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Hydrogen Deuterium Tritium Objectives Explain what an isotope is. Compare and contrast two different isotopes Calculate the average atomic mass of an element. Isotopes and Average Atomic Mass Isotopes Atoms When you change the number of electrons,, you electrons get an ion of the same element Mass Number → When you When you change the change the number of number of protons,, you get neutrons protons neutrons,, you an get completely isotopes of the new element same element 238 Can change! Atomic Number → NEVER Changes 92 U Symbols contain the mass number and the atomic number. Naming & Writing Isotopes There are two ways we can write isotopes. We can write the mass as an exponent after the number. Isotopes of Carbon include: C14 and C12 We can also put the mass number after the name of the element: carbon carbon--12 carbon carbon--14 uranium uranium--235 Atoms of the same element can have different numbers of neutrons.. neutrons Atoms with the same number of protons, but different mass isotopes.. numbers are called isotopes Isotopes can be natural like carbon--12/carbon carbon 12/carbon--14 or they man--made like can be man Einsteinium--252/Einsteinium Einsteinium 252/Einsteinium-251 Isotopes can be stable or unstable. Unstable isotopes will decay and are radioactive. How do we measure Atomic Mass? We use grams to measure the mass of most things in chemistry, but not for atomic mass. Why? Because the masses would be too small if measured in grams. grams. Instead of grams, the unit we use is the Atomic Mass Unit (amu amu)) It is defined as one one--twelfth the mass of a carbon--12 atom. carbon Don’t worry about why we use it, just memorize this as a fact! It is like 1 gallon = 4 quarts or why a dozen = 12. It just is. Carbon--12 chosen because of its isotope purity. Carbon purity. 1 Why Average Atomic Mass? The majority of the masses listed on the periodic table are decimals. Why? Because natural samples of elements are a mixture of naturally occurring isotopes. Ex: How heavy is an atom of cesium? It depends on which isotope. isotope. Most cesium isotopes have a mass of 133, but some have a mass of 132 and 134. To account for the mixture of isotopes, we report the masses of elements as the average atomic mass. This is based on the abundance (percentage) of each isotope of that element found in nature. Average Atomic Mass Decimal that is reported in the periodic table Weighted average of all naturally occurring isotopes What is the: Average atomic mass: 95.94 To calculate the Average Atomic Mass: How would you solve this Example: A sample problem? of cesium is 75% 1. Convert the abundance Cesium--133, 20% Cesium percentages into decimals (divide by 100) Cesium--132 and 5% Cesium Cesium--134. What Cesium 2. Multiply the abundance (in decimal form) by the mass of is its average atomic the isotope for each isotope mass? 3. Add the answers from step 2 together. Mass Number Whole Number It is the average atomic mass rounded Represents the most common isotope What is the: Average atomic mass: 40.08 Mass Number: Mass of Most Common Isotope: 96 40 2