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... Because ΔG is a state function (path independent), chemical reactions with known ΔG values can be manipulated to determine ΔG for a different reaction. ΔG for the different reaction is the sum of ΔG for all the steps (reactions) added together to get the different reaction. This is Hess’s law. ...
CHAPTER SIXTEEN SPONTANEITY, ENTROPY, AND FREE
CHAPTER SIXTEEN SPONTANEITY, ENTROPY, AND FREE

... Because ΔG is a state function (path independent), chemical reactions with known ΔG values can be manipulated to determine ΔG for a different reaction. ΔG for the different reaction is the sum of ΔG for all the steps (reactions) added together to get the different reaction. This is Hess’s law. ...
IB Chemistry Online SAQ_Ans
IB Chemistry Online SAQ_Ans

... corresponding to all the wavelengths (within a certain range) are present. In an emission spectrum only a limited number of radiations corresponding to a small number of wavelengths (within a certain range) are present. 10 This is a thought experiment illustrating the principles of quantum mechanic ...
1 Solutions 4a (Chapter 4 problems) Chem151 [Kua]
1 Solutions 4a (Chapter 4 problems) Chem151 [Kua]

... (c) The second two parts of this problem involve stoichiometric calculations. The problem gives information about the amounts of both starting materials, so this is a limiting reactant situation. We must calculate the number of moles of each species, construct a table of amounts, and use the result ...
SCH3U: Final Exam Review
SCH3U: Final Exam Review

... a. transition metals b. third energy level c. main group elements d. radioisotopes e. electron affinity f. electronegativity g. halogens h. transuranium elements i. valence shell j. third ionisation energy k. octet ...
Mole-mole factor
Mole-mole factor

... A balanced chemical equations tell us: – The formulas and symbols of the reactants and products – The physical state of each substance – If special conditions such as heat are required – The number of molecules, formula units, or atoms of each type of molecule involved in the reaction • Number can b ...
Chapter 5: Gases - HCC Learning Web
Chapter 5: Gases - HCC Learning Web

... 8. Copper metal has a specific heat of 0.385 J/g·°C. Calculate the amount of heat required to raise the temperature of 22.8 g of Cu from 20.0°C to 875°C. A) 1.97  10–5 J B) 1.0  10–2 J C) 329 J D) 7.51 kJ E) 10.5 kJ Ans: D Category: Medium Section: 6.5 9. Calculate the amount of heat necessary to ...
Homework 5-7 answers
Homework 5-7 answers

... 8. Copper metal has a specific heat of 0.385 J/g·°C. Calculate the amount of heat required to raise the temperature of 22.8 g of Cu from 20.0°C to 875°C. A) 1.97  10–5 J B) 1.0  10–2 J C) 329 J D) 7.51 kJ E) 10.5 kJ Ans: D Category: Medium Section: 6.5 9. Calculate the amount of heat necessary to ...
Homework 5-8 answers
Homework 5-8 answers

... A) the energy stored within the structural units of chemical substances. B) the energy associated with the random motion of atoms and molecules. C) solar energy, i.e. energy that comes from the sun. D) energy available by virtue of an object's position. Ans: C Category: Easy Section: 6.1 2. Thermal ...
1.09 MB / 64 pages
1.09 MB / 64 pages

... Note that there are two H bonds between H atoms in water molecules and nonbonding electron pairs on the oxygen of ethanol, and another H bond between the –OH group’s hydrogen and a nonbonding electron pair on the oxygen in water. The water molecules have other nonbonding pairs on oxygen and covalent ...
Adsorption and desorption
Adsorption and desorption

... If the transition state requires a complicated or “demanding” configuration which has a low probability of realization q# and νdes may get much smaller. The agreement between measured and calculated values of νdes is poor. Nevertheless, transition state theory gives an idea why νdes values vary so s ...
Chemistry – A Molecular Sciences Appendices
Chemistry – A Molecular Sciences Appendices

... dioxide molecule, which has the formula CO2, contains one carbon atom and two oxygen atoms. This information is contained in the subscripts after each element. A molecule of sucrose (C12H22O11) has 12 carbon atoms, 22 hydrogen atoms and 11 oxygen atoms. The subscripts also indicate the ratios of the ...
5 - Wiley
5 - Wiley

... which X O2 = 0.2095. Table 2-5 gives the vapour pressure of water at 20 ºC, 17.535 Torr; this is the partial pressure at 100% humidity for that temperature. To find the mole fraction of O2 at 100% humidity, first determine the partial pressure of O2. We can assume air is composed only of oxygen, nit ...
Early events in protein folding
Early events in protein folding

... polypeptide chain searches out its final native conformation from an inconceivably large number of available conformations. A polypeptide chain of 101 amino acid residues would have to sample 3100 = 5 × 1047 conformations, if each bond connecting two consecutive residues has only three possible conf ...
Solutions - ChemConnections
Solutions - ChemConnections

... ∆GE, HF must have a positive ∆G orxn value, while the other HX acids have ∆G°rxn < 0. The reason for the sign change in the Ka value, between HF versus HCl, HBr, and HI is entropy. ∆S for the dissociation of HF is very large and negative. There is a high degree of ordering that occurs as the water m ...
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Solutions

... An exothermic reaction is a chemical reaction or a physical change in which heat is evolved (q is negative). For example, burning one mol of methane, CH4(g), yields carbon dioxide, water, and 890.3 kJ of heat. An endothermic reaction is a chemical reaction or physical change in which heat is absorbe ...
Solutions to Exercises
Solutions to Exercises

... An exothermic reaction is a chemical reaction or a physical change in which heat is evolved (q is negative). For example, burning one mol of methane, CH 4(g), yields carbon dioxide, water, and 890.3 kJ of heat. An endothermic reaction is a chemical reaction or physical change in which heat is absorb ...
The science of chemistry is concerned
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... The chemical reaction in this example is of environmental interest. Iron pyrite (FeS2 ) is often an impurity in coal, and so burning this fuel in a power plant produces sulfur dioxide ( SO 2 ), a major air pollutant. Our next example also involves burning a fuel and its effect on the atmosphere. ...
Monoclonal Antibody between Cockroach Allergen Bla g 2 and a
Monoclonal Antibody between Cockroach Allergen Bla g 2 and a

... acid sequence of the lobes differs and thus would be expected to cause antigenic differences on their molecular surfaces. Our goal has been to map the antigenic surface of Bla g 2 by solving the x-ray crystallographic structures of complexes of the allergen with specific murine mAbs. Most of the rep ...
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... molecules spread out to occupy a greater volume, we expect there to be an increase in the entropy of the system. Use ΔSsys = Sfinal – Sinitial to solve for ΔSsys. R = 8.314 J/K∙mol, n = 1.0 mole, Vfinal = 5.0 L, and Vinitial = 2.5 L. ...
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... If you are given one dozen loaves of bread, a gallon of mustard, and three pieces of salami, how many salami sandwiches can you make? ...
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BRIEF ANSWERS TO SELECTED PROBLEMS APPENDIX G

... electron to form an ion with a 1 charge. Each sulfur atom gains two electrons to form an ion with a 2 charge. Two potassiums, losing one electron each, are required for each sulfur, which gains two electrons. The oppositely charged ions attract each other to form an ionic solid, K2S. 2.70 K; I 2 ...
Chapter 8: Balances on Nonreactive Processes
Chapter 8: Balances on Nonreactive Processes

... *The flow rates were obtained by multiplying the molar fraction of each component by the total flow rate of the corresponding stream. *The enthalpy of the liquid water exiting the system was set to zero since it is leaving the system at the reference conditions. This also occurs for the nitrogen and ...
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... moles to get the ratio of the elements, one to another. If any result is far from a whole number multiply through by a common factor that converts each number of moles to integers (or close) If each is close to a whole # round off each to nearest ...
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... began when we found unpredicted results; the results often pointed out our own misconceptions about the underlying chemistry. Presently, we site license CAChe software. The site license has made CAChe accessible to faculty and students; CAChe is available on all department and campus computer lab ma ...
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Implicit solvation

Implicit solvation (sometimes known as continuum solvation) is a method of representing solvent as a continuous medium instead of individual “explicit” solvent molecules most often used in molecular dynamics simulations and in other applications of molecular mechanics. The method is often applied to estimate free energy of solute-solvent interactions in structural and chemical processes, such as folding or conformational transitions of proteins, DNA, RNA, and polysaccharides, association of biological macromolecules with ligands, or transport of drugs across biological membranes. The implicit solvation model is justified in liquids, where the potential of mean force can be applied to approximate the averaged behavior of many highly dynamic solvent molecules. However, the interiors of biological membranes or proteins can also be considered as media with specific solvation or dielectric properties. These media are continuous but not necessarily uniform, since their properties can be described by different analytical functions, such as “polarity profiles” of lipid bilayers. There are two basic types of implicit solvent methods: models based on accessible surface areas (ASA) that were historically the first, and more recent continuum electrostatics models, although various modifications and combinations of the different methods are possible. The accessible surface area (ASA) method is based on experimental linear relations between Gibbs free energy of transfer and the surface area of a solute molecule. This method operates directly with free energy of solvation, unlike molecular mechanics or electrostatic methods that include only the enthalpic component of free energy. The continuum representation of solvent also significantly improves the computational speed and reduces errors in statistical averaging that arise from incomplete sampling of solvent conformations, so that the energy landscapes obtained with implicit and explicit solvent are different. Although the implicit solvent model is useful for simulations of biomolecules, this is an approximate method with certain limitations and problems related to parameterization and treatment of ionization effects.
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