Haloalkanes and Haloarenes
... chlorofluoromethanes are gases at room temperature. Higher members are liquids or solids. As we have already learnt, molecules of organic halogen compounds are generally polar. Due to greater polarity as well as higher molecular mass as compared to the parent hydrocarbon, the intermolecular forces o ...
... chlorofluoromethanes are gases at room temperature. Higher members are liquids or solids. As we have already learnt, molecules of organic halogen compounds are generally polar. Due to greater polarity as well as higher molecular mass as compared to the parent hydrocarbon, the intermolecular forces o ...
CHM-373 American Women in Science and Society
... Synthesis of Aldehydes and Ketones • Hydration of Alkynes • Involves a keto-enol tautomerization • Mixture of ketones seen with internal alkynes ...
... Synthesis of Aldehydes and Ketones • Hydration of Alkynes • Involves a keto-enol tautomerization • Mixture of ketones seen with internal alkynes ...
01. Introduction of bioorganic chemistry. Classification, structure
... So far as alkenes have double bonds they are more reactive than alkanes and undergo addition reactions. Some of the reagents that can be added to alkenes: hydrogen, halogens, hydrogen halides, water, sulfuric acid, etc. ...
... So far as alkenes have double bonds they are more reactive than alkanes and undergo addition reactions. Some of the reagents that can be added to alkenes: hydrogen, halogens, hydrogen halides, water, sulfuric acid, etc. ...
4.9 Preparation of Alkyl Halides from Alcohols and Hydrogen Halides
... by positively charged carbon because the s orbital can overlap with the empty 2p orbital of positively charged carbon ...
... by positively charged carbon because the s orbital can overlap with the empty 2p orbital of positively charged carbon ...
10. Alkyl Halides - faculty at Chemeketa
... Why this Chapter? Reactions involving organohalides are less ...
... Why this Chapter? Reactions involving organohalides are less ...
ETHER
... Has a pair of alkyl or atomic groups attached to a linking oxygen atom. Functional group is ROR Have primary, secondary, and tertiary structures ...
... Has a pair of alkyl or atomic groups attached to a linking oxygen atom. Functional group is ROR Have primary, secondary, and tertiary structures ...
Suggested Problems for Chapter 1
... 7. (12 pts.) An unknown compound A (molecular formula C7H14O) was treated with NaBH4 in CH3OH to form compound B (molecular formula C7H16O). Compound A has a strong absorption in its IR spectrum at 1716 cm-1. Compound B has strong absorption in its IR spectrum at 3200-3600 cm-1. The 1H NMR spectra ...
... 7. (12 pts.) An unknown compound A (molecular formula C7H14O) was treated with NaBH4 in CH3OH to form compound B (molecular formula C7H16O). Compound A has a strong absorption in its IR spectrum at 1716 cm-1. Compound B has strong absorption in its IR spectrum at 3200-3600 cm-1. The 1H NMR spectra ...
Chemistry of DOW Glycol Ether Products
... esterification with acetic acid or anhydride. DOWANOL DPMA is the acetate resulting from the reaction of DOWANOL DPM with acetic acid or anhydride. ...
... esterification with acetic acid or anhydride. DOWANOL DPMA is the acetate resulting from the reaction of DOWANOL DPM with acetic acid or anhydride. ...
An Oxidation-Reduction Scheme: Borneol, Camphor, Isoborneol1
... sodium borohydride NaBH4, are widely used in reducing carbonyl groups. Lithium aluminum hydride, for example, reduces many compounds containing carbonyl groups, such as aldehydes, ketones, carboxylic acids, esters, or amides, whereas sodium borohydride reduces only aldehydes and ketones. The reduced ...
... sodium borohydride NaBH4, are widely used in reducing carbonyl groups. Lithium aluminum hydride, for example, reduces many compounds containing carbonyl groups, such as aldehydes, ketones, carboxylic acids, esters, or amides, whereas sodium borohydride reduces only aldehydes and ketones. The reduced ...
Required Resources and Materials
... NB: Write down structures. Also write down explanation about the product (or lack of) Type of reaction: Alcohol oxidation Modelling: (Carbon-black; Hydrogen–white;Oxygen-Red) – model methylpropan-2-ol only but explain reaction ...
... NB: Write down structures. Also write down explanation about the product (or lack of) Type of reaction: Alcohol oxidation Modelling: (Carbon-black; Hydrogen–white;Oxygen-Red) – model methylpropan-2-ol only but explain reaction ...
Chapter 18 Carboxylic Acid Derivatives
... – Sulfonic acid esters are prepared by the reaction of an alkane- or arenesulfonyl chloride with an alcohol or phenol. – The key point here is that OH- is transformed into a sulfonic ester (a good leaving group) with retention of configuration at the chiral center. OT s ...
... – Sulfonic acid esters are prepared by the reaction of an alkane- or arenesulfonyl chloride with an alcohol or phenol. – The key point here is that OH- is transformed into a sulfonic ester (a good leaving group) with retention of configuration at the chiral center. OT s ...
organic powerpoint
... Organic acids, alcohols, esters, aldehydes, ketones, ethers, halides, amines, amides, and amino acids are categories of organic molecules that differ in their structures. Functional groups impart distinctive physical and chemical properties to organic compounds. (3.1hh) ...
... Organic acids, alcohols, esters, aldehydes, ketones, ethers, halides, amines, amides, and amino acids are categories of organic molecules that differ in their structures. Functional groups impart distinctive physical and chemical properties to organic compounds. (3.1hh) ...
PPT file
... electrophile is added (leaving neutral acetone molecules as the only available electrophiles) O ...
... electrophile is added (leaving neutral acetone molecules as the only available electrophiles) O ...
Carbohydrates I - ChemConnections
... Carbohydrates / Saccharides / Sugars Water, carbon dioxide, light and chlorophyll in green plants: n CO2 + n H2O Cn(H2O)n + n O2 Empirical formula = CH2O ...
... Carbohydrates / Saccharides / Sugars Water, carbon dioxide, light and chlorophyll in green plants: n CO2 + n H2O Cn(H2O)n + n O2 Empirical formula = CH2O ...
ALKANE ALKYL HALIDE Halogenation of Alkanes
... E2 mechanism (write on back of card) only works with 2o and 3o alkyl halides with 2o alkyl halides, use (CH3)3COK to avoid SN2 reactions must have a strong base (usually alkoxide ) constitutional isomers may form if more than one ! hydrogen is ...
... E2 mechanism (write on back of card) only works with 2o and 3o alkyl halides with 2o alkyl halides, use (CH3)3COK to avoid SN2 reactions must have a strong base (usually alkoxide ) constitutional isomers may form if more than one ! hydrogen is ...
Chapter 18
... The acid chloride can be reduced to an aldehyde with lithium tri(t-butoxy) hydride ...
... The acid chloride can be reduced to an aldehyde with lithium tri(t-butoxy) hydride ...
ether - HCC Southeast Commons
... are prepared by the sulfuric acid-catalyzed dehydration procedure? What product(s) would you expect if ethanol and 1-propanol were allowed to react together? In what ratio would the products be formed if the two alcohols were of equal reactivity? ...
... are prepared by the sulfuric acid-catalyzed dehydration procedure? What product(s) would you expect if ethanol and 1-propanol were allowed to react together? In what ratio would the products be formed if the two alcohols were of equal reactivity? ...
Alcohol
In chemistry, an alcohol is any organic compound in which the hydroxyl functional group (–OH) is bound to a saturated carbon atom. The term alcohol originally referred to the primary alcohol ethyl alcohol (ethanol), the predominant alcohol in alcoholic beverages.The suffix -ol appears in the IUPAC chemical name of all substances where the hydroxyl group is the functional group with the highest priority; in substances where a higher priority group is present the prefix hydroxy- will appear in the IUPAC name. The suffix -ol in non-systematic names (such as paracetamol or cholesterol) also typically indicates that the substance includes a hydroxyl functional group and, so, can be termed an alcohol. But many substances, particularly sugars (examples glucose and sucrose) contain hydroxyl functional groups without using the suffix. An important class of alcohols, of which methanol and ethanol are the simplest members is the saturated straight chain alcohols, the general formula for which is CnH2n+1OH.