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Leaders: Shealyn Course: Chem 178 Supplemental Instruction Iowa State University Instructors: Burnett/ Vela Date: 4-29-14 1. Battery: self-contained ________ device containing one or more ______ cells. For _______ cells placed in _____ (as shown) the voltage or potential is _______. 2. In the lead-acid battery used in automobiles, shown in the figure, each voltaic cell is 2 volts. To achieve 12 volts, _____ cells are placed in _____. 3. In the U.S. corrosion costs the economy roughly one-half to one trillion dollars annually, _____% of the GDP. 4. Most metal cations have ______ (negative/positive) standard reduction potentials, consequently they have a tendency to become ________ (reduced/oxidized). Which means that metals tend to spontaneously _______(reduce/oxidize) in air. 5. Some metals form a(n) _____ layer barrier that prevents further _________(reduction/oxidation). 6. Cathodic protection: add a ____ (more/less) reactive metal such as ___ or ___ that preferentially oxidizes and forces the iron to be the ______ (anode/cathode) and therefore remains in its reduced form. Such metals must have a more _______ (positive/negative) Eored potential. 7. The primary difference between a battery and a fuel cell is that a battery is ______________ and a fuel cell requires continuous ________(addition/removal)of ________(reactant/product) and _______(addition/removal) of _______(reactant/product). 8. Fuel cells: electrochemical devices that use ______ to produce electrical _____. 9. We have pointed out that combustion reactions are ______ reactions. Therefore the fuels used in combustion can be used to power fuel cells. Fuel cells can be very efficient in converting chemical ________(potential/electrical) energy into 1060 Hixson-Lied Student Success Center 515-294-6624 [email protected] http://www.si.iastate.edu _______(potential/electrical) work relative to energy of combustion being converted into work. 10. For nuclear processes, there is one criteria for spontaneity: if the reaction produces _____ (ΔE < 0), then the process is spontaneous (ΔSuniverse ___ (</>/=) 0). 11. nuclear processes are accompanied by ______ (small/large/average) amounts of energy. 12. Fission: a(n) _____(stable/unstable) nucleus _________ (decaying/combining) to form 2 or more more-stable nuclei Fusion: 2 relatively ________(stable/unstable) nuclei combining to form a single more ______(stable/unstable) nucleus Transmutation: the _________(decaying/combining) of one nucleus/isotope into a different nucleus/isotope. 13. Define nucleon: 14. For light elements (up to atomic number ___), stable nuclei have ____ (1:1. 1:2, 2:1) neutron to proton ratios. As the number of protons increases, stable isotopes have _________(decreasing/increasing) neutron to proton ratios. 15. We also saw that nuclei with more than ___ protons are ________(stable/unstable). 16. Decay mechanisms for unstable nuclei: a. _____ emission (reduces mass & charge of nuclei) b. _____ emission (increases charge of nuclei, mass unchanged) c. ______ ______ (decreases charge of nuclei, mass unchanged) d. _____ emission (reduces charge of nuclei, mass unchanged) 17. Nuclei with ____ (even/odd) numbers of nucleons are more stable. 18. Nuclei that are unstable are generally unstable for several possible reasons: a. proton:neutron ratio too large or too many ______ (protons/neutrons)for number of _______ (protons/neutrons) b. proton:neutron ratio too small or too many _______ (protons/neutrons) for number of _______ (protons/neutrons) c. nuclei too large (>___ protons) d. ____(even/odd) number of nucleons, protons, or neutrons e. unfilled shell structure for nucleons 19. Gamma particles are ____less and ______less. They are a form of electromagnetic radiation. Gamma particles are also called _______ (positrons/photons) and are emitted in all nuclear reactions. 20. Complete and balance the following nuclear equations, identify the type of radioactive decay, and deduce the source of nuclear instability of parent nuclei. a. 239 94 Pu 40 4 2 + ____ 40 K 20 Ca + ____ b. 19 0 40 e 18 Ar c. ____ + 1 d. 14 6C ____ + 0 1 e