carboxylic acids." A B C D E 19 Which of these is a thiol? A B C D E 20 2 3 4 5 6 -SH -OH -NH2 -COH none of the above Choose the pair of terms that complete this sentence about functional groups in organic chemistry: ______ is to acid as amino is to ______. A B C D E ketone; base carboxyl; base phosphate; ketone carbonyl; sulfhydryl sulfhydryl; carbonyl 8/24/2011 12:49:11 PM Page 6 Chapter 4 Review Page 7 Answer Key : Chapter 4 Review Question: 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 8/24/2011 12:49:11 PM Answer C C E C B E B E D B A B C D A A A E E B