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SCH 4C EXAM REVIEW UNIT 1 1. Study the WHMIS symbols on page 479. 2. What does the term qualitative analysis refer to? Give an example of a time where you carried out a qualitative analysis in class. 3. Distinguish between physical properties and chemical properties. Give an example of each. 4. Distinguish between physical changes and chemical changes. Give an example of each. 5. Define and give an example of each of the four classes of matter: elements, compounds, solutions, and mechanical mixtures. 6. What are the three subatomic particles? For each of these particles give its relative mass, relative charge, and location in the atom. 7. Give the group number from the periodic table for each of the following: halogens, alkali metals, noble gases, alkaline earth metals. Where on the periodic table are the metals and the nonmetals? How do the properties of metals compare to those of nonmetals, state at least 3 properties? 8. Give the numbers of protons, neutrons and electrons found in each of the following. 168O 199F 9. Draw Bohr-Rutherford diagrams for the atoms in number 9. 10. Define the following terms: conductivity, electrolyte, and non electrolyte. 11. What are valence electrons? State the octet rule. 12. What is an ion? What is the difference between an anion and a cation? 13. Draw Lewis symbols for the following atoms: H, F, Ar. 14. How does an ionic bond form? What type of elements do ionic bonds form between? Show what happens to the valence electrons during the formation of an ionic bond between (a ) Mg and Cl (b) Ca and O 1 15. How does a covalent bond form? What type of elements do covalent bonds form between? Draw Lewis structures for the following molecules: (a) H2O (b) NH3 16. Use the charts on pages 493 and 494 to help answer these questions (a) Give the correct formula for: iron(11) oxide, sodium carbonate, magnesium chloride, copper(11) sulphate, potassium nitrate (b) Give the correct names for: Ca(NO3)2, K2SO4, Cu(OH)2, HCl, MgCO3 17. Identify each of the following as synthesis, decomposition, single displacement, or double displacement. Balance each of the equations. (a) HCl + Zn ZnCl2 + H2 (b) Mg(NO3)2 + Na2CO3 NaNO3 + MgCO3 (c) H2O H2 + O2 (d) Na + Cl2 NaCl (e) H2SO4 + Mg MgSO4 + H2 18. Which one of the following two substances would be ionic? Give reasons for your answer. SUBSTANCE MELTING POINT BOILING POINT CONDUCTIVITY A 850ºC 1600ºC Good B 43ºC 125ºC does not conduct 2 UNIT 2 - SCH 4C 1. Define the term mole. 2. Calculate the molar mass of each of the following: (a) C6H6 (b) Ba(NO3)2 (c) K3PO4 ANS: (a) 78.12 g (b) 261.36 g (c) 212.27 g 3. What is the mass of 2.4 mol of H2O? ANS: 43 g 4. How many CO2 molecules do you have if you have 0.0052 mol of CO2? 3.13 X 1021 molecules ANS: 5. How many moles of Mg do you have if you have 50.0 g of Mg? ANS: 2.06 mol 6. How many moles of Na do you have if you have 8.74 X 1025 atoms of Na? ANS: 145 mol 7. What is the mass of 4.33 X 10 22molecules of SO2? ANS: 4.61 g 8. A compound is 38.71 % C, 9.71 % H and 51.58 % O. What is the empirical formula of this compound? ANS: CH3O 9. If the actual molar mass of the compound in number 8 is 93.12 g/mol, what is the molecular formula of this compound? ANS: C3H9O3 10. Propane reacts with oxygen according to the following equation: C3H8 + 5 O2 3 CO2 + + 4 H2O What mass of O2 is needed to react completely with 40.0 g of C3H8? ANS: 145 g 11. Determine the mass of Cu that can be obtained from a reaction between 286.2 g of Cu2O and 318.3 g of Cu2S. They react according to the following equation: 2 Cu2O + Cu2S 6 Cu + SO2 ANS: 381 g 12. Zinc reacts with HCl as shown in the following equation: Zn + 2 HCl ZnCl2 + H2 ANS: 82.% 13. In an experiment 16.1 g of FeS is added to an excess of oxygen and the following reaction occurs: 4 FeS + 7 O2 2 Fe2O3 + 4 SO2 (a) What is the theoretical yield of Fe2O3? (b) What is the percentage yield if 14.1 g of FeO3 is collected in the lab? ANS: (a) 14.6 g (b) 96.6% 3 UNIT 3 – SCH4C 1. What is a hydrocarbon? 2. (a) What is the difference between a saturated hydrocarbon and an unsaturated hydrocarbon? (b) Which type of hydrocarbons are saturated? (c) Which types of hydrocarbons are unsaturated? (d) Which are more reactive chemically, saturated hydrocarbons of unsaturated hydrocarbons? 3. What type of chemical reaction do all hydrocarbons undergo? 4. Write the balanced chemical equation for the complete combustion of the following hydrocarbons. (a) ethane (b) 1 – butene 5. What type of reaction will unsaturated hydrocarbons undergo that saturated hydrocarbons will not? 6. Write a complete balanced equation for the following addition reactions. (a) H C CH3 H2C + Cl2 (b) H3C H2 C C C CH3 + 2 Br2 (c) H3C H C C H CH3 + H2O 7. (a) How does the length of the carbon chain effect the melting points and boiling points of hydrocarbons? (b) Which of the following would you expect to have the highest boiling point? (1) CH3CH2CH2CH2CH3 (2) CH4 (3) CH3CH3 8. Are hydrocarbons soluble in water? Why or why not? 9. What are isomers? 4 10. Which of the following pairs represents pairs of isomers? (a) (b) H2C CH2 H3C CH3 H C H2C H C H2C (c) CH3 C H2 H3C H C CH 2 CH3 H3C H C C H CH3 11. Classify each of the following as an alkane, an alkene or an alkyne. (a) propane (b) CH2 H2C (c) ethyne (d) H3C H2 C C C C H2 H2 C C H2 H2 C CH3 12. Give the correct name for each of the following hydrocarbons. (a) H2 H2 H2 C C C C CH3 C C C H3C H2 H2 H2C (b) (c) H3C C CH2 C CH3 (d) H3C CH HC CH2 H3C 5 13. Draw the structural formula and give the molecular formula for: (a) butane (b) 1 – hexene (c) 2 – pentyne (d) ethyne (e) 4- nonene 14. Why is no number used in the names “ethene” and “propene”? 15. Why is the name 3 - pentyne incorrect? 16. Describe and explain the relationship between the sizes of hydrocarbon molecules and their boiling points. 20 What is a functional group? 21. What type of functional group does an alcohol contain? 22. Give the physical properties of alcohols. 23. Write the equation for the complete combustion of methanol. 24. (a) Name the following: (1) CH3CH2OH (2) CH3CH2CH(OH)CH3 (3) CH3 CH2 CH2CH(OH) CH2 CH2CH3 (b) Draw the structural formula for each of the following: (1) 1 – propanol (2) ethanol (3) 3 – hexanol 25. What type of functional group does an ether contain? 26. Describe the physical properties of ethers. 27. Explain why methanol has a higher melting point than methane. 29. Consider the following two compounds: CH3CH2CH2CH2CH2CH2OH and CH3CH2CH2OCH2CH2CH3. (a) Which is an ether and which is an alcohol? (b) Which will evaporate at the lower temperature? (c) Which has the higher solubility in a polar solvent? 30. What type of functional group does a carboxylic acid have? 31. What type of chemical reaction is common for carboxylic acids? 32. What is the functional group for an ester? 34. What are the products and the reactants in an esterification reaction? 41. What is a polymer? 6 UNIT 4 – SCH4C 1. What is an electrolyte? What evidence do we have that acids and bases are electrolytes? 2. List three properties of bases. 3. List three properties of acids. 4. What colour is litmus in acid? In base? 6. Give the Arrhenius definition of an acid. 7. Give the Arrhenius definition of a base. 8. Classify each of the following as an acid, a base, or a salt. (a) HCl (b) Mg(OH)2 (c) MgCl2 (d) HC2H3O2 (e) NaNO3 (f) KOH (g) BaBr2 (h) Ca(OH)2 (i) H2SO4 (j) NaOH 10. Show the dissociation or ionization reactions for each of the following: (a) Ba(OH)2 (b) HNO3 (c) Ca(NO3)2 11. What does pH stand for? 12. Determine the pH of each of the following given the hydrogen ion concentration in the solution. (a) [H+] = 10-5 mol/L (b) [H+] = 10-14 mol/L (c) [H+] = 10-2 mol/L (d) [H+] = 10-7 mol/L (e) [H+] = 10-6 mol/L 13. State whether each of the solutions in number 12 is acidic, basic, or neutral. 14. Find the [H+] in solutions with each of the following pH values. (a) pH = 5 (b) pH = 10 (c) pH = 13 (d) pH = 4 15. State whether each of the solutions in number 14 is acidic, basic, or neutral. 16. If the pH of one solution is 4 and the pH of another solution is 7, which solution is more acidic? How many times greater is the [H+] in the more acidic solution? 17. Define the term salt. 18. What are the three characteristic reactions that acids undergo? Write the general equation for each one. 7