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Light-trapping pigments Radiant energy from the sun includes a range of wavelengths: o Visible light, in the range from about 0.4 to 0.7µm o Infra-red (IR), with wavelengths greater than 0.7µm o Ultraviolet light (UV), with wavelengths shorter than 0.4µm Various pigments can trap light energy: o Major light trapping pigments are green chlorophylls located on the grana membranes. o Other kinds of light-trapping pigments are also found in chloroplasts of various organisms = accessory pigments. Pigment Chlorophyll a Chlorophyll b Chlorophyll c Chlorophyll d Carotenoids Phycobilins Organisms where found All plants and all algae All plants and green algae Brown algae and phytoplankton Red algae All plants and green algae Red algae Carotenoids are red, orange and yellow pigments that are normally masked by the green chlorophylls. In temperate climates in early autumn, deciduous trees begin to withdraw the chlorophyll from their leaves, exposing the carotenoids and other pigments that are normally hidden. Phycobilins are blue-green (phycocyanin) and red (phycoerythrin) watersoluble pigments. The various pigments trap light energy of different wavelengths (see figure below). The presence of accessory pigments extends the range of light wavelengths that can be absorbed by a plant and converted to chemical energy. Light energy absorbed by accessory pigments must be transferred to chlorophyll a before it can be converted into chemical energy. Photosynthesis is most efficient in light of red and blue wavelengths. These wavelengths do not penetrate very far below the surface of water. In deeper waters most of the light wavelengths available are blue-green, which accessory pigments can absorb. The phycobilins, in particular, contribute to photosynthesis in deeper waters and these are found in seaweeds. Seaweeds that have colour when brought to the surface of the water often look black when looked at in water.