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Problem Set 11: Chemistry Graduate Quantum I Physics 6572
Problem Set 11: Chemistry Graduate Quantum I Physics 6572

... Here kε = 1 in CGS units, and kε = 1/(4πε0 ) in SI units. We are ignoring the slight shift in effective masses due to the motion of the nucleus. ...
Structure, Reactivity and Dynamics
Structure, Reactivity and Dynamics

... years particularly in view of the formation and decay of the resonant metastable negative molecular ion which can decay either giving rise to internally excited neutral molecule plus (an extra) electron or dissociate into the neutral and anionic fragments (disssociative electron attachment, DEA). Qu ...
Project Title : X-RAY LASER RESEARCH
Project Title : X-RAY LASER RESEARCH

n= n= n=1
n= n= n=1

... the following sub levels, (which are also shown in the accompanying diagram) |n, l, j⟩ = |2, 0, 1/2⟩ |n, l, j⟩ = |2, 1, 1/2⟩ |n, l, j⟩ = |2, 1, 3/2⟩. According to fine-structure correction, the energy of each level is, ...
3. Born-Oppenheimer approximation
3. Born-Oppenheimer approximation

View accepted manuscript: Metastable triply charged diatomic
View accepted manuscript: Metastable triply charged diatomic

Lectures 1-2: Introduction to Atomic Spectroscopy Types of Spectra
Lectures 1-2: Introduction to Atomic Spectroscopy Types of Spectra

discrete spectra - Project PHYSNET
discrete spectra - Project PHYSNET

Path integral Monte Carlo
Path integral Monte Carlo

A Simply Regularized Derivation of the Casimir Force
A Simply Regularized Derivation of the Casimir Force

polar molecules in topological order
polar molecules in topological order

... regard to controlling the effective couplings between the constituent spins. In this issue, Micheli, Brennen and Zoller1 kill two birds with one stone: they propose to combine microwave excitations with dipole–dipole interactions and spin–rotation couplings in polar molecules, to realize effective s ...
Fulltext PDF - Indian Academy of Sciences
Fulltext PDF - Indian Academy of Sciences

Isotopic indistinguishibility, scattering processes and the non mass
Isotopic indistinguishibility, scattering processes and the non mass

17588_lecture10-11_11795_laser-and-its-applications2
17588_lecture10-11_11795_laser-and-its-applications2

... decay to the lower state E1. In this process, the atom releases a photon of the same energy, direction, phase and polarization as that of the photon passing by, the net effect is two identical photons (2h) in the place of one, or an increase in the intensity of the incident beam. It is precisely th ...
Problems from Quantum Mechanics
Problems from Quantum Mechanics

Electronic Structure Calculations of InP
Electronic Structure Calculations of InP

... In Fig. 2 the transition energies (solid lines with filled symbols) and their oscillator strengths (dashed lines with empty symbols) versus the conduction band offset for QW widths of 4 nm (a) and 8 nm (b) are shown (a very similar situation takes place for a QW 6 nm and 10 nm wide). At low values o ...
The Franck-Hertz Experiment with Neon tube
The Franck-Hertz Experiment with Neon tube

Slides - GSI IndiCo
Slides - GSI IndiCo

Lecture 23
Lecture 23

Simulation of Spin-Spin Coupling Dynamics in EPR
Simulation of Spin-Spin Coupling Dynamics in EPR

... Conservation of angular momentum prohibits transitions from the singlet to the triplet. At low temperature, two transitions occur in the triplet: between the ground state |1,|1,-1> and the intermediate state |1, 0> (1(1-photon transition) and between |1,|1,-1> and the excited state |1,1> (2(2-photon ...
Introduction to Nanoelectronics Marc Baldo MIT OpenCourseWare Publication May 2011
Introduction to Nanoelectronics Marc Baldo MIT OpenCourseWare Publication May 2011

Pdf - Text of NPTEL IIT Video Lectures
Pdf - Text of NPTEL IIT Video Lectures

Communicating Research to the General Public
Communicating Research to the General Public

schoa - Schieck
schoa - Schieck

... 11. What is the empirical (observed) distinction between emission and absorption spectra? 12. In General terms, how did Bohr explain emission and absorption spectra? 13. If there are many relaxation transitions possible in the Hydrogen atom, why are only 4 bright lines observed on the atomic spectru ...
Atomic Structure and Atomic Spectra
Atomic Structure and Atomic Spectra

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Franck–Condon principle



The Franck–Condon principle is a rule in spectroscopy and quantum chemistry that explains the intensity of vibronic transitions. Vibronic transitions are the simultaneous changes in electronic and vibrational energy levels of a molecule due to the absorption or emission of a photon of the appropriate energy. The principle states that during an electronic transition, a change from one vibrational energy level to another will be more likely to happen if the two vibrational wave functions overlap more significantly.
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