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Activation of Nitrous Oxide and Selective Epoxidation of Alkenes
Activation of Nitrous Oxide and Selective Epoxidation of Alkenes

... Nitrous oxide is usually considered to be inert1 and a poor ligand toward transition metals.2 However, there is incentive to use N2O as an oxygen donor because it contains 36 wt % oxygen, and the byproduct of an oxidation reaction would be N2. In practice, there are only a few catalytic systems that ...
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... However, lone pairs cause more repulsion than bonding pairs. The oxygen in water is surrounded by two lone pairs (maximum repulsion), the nitrogen atom in ammonia contains one lone pair, but the carbon in methane has no lone pairs (least repulsion). Q3 B H2S has a higher molecular mass than H2O ...
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... •  Balanced chemical equations provide the exact relationships between the amount of reactants and products. •  2 C8H18 (l) + 25 O2 (g) → 16 CO2 (g) + 18 H2O (g) •  For example 2 molecules of octane (gasoline) react with 25 molecules of oxygen to produce 16 molecules of carbon dioxide gas and 18 mol ...
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Hydrogen-bond catalysis

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