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Active Reading 3.1: Matter and Substances
Active Reading 3.1: Matter and Substances

Equipment o Ppt. o Gas discharge tubes and hand
Equipment o Ppt. o Gas discharge tubes and hand

... We‟d connected the boundary conditions in a square well – that the wavefunction must go to 0 at the edges, with possible wavelengths, thus momenta, and thus energies. See ppt. We‟d made similar arguments for the harmonic potential and for the electric potential via the Bohr model. Q8.1 Energy-Level ...
Angular momentum
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Finite Nuclear Size Effect - Physics
Finite Nuclear Size Effect - Physics

... the lowest energy orbital, n = 1. This much should be intuitive, considering that on average an electron is closer to the nucleus in this lower energy orbital, and therefor experiences this distribution of charge to a larger degree than a more distant electron in the n = 4 orbitals. Likewise, each i ...
E f - Wappingers Central School District
E f - Wappingers Central School District

... The lowest energy level is called the “ground state” (All electrons are in their proper orbitals). When an atom is not in the ground state, it is considered to be in an “excited state”. When an electron absorbs energy from a photon of light, it can transition to another discrete energy level if the ...
The Spectrum of Helium and Calcium
The Spectrum of Helium and Calcium

... 4a. Spectrum of Ca. Another atom with two electrons in a closed sshell is calcium. As one would expect from its greater chemical reactivity, the lowest excited states of Ca are substantially lower than the lowest excited states of He. [For example, the 23 S level of He is at 19.8 eV compared to the ...
Hund`s multiplicity rule: From atoms to quantum dots
Hund`s multiplicity rule: From atoms to quantum dots

... singlet and triplet excited states can be explored by calculations within the framework of the mean-field approximation, and, surprisingly, without the need of introducing the angular electronic correlation. Moreover, our calculations have shown that the triplet state of the QD is lower in energy th ...
Experiment 1 – Data and Error Analysis
Experiment 1 – Data and Error Analysis

Nonlinear Optical Methods to Study Condensed Phase
Nonlinear Optical Methods to Study Condensed Phase

... The reorganization of a solvent around a newly formed state, such as an electronically excited state created by a short optical pulse, can be followed by means of a time-dependent shift in the fluorescence spectrum--the time-dependent Stokes shift. The response can be characterized by a Stokes shift ...
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PowerPoint - Subir Sachdev

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7. Heat capacity

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TDDFT as a tool in chemistry
TDDFT as a tool in chemistry

Part 2. Three Primary Areas of Theoretical Chemistry
Part 2. Three Primary Areas of Theoretical Chemistry

Chapter 5. An Overview of Theoretical Chemistry
Chapter 5. An Overview of Theoretical Chemistry

the quantum mechanical potential for the prime numbers
the quantum mechanical potential for the prime numbers

3D quantum mechanics, hydrogen atom
3D quantum mechanics, hydrogen atom

... (Actually solving the equations is too much math for us.) ...
atomicspectra1-2
atomicspectra1-2

... Ca I 3d4p 3D°2 level belongs to the 3D° term which, in turn, belongs to the 3d4p 3(P° D° F°) triplet triad 3d4p configuration also has a 1(P° D° F°) singlet triad. 3d4s configuration has only monads, one 1D and one 3D 3d4s 3D2 - 3d4p 3D°3 line belongs to the corresponding 3D - 3D° triplet multiplet ...
Dynamical model of nuclear motion in the Auger emission spectrum
Dynamical model of nuclear motion in the Auger emission spectrum

... second-order quantum processes, such as the resonant x-rayemission spectrum ~RXES! or the resonant Auger electronemission spectrum ~RAES!. Gel’mukhanov and Ågren developed a general theory of RXES and RAES for molecules involving the dissociative state @6,7#. Pahl et al. extensively discussed the co ...
Stochastic mechanism of excitation of molecules that interact with
Stochastic mechanism of excitation of molecules that interact with

... anharmonicity parameter chosen by us is therefore higher than used in r e a l experiments on the excitation of polyatomic molecules. The chosen model makes it possible nevertheless to trace the characteristic singularities of the influence of the stochastic component of the motion on the possibility ...
CAPE CHEMISTRY UNIT TWO REVISION PAPER MODULE 1 (a
CAPE CHEMISTRY UNIT TWO REVISION PAPER MODULE 1 (a

... Redistribution of outer electrons in molecular orbitals Quantitative analysis Redistribution of outer electrons in molecular orbitals Qualitative analysis Vibration of chemical bonds ...
ELECTRONIC PROPERTIES OF GaAs AND HUBBARD
ELECTRONIC PROPERTIES OF GaAs AND HUBBARD

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l - Evergreen

I believe the chemical bond is not so simple as people seem to think
I believe the chemical bond is not so simple as people seem to think

... Hea2 .butterfly, Its existence was for a long delicate molecule formed by two helium atoms requires a light touch. time disputed because of its extremely small binding enThe helium dimer is the largest two-atom molecule and has the ...
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Franck–Condon principle



The Franck–Condon principle is a rule in spectroscopy and quantum chemistry that explains the intensity of vibronic transitions. Vibronic transitions are the simultaneous changes in electronic and vibrational energy levels of a molecule due to the absorption or emission of a photon of the appropriate energy. The principle states that during an electronic transition, a change from one vibrational energy level to another will be more likely to happen if the two vibrational wave functions overlap more significantly.
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