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... substances. It is not readily oxidized or reduced, unlike other oxides of nitrogen. When passed over heated metals such as iron, copper, and lead, nitrous oxide decomposes to nitrogen and oxygen, exothermically: N2O → N2 + ½ O2 Because of its ability to release oxygen at high temperatures, nitrous o ...
Antioxidant activities of dithiol alpha
Antioxidant activities of dithiol alpha

... factor which play important role in the regulation of number of genes which are related to inflammation and pathogenesis of number of diseases including atherosclerosis, cancer, diabetes and HIV11. Physiologically concentrations of alpha-lipoic acid have been found to inhibit NF-κB induced activatio ...
1 Glucose: evolution`s favorite flavor… In any metabolism course
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... without exception, every participant in life’s rich panoply of organisms loves, wants, craves and preferably uses glucose for energy whenever possible. Energy? Who said anything about energy? I just did, in a brilliant literary trick called “foreshadowing” which in other situations might also be cal ...
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11.2 Types of Chemical Reactions

... These equations describe two examples of single-replacement reactions. A single-replacement reaction is a chemical change in which one element replaces a second element in a compound. You can identify a singlereplacement reaction by noting that both the reactants and the products consist of an eleme ...
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Chapter 20
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Radical (chemistry)



In chemistry, a radical (more precisely, a free radical) is an atom, molecule, or ion that has unpaired valency electrons.With some exceptions, these unpaired electrons make free radicals highly chemically reactive towards other substances, or even towards themselves: their molecules will often spontaneously dimerize or polymerize if they come in contact with each other. Most radicals are reasonably stable only at very low concentrations in inert media or in a vacuum.A notable example of a free radical is the hydroxyl radical (HO•), a molecule that has one unpaired electron on the oxygen atom. Two other examples are triplet oxygen and triplet carbene (:CH2) which have two unpaired electrons. In contrast, the hydroxyl anion (HO−) is not a radical, since the unpaired electron is resolved by the addition of an electron; singlet oxygen and singlet carbene are not radicals as the two electrons are paired.Free radicals may be created in a number of ways, including synthesis with very dilute or rarefied reagents, reactions at very low temperatures, or breakup of larger molecules. The latter can be affected by any process that puts enough energy into the parent molecule, such as ionizing radiation, heat, electrical discharges, electrolysis, and chemical reactions. Indeed, radicals are intermediate stages in many chemical reactions.Free radicals play an important role in combustion, atmospheric chemistry, polymerization, plasma chemistry, biochemistry, and many other chemical processes. In living organisms, the free radicals superoxide and nitric oxide and their reaction products regulate many processes, such as control of vascular tone and thus blood pressure. They also play a key role in the intermediary metabolism of various biological compounds. Such radicals can even be messengers in a process dubbed redox signaling. A radical may be trapped within a solvent cage or be otherwise bound.Until late in the 20th century the word ""radical"" was used in chemistry to indicate any connected group of atoms, such as a methyl group or a carboxyl, whether it was part of a larger molecule or a molecule on its own. The qualifier ""free"" was then needed to specify the unbound case. Following recent nomenclature revisions, a part of a larger molecule is now called a functional group or substituent, and ""radical"" now implies ""free"". However, the old nomenclature may still occur in the literature.
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