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4. Accessory Organs (NO FOOD IN HERE) The liver produces bile, a substance that breaks up fat particles. The gallbladder stores and concentrates bile. The pancreas produces enzymes that help break down starches, proteins, and fats. 6. Large Intestine Contains bacteria that feed on materials as they pass through. Many of them make vitamins like vitamin K. Water is absorbed from the digested food materials into the bloodstream. 7. The rectum, is where wastes are compressed into solid form.