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B.Pharm III (Third) Semester Examination 2011-12 Course Code:BPH304 Paper ID:0953104 Pharmaceutical Organic Chemistry-II Time: 3 Hours Max. Marks: 70 Note: Attempt six questions in all. Q. No. 1 is compulsory. 1. a) b) c) d) e) f) g) h) Answer any five of the following (limit your answer to 50 words). (4x5=20) Write about ketonic hydrolysis of acetoacetic ester. On basis of which two chemical properties Malonic ester is used as a synthetic reagent? Draw structure of Guanine. Define frie’s reaction. Define Witting reaction. Which name reaction describes synthesis of ketone from secondary alcohol? Name refluxing agents and bases used in this reaction. Classify amino acids with examples. In furan, substitution at 2-position is favoured. Why? 2. Write general methods of synthesis of amino acids with one example in each method. Write various reactions of amino acids due to Amino group. (10) 3. Define Mannich reaction and Benzoin condensation along with their mechanism. (10) 4. Write synthetic applications of Merwin Pondorff Verley reduction and Oppeneaur oxidation with examples. (10) 5. Write methods of preparation and reactions of Methyl vinyl ketone. Write synthetic applications of Malonic easter. (10) 6. Classify proteins with example. identification tests of proteins. Describe various (5) 7. Write definition, mechanism and applications of Michael condensation. (5) 8. Write methods of preparation and properties of Pyridine and Indole. (5)