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Honors Chemistry Content Standards Iowa Core Curriculum 2011 Semester 2 Chemistry is the science of matter. Its studies include atomic theory; water and its properties; chemical elements, chemical reactions, and energy transformations; nuclear chemistry; and organic chemistry. In all areas of physical science the focus is on the application of the knowledge to solve real life problems. It is the use of the conceptual knowledge and not simply the knowledge itself that should form the core of this discipline. Physical science instruction must include the inquiry knowledge and skills described in the inquiry section of the Science Core Curriculum. Instruction should be engaging and relevant and strong connections must be made the student’s lives. All standards listed are directly from the Iowa Core Curriculum Physical Science Standards. * denotes more complex standards than indicated by the Iowa Core Curriculum denotes standards that are not part of the Iowa Core Curriculum I. SCIENCE AS INQUIRY I.1 Students can formulate a testable hypothesis and demonstrate the logical connections between the scientific concepts guiding hypothesis and the design of an experiment I.2 Students can design and conduct scientific investigations using proper equipment, safety precautions, appropriate technologies, inquiry skills and use appropriate resources to clarify: questions, methods, controls, variables, organization, and presentation to produce critical thought and discussion I.3 Students will use appropriate technology and mathematics to improve investigations and communicate effectively I.4 Student inquires will culminate in formulating an explanation or model to stimulate discussion and/or demonstrate a logical cause and effect relationship I.5 Students will be able to recognize and analyze alternative explanations or models by critically analyzing or reviewing current scientific understandings weighing evidence and logically apply scientific reasoning to evaluate any and all plausible explanations I.6 Students will develop refined ability to communicate and defend their scientific argument using writing, procedures, expressed concepts, accurate data and current scientific models to express themselves verbally, statistically, and logically using charts, diagrams, digital media and written reports 1. Organic Chemistry 1.1 Students know that carbon atoms can bond to one another in chains, rings and branching networks to form a variety of structures 1.2* Students can identify, name and draw the first ten hydrocarbons 1.3* Students can derive and draw structural formulas, molecular formulas and organic short hand interchangeably LAB: Calorimeters LAB: Percent Yield LAB: Electrolysis of Water LAB: Enthalpies of Reactions LAB: Orders of Reactions ACT: Building Blocks of Life LAB: Saponification 2*. Functional Groups 2.1* Students can identify and draw organic functional groups and classes of organic molecules such as: alkanes, alkenes, alkynes, alcohols, aldehydes, ketones, organic acids, lipids, monosaccharide, disaccharides, polysaccharides, esters, ethers, amines, and amino acids and polymers 3. Empirical and Molecular Formulas () 3.1 Students know that empirical formulas are simplest hole number ratio of elements in a compounds 3.2 Students can derive empirical formulas from percent composition 3.3 Students know that the molecular formula is the whole number composition of a molecule calculated as a factor of an empirical formula 3.4 Students can calculate molecular formulas from percent composition, molecular mass and the derived empirical formula 4. Chemical Reactions 4.1 Students know that chemical reactions occur all around us: health care, cooking, cosmetics, automobiles, environmentally, physiologically, industrially… 4.2 Students can identify classes of simple chemical reactions such as: synthesis, decomposition, combustion, single displacement and double displacement 4.3 Students know that the Law of Conservation of Matter states that matter can not be created or destroyed or re-arranged in a chemical reaction and therefore equations must be balanced 4.4 Students will be able to balance all types of chemical equations 5*. Predicting Products 5.1* Students will be able to predict the products of chemical reactions given reactants and balance the equation 5.2* Students will be able to utilize the Activity Series to determine the likelihood of a reaction propagating forward 6. Oxidation Reduction Reactions 6.1 Students know that a large number of important reactions involve the transfer of electrons between atoms, molecules or ions 6.2 Students know that oxidation reaction involve the loss of electrons in a half reaction 6.3 Students know that reduction reactions involve the gain of electrons in a half reaction 6.4* Students will be able to identify and balance redox half reactions 6.5* Students will be able to explain the electrolysis of water and the Hoffman Apparatus LAB: Polymer Balls LAB: Production of Magnesium Oxide LAB: Chemical Equations 7. Stoichiometry () 7.1 Students know that stoichiometry is the application of molar relationships between reactants and products in a balanced chemical equation 7.2 Students will be able to apply dimensional analysis using stoichiometry to solve mole-mole, mole-mass and mass-mass problems 7.3 Students know that some reactants limit the overall outcome or production of products in a chemical reaction 7.4 Students can utilize stoichiometry and dimensional analysis to quantitatively identify limiting reactants and expected yields 7.5 Students can utilize stoichiometry and dimensional analysis to the percent yield for a chemical reaction and limiting reactants LAB: Molar Relationships LAB: Iron & Copper Sulfate LAB: Percent Yield 8. Thermochemistry – Endothermic and Exothermic Reactions 8.1 Students know that the study of thermodynamics involves the production and/or utilization of heat (energy) in all chemical reactions 8.2* Students know that endothermic reactions involve the overall input of heat in a chemical reaction whereas exothermic reactions involve the overall liberation of heat energy in a chemical reaction 8.3* Students can diagram and write endothermic reactions and LAB: Copper and exothermic reactions Energy 9*. Thermochemistry – Calorimeters & Specific Heat Capacity 9.1* Students know that enthalpy is the quantitative expression of the total amount of heat (energy) involved in a chemical reaction 9.2* Students know that calorimeters are tools used to experimentally calculate the heat of a reaction 9.3* Students know that the Specific Heat Capacity of substance is the amount of energy needed to raise 1 gram of that substance 1 degree Celsius 9.4* Students can utilize the Calorimeter Equation to the amount of energy required or produced in a chemical reaction 9.5* Students can utilize stoichiometry and dimensional analysis to calculate the overall enthalpy of a reaction 10*. Thermochemistry – Hess’s Law, Entropy, Gibbs Free Energy 10.1* Students can apply Hess’s Law to calculate the theoretical enthalpy of a reaction 1.2* Students know that entropy measures the degree of disorder in a system 10.3* Students can apply the Second Law of Thermodynamics – the tendency in nature is always towards more disorder LAB: Heats of Reactions 10.4* 10.5* 10.6* 10.7* Students can calculate entropy changes in chemical reactions to determine if a reaction will be spontaneous or non-spontaneous Students know that Gibb’s Free Energy is the quantify of energy that is available or stored to do useful or work or cause change Students will be able to calculate Gibb’s Free Energy in chemical reactions to determine if a reaction is favorable or unfavorable Students will be able to diagram and explain the Heating Curve of Water incorporating Heats of Fusion, Specific Heat Capacity and Heats of Vaporization DEMOS: Spontaneous Combustion of Gummy Bear DEMO: Ammonium Dichromate Volcano 11. Kinetic Molecular Theory of Gases () 11.1 Students can use the Kinetic Molecular Theory of Matter to list and explain the six properties of gases 11.2 Students can use the Kinetic Molecular Theory of Matter to list and explain the four variables that influence and dictate the behavior of a gas 11.3 Students can apply dimensional analysis to perform calculations and conversions between temperatures, volumes and pressures 12. Gas Laws () 12.1 Students can utilize Boyle’s Law to explain and calculate the inverse relationship between the pressure of gas and volume of a gas 12.2 Students can utilize Dalton’s Law of Partial Pressures to explain and calculate the total pressure of a system as the sum of the partial pressures of each individual gas 12.3 Students know that Avogadro’s Principle states that 1 mole of any gas will occupy a constant volume (22.4 L) at standard temperature and pressure (STP) 12.4 Students can utilize Avogadro’s Principle to quantitatively analyze the relationship between moles and volumes of a gas at STP 12.5 Students can utilize Charles’ Law to explain and calculate the direct relationship between absolute temperature a gas and volume of a gas 12.6 Students know that Absolute Zero (O Kelvin) is a theoretical temperature in which all molecular motion stops and matter ceases to exist 12.7 Students can utilize the Ideal Gas Law to explain and calculate the hypothetical behavior of a gas involving all four variables 12.8 Students can utilize the Combined Gas Law to explain and calculate the ratio between the pressure-volume product and the temperature of a system as it remains constant for a given amount of gas 13. Phase Diagrams () 13.1 Students know that absolute temperature and pressure influence and dictate the phases of matter 13.2 Students can interpret and analyze phase diagrams LAB: Charles Law VIDEO: Search for Absolute Zero DEMOS: Fun with Pressure 14. Solutions () 14.1 Students know that a solution is a homogenous mixture of two or more substances composed a solvent and solutes 14.2 Students know that a solute is the substance that dissolve into a solvent 14.3 Students can interpret solubility diagrams to determine concentrations and solubilities as related to temperature 14.4 Students can indentify and explain solutions as unsaturated, saturated and supersaturated 15. Molarity () 15.1 Students know that molarity is a the quantitative description of the amount of solute in one liter of solvent 15.2 Students can quantitatively describe a solutions molarity using stoichiometry and dimensional analysis 15.3 Students can apply solution chemistry, solubilities and molarity to prepare solutions and create quantitative dilutions 16. Equilibrium and Le Chatlier’s Principle () 16.1 Students know that an equilibrium has been reach in a reaction when there is not net change in the concentration of the products or the reactants 16.2 Students can write dissociation reactions for reversible reactions in equilibrium 16.3 Students can diagram and explain the propagation of dissociation reactions until equilibrium is achieved 16.4 Students know that the dissociation constant is the quantitative description of equilibrium reaction that is a ratio of the forward reaction and the reverse reaction 16.5 Students can calculate and interpret dissociation constants to determine the favorability of forwards reactions as compared to the favorability of reverse reactions 16.5 Students know that equilibrium systems are influenced by three factors: temperature, pressure and concentration 16.7 Students know that Le Chatlier’s Principle implies that when a stress is applied to an equilibrium system the equilibrium will shift to decrease the effects of the stress 16.8 Students can predict and explain the direction a equilibrium will shift as different stress are applied 17. Acid and Base Reactions 17.1 Students can list and explain characteristics of acids and bases 17.2 Students that know Arrhenius Acids dissociate in water to produce the hydrogen ion and that Arrhenius Bases dissociate in water to produce the hydroxide ion 17.3* Students can write Arrhenius Acid and Arrhenius Base dissociation reactions 17.4 Students know that a Bronsted-Lowry Acid is any substance that donates a hydrogen ion to produce the hydronium ion whereas a Bronsted-Lowry Base is any substance that accepts a hydrogen ion 17.5* Students can write Bronsted-Lowry Acid/Base reactions identifying the acid, base, conjugate acid and conjugate base 17.6 Students know that acids are classified by the number of hydrogen ions they can donate to identify monoprotic acids, diprotic acids and polyprotic acids 17.7* Students can write the first, second and third dissociation reactions for polyprotic acids 17.8 Students know that when a metal reacts with an acid it always produces hydrogen gas 17.9* Students can predict the write the outcome of an acid reacting with a metal 17.10 Students know that acid and bases react together in neutralization LAB: Acid-Base reactions to produce a salt and water Titration 17.11* Students can predict and write the out of an acid-base neutralization reaction 18. Acid-Base: pKa, pKb, pH 18.1* Students know that the Acid Dissociation Constant indicates the strength of an acid and the Base Dissociation Constant indicates the strength of a base 18.2* Students can calculate the Acid Dissociation Constant or the Base Dissociation Constant of a reaction 18.3* Students can calculate the hydronium ion concentration in an acid/base reaction or the hydroxide ion concentration interchangeably 18.4 Students know that pH is a scale that indicates the strength of acid or a base as determined by the negative logarithm of the hydronium ion concentration 18.5 Students can calculate pH of solution using either the hydronium ion concentration or the hydronium ion concentration 18.6* Students can calculate the hydronium ion concentration or the hydronium ion concentration of solution given a pH 19. Kinetics: Collision Theory 19.1 Students know that chemical reactions can take place in time periods ranging from a few femtoseconds required for an atom to move a fraction of a chemical bond to geological time scales of billions of years 19.2 Students know that kinetics is the study of reaction rates and reaction mechanisms 19.3 Students know that Collision Theory requires that reactants must physically collide with correct geometric orientation and sufficient energy for a reaction to proceed 19.4* 19.5* Students can diagram and explain the Maxwell-Boltzman Energy Distribution Curve for a reaction Students can identify and explain activated complexes according to the Absolute Reaction Rate Theory 20. Kinetics: Rates of Reactions 20.1 Students know that a reaction rate is the change in reactant concentrations in a given amount of time and is determined experimentally as the disappearance of reactants and the appearance of products 20.2* Students can calculate reactions rates as the quotient of concentration changes in a given period of time 20.3* Students can calculate and identify the order of reactions as either: zero order, first order or second order 20.4 Students can identify and explain the four factors that affect reaction rates: temperature, contact probability, complexity of reactants and catalyst 20.5* Students know that increasing temperature increases the number of molecules effectively colliding and decrease the activation energy 20.6* Students know that increasing concentrations, increasing surface areas and physical integration increases the collision probability and increases the number of effective collision 20.7* Students can analyze the complexity of reactions to determine the favorability of a reaction by using G, H and S 20.8* Students know that a catalyst is a mechanism that speeds up the rate of a reaction by decreasing the activation energy and increasing the effective number of collisions LAB: Order of Reactions